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Bright waterborne polyurethane and production method thereof

A water-based polyurethane, bright technology, applied in the field of polyurethane preparation, can solve the problems of non-compliance with environmental protection requirements, physical and mental health, environmental pollution, etc., and achieve the effects of scientific and rigorous formulation, avoid environmental pollution, and simple and convenient methods

Inactive Publication Date: 2019-10-08
安徽聚合辐化化工有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The existing solvent-based polyurethane resin needs to be diluted with an organic solvent. During use, the solvent will volatilize and cause environmental pollution, which does not meet environmental protection requirements and physical and mental health. Therefore, in recent years, people have focused on the development of water-based polyurethane bright resin

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] A bright water-based polyurethane, including component A and component B, component A includes the following components in parts by weight: polycarbonate diol UH-20070 parts, polyoxypropylene triol 10 parts, isophorone diol 30 parts of isocyanate, 5 parts of dimethylol propionic acid, 5 parts of 1-2 propylene glycol, 0.2 part of stannous octoate, 5 parts of triethylamine and 200 parts of deionized water; component B includes the following components in parts by weight: 70 parts of polycarbonate diol PC-2000, 10 parts of polyoxypropylene triol, 20 parts of isophorone diisocyanate, 5 parts of dimethylol propionic acid, 0.2 parts of stannous octoate, 0.3 parts of ethylenediamine, triethylene 5 parts of amine and 180 parts of deionized water.

[0021] According to the preparation method of above-mentioned bright waterborne polyurethane, comprise the steps,

[0022] (1) Prepare component A; weigh the raw materials according to the formula, add polycarbonate diol UH-200, pol...

Embodiment 2

[0026] A bright water-based polyurethane, comprising component A and component B, said component A comprising the following components in parts by weight: 60 parts of polycarbonate diol, 15 parts of polyoxypropylene triol, isophorone diol 35 parts of isocyanates, 7.5 parts of dimethylol propionic acid, 7.5 parts of 1-2 propylene glycol, 0.5 parts of stannous octoate, 7.5 parts of triethylamine and 225 parts of deionized water; the component B includes the following parts by weight Subdivision: 75 parts of polycarbonate diol, 15 parts of polyoxypropylene triol, 25 parts of isophorone diisocyanate, 7.5 parts of dimethylol propionic acid, 0.5 parts of stannous octoate, 0.5 parts of ethylenediamine, triethylene 7.5 parts of amine and 190 parts of deionized water.

[0027] According to the preparation method of above-mentioned bright waterborne polyurethane, comprise the steps,

[0028] (1) Preparation of component A; Weigh the raw materials according to the formula, add polycarbo...

Embodiment 3

[0032] A bright water-based polyurethane, including component A and component B, component A includes the following components in parts by weight: polycarbonate diol UH-20080 parts, polyoxypropylene triol 20 parts, isophorone diol 40 parts of isocyanate, 10 parts of dimethylol propionic acid, 10 parts of 1-2 propylene glycol, 0.8 parts of stannous octoate, 10 parts of triethylamine and 250 parts of deionized water; component B includes the following components in parts by weight: 80 parts of polycarbonate diol PC-2000, 20 parts of polyoxypropylene triol, 30 parts of isophorone diisocyanate, 10 parts of dimethylol propionic acid, 0.8 parts of stannous octoate, 0.7 parts of ethylenediamine, triethylene 10 parts of amine and 200 parts of deionized water.

[0033] According to the preparation method of above-mentioned bright waterborne polyurethane, comprise the steps,

[0034] (1) Prepare component A; weigh the raw materials according to the formula, add polycarbonate diol UH-20...

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PUM

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Abstract

The invention relates to the technical field of production of polyurethane, and particularly discloses bright waterborne polyurethane. The bright waterborne polyurethane comprises a component A and acomponent B, wherein the component A comprises the following components in parts by weight: 70-80 parts of polycarbonate diol, 10-20 parts of polyoxypropylene triol, 30-40 parts of isophorone diisocyanate, 5-10 parts of dimethylolpropionic acid, 5-10 parts of 1,2-propanediol, 0.2-0.8 part of a catalyst, 5-10 parts of triethylamine and 200-250 parts of deionized water; and the component B comprisesthe following components in parts by weight: 70-80 parts of polycarbonate diol, 10-20 parts of polyoxypropylene triol, 20-30 parts of isophorone diisocyanate, 5-10 parts of dimethylolpropionic acid,0.2-0.8 part of a catalyst, 0.3-0.7 part of ethylenediamine, 5-10 parts of triethylamine and 180-200 parts of deionized water. According to the bright waterborne polyurethane, the defects of the priorart are overcome, use of toxic organic solvents is reduced, the situation that the toxic organic solvents volatilize to cause environmental pollution is avoided, and meanwhile, the finished product polyurethane is high in glossiness after forming a film, feels soft, and is good in color fastness to water.

Description

technical field [0001] The invention relates to the technical field of polyurethane preparation, in particular to a bright water-based polyurethane and a preparation method thereof. Background technique [0002] Bright resin is a kind of resin commonly used in the production of fabric printing adhesives, which can give the printed surface a bright appearance, and can also give the synthetic a certain feel. Most of the existing bright resins are solvent-based polyurethane resins, which are prepared by adding various additives after dilution with solvents. [0003] The existing solvent-based polyurethane resin needs to be diluted with an organic solvent. During use, it will cause environmental pollution due to solvent volatilization, which does not meet environmental protection requirements and physical and mental health. Therefore, in recent years, people have focused on the development of water-based polyurethane bright resin. Contents of the invention [0004] The purpos...

Claims

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Application Information

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IPC IPC(8): C08G18/66C08G18/12C08G18/32C08G18/34C08G18/40C08G18/44C08G18/48
CPCC08G18/12C08G18/3206C08G18/348C08G18/4018C08G18/44C08G18/4829C08G18/6607C08G18/6618C08G18/6625C08G18/3228
Inventor 苏国庆谢伟黄世江杨明虎胡中青朱亮
Owner 安徽聚合辐化化工有限公司
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