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A kind of method for preparing low-temperature polyvinyl alcohol water-soluble fiber

A technology of water-soluble fiber and polyvinyl alcohol, which is applied in the direction of fiber chemical characteristics, melt spinning method, stretch spinning method, etc., can solve the problems of low usability and long dissolution time of water-soluble fiber, and achieve short production process , high yield and low water melting temperature

Active Publication Date: 2021-12-07
ANHUI WANWEI UPDATED HIGH TECH MATERIAL CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the water-soluble fiber prepared by it takes a long time to dissolve in low-temperature water (more than 20 minutes), and the actual usability is not high.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] The preparation method of the present embodiment polyvinyl alcohol water-soluble fiber, comprises the steps:

[0029] 1. Preparation of plasticizer

[0030] Prepare a compound plasticizer according to the mass ratio of glycerin, ethylene glycol, and N,N-dimethylformamide at 3:1:1, and mix at 40°C for 2 hours.

[0031] 2. Melt spinning

[0032] The raw material is polyvinyl alcohol powder with a degree of polymerization of 1700, a degree of alcoholysis of 99%, and a fineness of 100 mesh. The raw materials and compound plasticizer are added into the twin-screw extruder at a mass ratio of 7:3, fully melted, and then sprayed out through a 0.1mm spinneret, and the melt is cooled to obtain polyvinyl alcohol primary fibers. The temperature of each section of the screw is: feeding section 50°C, mixing section 80°C, melting section 180°C, compression section 180°C, metering section 180°C, spinneret temperature 170°C, cooling air temperature 45°C.

[0033] 3. Stretching and sh...

Embodiment 2

[0039] The preparation method of the present embodiment polyvinyl alcohol water-soluble fiber, comprises the steps:

[0040] 1. Preparation of plasticizer

[0041] Prepare a compound plasticizer according to the mass ratio of glycerin and caprolactam at 3:1, and mix at 60°C for 2.5 hours.

[0042] 2. Melt spinning

[0043] The raw material is polyvinyl alcohol powder with a degree of polymerization of 1700, a degree of alcoholysis of 88%, and a fineness of 80 mesh. The raw materials and compound plasticizer are added into the twin-screw extruder at a mass ratio of 6:4, fully melted, and then sprayed out through a 0.2mm spinneret, and the melt is cooled to obtain polyvinyl alcohol primary fibers. The temperature of each section of the screw is: feeding section 50°C, mixing section 80°C, melting section 180°C, compression section 180°C, metering section 180°C, spinneret temperature 170°C, cooling air temperature 45°C.

[0044] 3. Stretching and shaping

[0045] The as-spun f...

Embodiment 3

[0050] The preparation method of the present embodiment polyvinyl alcohol water-soluble fiber, comprises the steps:

[0051] 1. Preparation of plasticizer

[0052] Prepare a compound plasticizer according to the mass ratio of glycerin, caprolactam, and polyethylene glycol-200 at a ratio of 3:1:1, and mix at 60°C for 2 hours.

[0053] 2. Melt spinning

[0054] The raw material is polyvinyl alcohol powder with a degree of polymerization of 500, a degree of alcoholysis of 99%, and a fineness of 80 mesh. The raw materials and compound plasticizer are added into the twin-screw extruder at a mass ratio of 7:3, fully melted, and then sprayed out through a 1mm spinneret, and the melt is cooled to obtain polyvinyl alcohol primary fibers. The temperature of each section of the screw is: feeding section 50°C, mixing section 80°C, melting section 180°C, compression section 180°C, metering section 180°C, spinneret temperature 170°C, cooling air temperature 45°C.

[0055] 3. Stretching a...

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Abstract

The invention discloses a method for preparing low-temperature polyvinyl alcohol water-soluble fibers, which comprises unit processes of raw material mixing, melt spinning, stretching and shaping, crimping and cutting. The invention realizes polyvinyl alcohol melt spinning by plasticizing polyols and amide compounds, which can fully dissolve the raw material polyvinyl alcohol than general water as a plasticizer, because the polyvinyl alcohol raw material contains a small amount of impurities that are insoluble in water , These impurities affect the forming and fiber structure of the fiber during spinning; and the present invention has shorter process flow than the traditional water-soluble fiber preparation method, high production efficiency and no pollution.

Description

technical field [0001] The invention relates to a method for water-soluble polyvinyl alcohol fibers, in particular to a method for preparing low-temperature polyvinyl alcohol water-soluble fibers. Background technique [0002] Polyvinyl alcohol is a polymer compound with good water solubility and biodegradability, strong acid and alkali resistance, and strong adsorption. It is tasteless and non-toxic after being dissolved in water, and can be decomposed naturally in a short time. It does not produce any environmental pollution, and is widely used in non-woven fabrics, embroidery base fabrics, papermaking, medical disposable surgical gowns and other fields. At present, wet spinning is basically used in China to prepare polyvinyl alcohol water-soluble fibers, and its dissolution temperature is relatively high, ranging from 80°C to 100°C. Moreover, the wet spinning process is long, the three wastes in the process are polluted, and the energy consumption is high. When the fabri...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D01F6/50D01F1/10D01D5/08D01D5/12D02J13/00
CPCD01D5/08D01D5/12D01F1/10D01F6/50D02J13/00
Inventor 唐成宏姜家保王平林胡庆东张晓春沈瑞葛琳王健汤立业
Owner ANHUI WANWEI UPDATED HIGH TECH MATERIAL CO LTD