Ideal two-dimensional Fermi liquid system Bi2O2Se single crystal and preparation method and application thereof

A single crystal and multi-purpose technology, applied in the ideal two-dimensional Fermi liquid system—Bi2O2Se single crystal and its preparation field, can solve the problem of small amount of crystal materials, achieve low cost, simple preparation method, and excellent crystal quality.

Active Publication Date: 2019-10-29
NANJING UNIV
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, so far, the number of such crystalline materials that confo

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  • Ideal two-dimensional Fermi liquid system Bi2O2Se single crystal and preparation method and application thereof
  • Ideal two-dimensional Fermi liquid system Bi2O2Se single crystal and preparation method and application thereof

Examples

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Embodiment 2

[0062] Example 2. With Bi 2 o 3 , Bi, Se as raw materials through solidification and crystallization growth to obtain Bi 2 o 2 Se crystal

[0063] Weigh 0.01mol of Bi 2 o 3Powder (4.6608g), 0.01mol of Bi powder (2.0900g), and 0.015mol of Se powder (1.1845g) were mixed evenly and loaded into a pre-prepared quartz tube (length 10cm, diameter 2cm). Using a mechanical pump, The molecular pump is vacuumed and sealed, and then the sealed quartz tube is fixed on the pulling rod of the molten salt pulling furnace, and the raw material reaction temperature is set at 550°C, and the reaction time is 48h, and then the temperature is raised to 950°C, at 950°C Keep it warm for 24 hours to make it melt evenly, then cool down at a rate of 2°C / h. After a 10-day growth cycle, naturally cool down to obtain Bi 2 o 2 Se bulk, dissociated to obtain millimeter-scale Bi with high quality 2 o 2 Se single crystal, the maximum size reaches about 2mm, such as figure 2 (a) shown.

[0064] Such...

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Abstract

The invention discloses an ideal two-dimensional Fermi liquid system Bi2O2Se single crystal, and belongs to the field of electronic materials. The crystal structure of the Bi2O2Se single crystal is atetragonal crystal system, and the space group is I4/mmm (139). The Bi2O2Se single crystal can be prepared by using a chemical vapor-phase transport method (i.e. a sublimation method) and a solidification crystallization method. The Bi2O2Se single crystal which is obtained through growth by using the two methods is of a sheet shape, and the crystal has a size range of millimeters, high purity andgood chemical composition uniformity. In a wide temperature range of 2-300 K, the experimentally-measured resistivity of the Bi2O2Se crystal is proportional to the square of temperature (T<2>), the Fermi liquid theory is conformed, and the Bi2O2Se single crystal is an ideal two-dimensional Fermi liquid system. In addition, the electron mobility of the Bi2O2Se crystal is not less than 2.24x10<5> cm<2>V<-1>s<-1> at 2 K and 300 cm<2>V<-1>s<-1> at 300 K separately, and the Bi2O2Se has good stability in air, so good application prospects are achieved in the field of future electronic devices; and meanwhile the Bi2O2Se has a simple growth method and low cost, and is conducive to industrial production.

Description

technical field [0001] The invention belongs to the field of electronic materials, in particular to an ideal two-dimensional Fermi liquid system—Bi 2 o 2 Se single crystal and its preparation method and application. Background technique [0002] The Landau Fermi liquid theory is a phenomenological theory describing the quasiparticle behavior of the interacting fermion system and the corresponding physical properties of the system. This theory was first applied to explain 3 In He's question. Subsequently, under the premise of ignoring the potential energy of the periodic lattice in the metal, this theory was slightly modified and extended to deal with the electron problem in the metal, which is called the gel model of the metal. The underlying assumption is that a group of interacting particles can be described by a gas of nearly non-interacting quasiparticles. On the physical picture, a quasiparticle can be regarded as an independent electron moving under the mean field ...

Claims

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Application Information

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IPC IPC(8): C30B29/46C30B25/00C30B11/02
CPCC30B11/02C30B25/00C30B29/46
Inventor 吕洋洋徐璐陈延彬姚淑华周健陈延峰
Owner NANJING UNIV
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