Polymerizable compound and method for producing the same, polymerizable composition, polymer, optical film, and optically anisotropic body
A technology of a polymerizable compound and hydrogen atom is applied to polarizers, the manufacture of the above-mentioned polymerizable compound, a display device and an anti-reflection film, the compound of the preparation of the polymerizable compound, the use field of the above-mentioned compound, can solve the problem of color, etc., Achieve the effect of improved in-plane uniformity and excellent in-plane uniformity
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[0649] Hereinafter, the present invention will be described in more detail through examples. However, the present invention is not limited in any way by the following examples.
Synthetic example 1
[0650] (Synthesis example 1) Synthesis of polymerizable compound 1 (an example of a compound represented by formula (III-1))
[0651] [chemical formula 66]
[0652]
[0653]
[0654] [chemical formula 67]
[0655]
[0656] In a nitrogen stream, in a 3-port reactor with a thermometer, 83.05g (0.40mol) trans-1,4-cyclohexanedicarboxylic acid dichloride was added to 600g cyclopentyl methyl ether, in an ice bath Cool down to 5°C. To this solution were added 100 g (0.38 mol) of 4-(6-acryloyloxy-hex-1-yloxy)phenol (manufactured by DKSH), and 1.67 g of 2,6-di-tert-butyl-4- methylphenol and 230 g tetrahydrofuran (THF). Under vigorous stirring, 40.2 g (0.40 mol) of triethylamine was slowly added dropwise thereto. After completion of the dropwise addition, the reaction was carried out at 5° C. for 1 hour. After the reaction was completed, 250 g of water was added, and then, the temperature was raised to 50° C. and stirred for 4 hours. Then, 416 g of 1 mol / L concentration of...
Synthetic example 2
[0676] (Synthesis example 2) Synthesis of polymerizable compound 2 (another example of the compound represented by formula (III-1))
[0677] [chemical formula 71]
[0678]
[0679]
[0680] [chemical formula 72]
[0681]
[0682] In a nitrogen stream, 11.49 g (54.65 mmol) of 9-fluorenecarboxylic acid and 75 mL of N-methyl-2-pyrrolidone were charged into a three-port reactor equipped with a thermometer to form a uniform solution. 7.50 g (45.55 mmol) of 8-chloro-1-n-octanol were added thereto. Next, 1.33 g (10.89 mmol) of N,N-dimethyl-4-aminopyridine was added. Then, 12.57 g (65.59 mmol) of 1-ethyl-3-(3-dimethylaminopropyl) carbodiimide hydrochloride was added over 5 minutes while maintaining the temperature in the reaction solution at 20 to 30° C., and then The entire contents were stirred for a further 4 hours at 25°C. After the reaction, 250 mL of saturated brine was added to the reaction liquid, and extracted twice with 250 mL of ethyl acetate. The organic layer...
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Abstract
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