Multilayer Coating Film Formation Method
A multi-layer coating film and coating technology, which is applied in coatings, devices for coating liquid on the surface, primers, etc., can solve problems such as damage to the glossy feeling of the inner panel coating film, and achieve an excellent glossy effect
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[0078] Hereinafter, an Example and a comparative example are given, and this invention is demonstrated more concretely. However, the present invention is not limited to these Examples. In addition, both "part" and "%" are based on mass.
[0079] Manufacture of acrylic resin emulsion (a)
manufacture example 1
[0081] 128 parts of deionized water, "Adekaliasoup SR-1025" (trade name, manufactured by ADEKA, emulsifier , active ingredient 25%) 2 parts, stirred and mixed in a nitrogen flow, and heated to 80 ° C.
[0082]Next, 1% of the total amount of the monomer emulsion for core parts described below and 5.3 parts of a 6% ammonium persulfate aqueous solution were introduced into the reaction container, and kept at 80° C. for 15 minutes. Then, the remaining part of the monomer emulsion for core part was dripped in the reaction container maintained at the same temperature over 3 hours, and aging was performed for 1 hour after completion|finish of dripping. Next, the following shell monomer emulsion was added dropwise over 1 hour, and after aging for 1 hour, 40 parts of 5% 2-(dimethylamino)ethanol aqueous solution was slowly added to the reaction vessel while cooling to 30°C. , and discharged while filtering through a 100-mesh nylon mesh to obtain an acrylic resin emulsion (a) with an av...
manufacture example 2
[0087] Put 35 parts of propylene glycol monopropyl ether into a reaction vessel equipped with a thermometer, a thermostat, a stirring device, a reflux cooler, a nitrogen introduction pipe and a dropping device, and after raising the temperature to 85°C, add methyl methacrylate dropwise over 4 hours 30 parts of ester, 20 parts of 2-ethylhexyl acrylate, 29 parts of n-butyl acrylate, 15 parts of 2-hydroxyethyl acrylate, 6 parts of acrylic acid, 15 parts of propylene glycol monopropyl ether, and 2,2'-azo A mixture of 2.3 parts of bis(2,4-dimethylvaleronitrile) was aged for 1 hour after the dropwise addition was completed. Then, a mixture of 10 parts of propylene glycol monopropyl ether and 1 part of 2,2'-azobis(2,4-dimethylvaleronitrile) was added dropwise over 1 hour, and aging was carried out for 1 hour after the dropwise addition was completed. Furthermore, 7.4 parts of diethanolamines were added, and the hydroxyl group containing acrylic resin solution (b-1) whose solid conten...
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