Unlock instant, AI-driven research and patent intelligence for your innovation.

Multicomponent flame-retardant polypropylene material and preparation method thereof

A flame retardant polypropylene and polypropylene technology, applied in the field of multi-component flame retardant polypropylene materials and their preparation, can solve the problems of poor flame retardant effect, high application cost, low hygroscopicity, etc., and achieve high flame retardant efficiency and difficult processing. Low, low cost effect

Active Publication Date: 2019-12-06
FUJIAN NORMAL UNIV
View PDF8 Cites 2 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

As one of the commonly used halogen-free flame retardants, ammonium polyphosphate does not produce corrosive gas during the decomposition process, has low hygroscopicity and high thermal stability, and is a halogen-free flame retardant with excellent performance; aluminum hypophosphite is a High-efficiency inorganic phosphorus-containing flame retardant, with a phosphorus content of up to 41.9%, has high flame-retardant efficiency, excellent thermal stability and hydrolytic stability, and is not easy to cause polymer decomposition during processing. It can be added alone , and can also be compounded with other flame retardants. It is a widely used flame retardant. The disadvantage is that the price is relatively high and the application cost is high; melamine cyanurate is a nitrogen-based halogen-free flame retardant. Odorless and tasteless, with high decomposition temperature, it is an ideal flame retardant synergist in industrial production
Usually, when a single flame retardant is added to polypropylene, the flame retardant effect is often poor, so the compounding of multiple flame retardants in an appropriate ratio is an effective means for flame retardant polypropylene at present.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Multicomponent flame-retardant polypropylene material and preparation method thereof
  • Multicomponent flame-retardant polypropylene material and preparation method thereof
  • Multicomponent flame-retardant polypropylene material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0056] A multi-component flame-retardant polypropylene material and a preparation method thereof, comprising: 70 parts of polypropylene, 15 parts of ammonium polyphosphate, 10 parts of aluminum hypophosphite, 2 parts of compatibilizer, 2 parts of coupling agent, and 1 part of antioxidant.

[0057] (1) Dry 70 parts of polypropylene, 15 parts of ammonium polyphosphate and 10 parts of aluminum hypophosphite in a drying oven at 80~90°C for 4~6 hours;

[0058] (2) Add 15 parts of ammonium polyphosphate after drying, 10 parts of aluminum hypophosphite and 2 parts of coupling agent into the high mixer, keep the speed at 2000 rpm, and stir at high speed for 5 minutes to obtain surface-modified ammonium polyphosphate And aluminum hypophosphite, stand-by;

[0059] (3) According to the proportion, put 70 parts of polypropylene and 2 parts of compatibilizer in the high-speed mixer after drying to remove moisture, and mix for 10 minutes at 2000 rpm to obtain the mixed material;

[0060] (...

Embodiment 2

[0064] A multi-component flame-retardant polypropylene material and its preparation method, comprising: 70 parts of polypropylene, 13 parts of aluminum hypophosphite, 12 parts of melamine cyanurate, 2 parts of compatibilizer, 2 parts of coupling agent, and 1 part of antioxidant share.

[0065] (1) Dry 70 parts of polypropylene, 13 parts of aluminum hypophosphite and 12 parts of melamine cyanurate in a drying oven at 80~90°C for 4~6 hours;

[0066] (2) Add 13 parts of aluminum hypophosphite, 12 parts of melamine cyanurate and 2 parts of coupling agent into the high-mixer after drying, keep the speed at 2000 rpm, and stir at high speed for 5 minutes to obtain the surface-modified secondary Aluminum phosphate and melamine cyanurate, ready for use;

[0067] (3) According to the proportion, put 70 parts of polypropylene and 2 parts of compatibilizer in the high-speed mixer after drying to remove moisture, and mix for 10 minutes at 2000 rpm to obtain the mixed material;

[0068] (...

Embodiment 3

[0072] A multi-component flame-retardant polypropylene material and its preparation method, comprising: 70 parts of polypropylene, 15 parts of ammonium polyphosphate, 5 parts of aluminum hypophosphite, 5 parts of melamine cyanurate, 2 parts of compatibilizer, and 2 parts of coupling agent 1 part, antioxidant 1 part.

[0073] (1) Dry 70 parts of polypropylene, 15 parts of ammonium polyphosphate, 5 parts of aluminum hypophosphite and 5 parts of melamine cyanurate in a drying oven at 80~90°C for 4~6 hours;

[0074] (2) Add 15 parts of ammonium polyphosphate, 5 parts of aluminum hypophosphite, 5 parts of melamine cyanurate and 2 parts of coupling agent into the high mixer, keep the speed at 2000 rpm, and stir at high speed for 5 minutes. Obtain surface-modified ammonium polyphosphate, aluminum hypophosphite and melamine cyanurate, stand-by;

[0075] (3) According to the proportion, put 70 parts of polypropylene and 2 parts of compatibilizer in the high-speed mixer after drying to...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
particle diameteraaaaaaaaaa
degree of polymerizationaaaaaaaaaa
Login to View More

Abstract

The invention discloses a multicomponent flame-retardant polypropylene material and a preparation method thereof. The multicomponent flame-retardant polypropylene material comprises the following components in parts by weight: 70-80 parts of polypropylene, 10-30 parts of ammonium polyphosphate, 5-30 parts of aluminum hypophosphite, 5-30 parts of melamine cyanurate, 0.5-3 parts of a compatilizer, 0.5-3 parts of a coupling agent and 1-3 parts of an antioxidant. According to the invention, the polypropylene material has excellent flame retardant performance by optimizing the proportion among themulti-component flame retardants, and the mechanical property of the polypropylene material can be well maintained. In addition, processing difficulty is low, the application range is wide, and the production process is environmentally friendly and pollution free.

Description

technical field [0001] The invention relates to the technical field of polypropylene material production, in particular to a multi-component flame-retardant polypropylene material and a preparation method thereof. Background technique [0002] Polypropylene (PP) is a widely used thermoplastic, which has the advantages of high crystallinity, regular structure, good heat resistance, etc., and is widely used in various fields in daily life. However, the limiting oxygen index of pure polypropylene resin is extremely low, only 18%, and a large number of molten droplets will be generated during the combustion process, which will cause the fire to continue to expand and lead to serious fire accidents. [0003] In view of the flammability of polypropylene materials, flame retardant modification of polypropylene is required. At present, there are many types of polypropylene flame retardants, mainly divided into halogen flame retardants and halogen-free flame retardants. Among them, ...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/12C08L51/06C08K13/06C08K9/00C08K3/32C08K5/3492C08K5/134C08K5/526
CPCC08L23/12C08L2201/02C08K2003/323C08L51/06C08K13/06C08K9/00C08K3/32C08K5/34928C08K5/1345C08K5/526
Inventor 李红周魏雄雄刘懿德陈嘉炼颜品萍罗富彬陈庆华
Owner FUJIAN NORMAL UNIV