A karst pipeline-type water gushing high-efficiency plugging ultra-high expansion grouting material and its preparation, use and application
A kind of grouting material and ultra-high technology, which is applied in the field of karst pipeline type water gushing high-efficiency plugging ultra-high expansion grouting material, which can solve the problems of cross-linking and curing of acrylic resin particles, and achieve the effect of low cost and simple operation
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Embodiment 1
[0076] A preparation of super-high expansion grouting material for high-efficiency plugging of karst pipeline-type water gushing, comprising the following steps:
[0077] 1. Preparation of polymer granules A:
[0078] (1) Acrylic acid neutralization stage: first prepare 36 parts of 10% acrylic acid solution and 5 parts of 20% acrylamide interpolymer solution with ice water, add 12 parts of 10% lye to obtain neutralization degree 60% acrylic acid solution.
[0079] (2) Initiating polymerization reaction stage: 0.072 parts of crosslinking agent N, N-methylenebisacrylamide is configured into a solution with a mass fraction of 50%, added to the acrylic acid neutralizing solution configured in step (1), and Stir evenly for 1 hour, then add 50% initiator solution prepared by 0.025 parts of potassium persulfate, heat up to 80° C., and react for 23 minutes to form a colloidal polymer.
[0080] (3) Drying and crushing stage: Grinding the colloidal polymer obtained in step (3), drying...
Embodiment 2
[0103] A preparation of super-high expansion grouting material for high-efficiency plugging of karst pipeline-type water gushing, comprising the following steps:
[0104] 1. Preparation of polymer granules A:
[0105] (1) Acrylic acid neutralization stage: first prepare 36 parts of acrylic acid solution with a mass fraction of 80% and 5 parts of acrylamide interpolymer solution with a mass fraction of 80% with ice water, and add 24 parts of lye with a mass fraction of 60% to obtain the degree of neutralization Neutralizing liquid for 90% acrylic acid solution.
[0106] (2) The stage of initiating polymerization reaction: 0.09 parts of crosslinking agent N, N-methylenebisacrylamide is configured into a solution with a mass fraction of 50%, and 5 parts of the gelling catalyst (polyethylene bisacrylamide) of crosslinking solidification solution B Alcohol: p-di-o-chloroaniline methane: polyether polyol = 2:1:2) to prepare a solution with a mass fraction of 50%, add it to the acry...
Embodiment 3
[0121] A preparation of super-high expansion grouting material for high-efficiency plugging of karst pipeline-type water gushing, comprising the following steps:
[0122] 1. Preparation of polymer granules A:
[0123] (1) Acrylic acid neutralization stage: first prepare 36 parts of acrylic acid solution with a mass fraction of 40% and 5 parts of acrylamide interpolymer solution with a mass fraction of 40% with ice water, and add 12 parts of lye with a mass fraction of 50% to obtain the degree of neutralization It is 75% acrylic acid neutralizing solution.
[0124] (2) Initiating polymerization reaction stage: 0.05 part of crosslinking agent N,N-methylenebisacrylamide is configured into a solution with a mass fraction of 50%, and added to the acrylic acid neutralizing solution prepared in step (1), and uniformly Stir for 1h. Then add a 50% initiator solution prepared by 0.025 parts of ammonium persulfate, heat up to 80° C., and react for 88 minutes to form a colloidal polymer...
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