Method for treating high-fluorine-content wastewater by utilizing fly ash
A fly ash and waste water technology, applied in water/sewage treatment, chemical instruments and methods, adsorption water/sewage treatment, etc., can solve the problems of lack of large adsorption capacity, low-cost adsorbent, poor treatment effect and high treatment cost , achieve the effect of shortening the heating reaction time and improving the efficiency of fluorine removal
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Embodiment 1
[0036] A method of utilizing fly ash to treat high fluorine-containing wastewater comprises the following steps:
[0037] a. Pretreatment of fly ash: get the fly ash to pick out the impurities mixed therein, use Raymond mill to grind the fly ash evenly, then pass through a 300 mesh sieve for subsequent use; get the pretreated fly ash (containing 47.8g SiO 2 and 40.2g Al 2 o 3 ) 100g and 500g concentration are 3mol / L sodium hydroxide solution (alkaline density is 1.12g / cm 3 ) in an open reactor at a reaction temperature of 95-100°C, a stirring speed of 100 rpm and a reaction time of 6 hours for a modification reaction, and then the reaction product is cooled and separated from solid and liquid by a centrifuge to obtain a modification Reactive solid phase and alkaline liquid, take the modified solid phase, filter and dry naturally to obtain modified fly ash; in step a, the modification reaction adopts electric heating or oil bath heating to heat the reactor ; The modificatio...
Embodiment 2
[0042] In step a, the liquid-solid ratio of sodium hydroxide solution and the fly ash after pretreatment is 4:1, and other technical schemes are the same as embodiment 1, and the fluorine removal rate is 81.9%.
Embodiment 3
[0044] The sodium hydroxide solution adopts 2mol / L in the step a, and other technical schemes are the same as embodiment 1, and the fluorine removal rate is 79.8%.
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