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Waste ash curing agent and preparation method thereof and application of waste ash curing agent in sludge curing

A technology of curing agent and slag, applied in the field of engineering, can solve the problems of poor sludge strength and poor water absorption effect, and achieve the effect of good freeze-thaw resistance and large internal friction angle.

Active Publication Date: 2020-04-10
福建原野环保科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The curing agent in the prior art has poor water absorption effect, and the mud strength after curing is poor

Method used

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  • Waste ash curing agent and preparation method thereof and application of waste ash curing agent in sludge curing
  • Waste ash curing agent and preparation method thereof and application of waste ash curing agent in sludge curing

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0044] A solidifying agent for waste ash, prepared from the following raw materials in parts by weight: 55 parts of modified waste ash, 30 parts of modified fly ash, 8 parts of slaked lime, 5 parts of sodium lignosulfonate, and active activator 2 servings.

[0045] The active agent activator is potassium carbonate.

[0046] The preparation method of the modified waste ash comprises the following steps:

[0047](1) Pretreatment: Grind waste ash from the power plant, pass through a 200-mesh sieve, and dry at 100°C to constant weight to obtain pretreated ash;

[0048] (2) Activation: Mix the pretreated ash and sodium carbonate in a mass ratio of 100:1 to obtain the ball milling raw material. The mass ratio of the ball milling raw material to the zirconia ball is 1:2, and ball mill it at 80 rpm for 80 minutes, then Calcined at 650°C for 2 hours, cooled naturally to 25°C, added an activator of 6% of the mass of the pretreated ash slag, then added water 8 times the mass of the pre...

Embodiment 2

[0056] A solidifying agent for waste ash, prepared from the following raw materials in parts by weight: 55 parts of modified waste ash, 30 parts of modified fly ash, 8 parts of slaked lime, 5 parts of sodium lignosulfonate, and active activator 2 servings.

[0057] The active agent activator is potassium carbonate.

[0058] The preparation method of the modified waste ash comprises the following steps:

[0059] (1) Pretreatment: Grind the waste ash from the power plant, pass it through a 200-mesh sieve, and dry it at 100°C to constant weight to obtain a finely ground ash. Mix the finely ground ash and 12wt% hydrochloric acid at a solid-to-liquid ratio of 1g: 8mL , stirred at 65°C at 200 rpm for 80 minutes, centrifuged at 4000 rpm for 10 minutes, washed the precipitate with deionized water until the washing liquid was neutral, and dried at 100°C to constant weight to obtain pretreated ash;

[0060] (2) Activation: Mix the pretreated ash and sodium carbonate in a mass ratio of...

Embodiment 3

[0068] A solidifying agent for waste ash, prepared from the following raw materials in parts by weight: 55 parts of modified waste ash, 30 parts of modified fly ash, 8 parts of slaked lime, 5 parts of sodium lignosulfonate, and active activator 2 servings.

[0069] The active agent activator is potassium carbonate.

[0070] The preparation method of the modified waste ash comprises the following steps:

[0071] (1) Pretreatment: Grind the waste ash from the power plant, pass it through a 200-mesh sieve, and dry it at 100°C to constant weight to obtain a finely ground ash. Mix the finely ground ash and 12wt% hydrochloric acid at a solid-to-liquid ratio of 1g: 8mL , stirred at 65°C at 200 rpm for 80 minutes, centrifuged at 4000 rpm for 10 minutes, washed the precipitate with deionized water until the washing liquid was neutral, and dried at 100°C to constant weight to obtain pretreated ash;

[0072] (2) Modification: Add the modifier to deionized water to obtain a modifier aqu...

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Abstract

The invention discloses a waste ash curing agent and a preparation method thereof and application of the waste ash curing agent in sludge curing. The waste ash curing agent is prepared from the following raw materials in parts by weight: 50-60 parts of modified waste ash, 25-35 parts of modified fly ash, 5-10 parts of slaked lime, 3-8 parts of sodium lignin sulfonate and 1-3 parts of active activators. According to the waste ash curing agent and the preparation method thereof and application of the waste ash curing agent in sludge curing, the waste ash is modified, the curing agent is preparedfrom the modified waste ash, the obtained curing agent has a remarkable sludge curing effect, the cured sludge is good in freezing and thawing resistance and large in internal friction angle and theengineering soil testing requirement of building rolling can be met.

Description

technical field [0001] The invention relates to the field of engineering technology, in particular to a waste ash solidifying agent, a preparation method and its application in sludge solidification. Background technique [0002] Class I and Class II fly ash of thermal power plants have been widely used, but there are still a large amount of poor quality ash that has not been utilized. A large amount of hoarding not only occupies land, but also generates serious dust in dry weather. Therefore, they are two major pollution sources affecting the urban environment, and using them to produce ecological environment materials is in line with the development direction of circular economy. Rational use of solid waste resources such as fly ash and ash to increase the added value of waste ash can not only turn waste into wealth, reduce land occupation, and reduce pollution, but also bring huge economic benefits to society and enterprises. Greatly mobilize the enthusiasm of enterprise...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F11/00
CPCC02F11/008Y02W30/91
Inventor 陈红元
Owner 福建原野环保科技有限公司