Method for reducing porosity of surface coating of neodymium iron boron permanent magnet material

A permanent magnet material, NdFeB technology, used in the manufacture of permanent magnets, inductors/transformers/magnets, electrical components, etc., can solve the problems of decreased coating adhesion, high porosity, difficult to clean, etc., to reduce the magnetic flux loss, improve coating adhesion, optimize the effect of sealing effect

Inactive Publication Date: 2020-04-17
ARCFL TECHNOLOGY LIMITED
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the manufacture of NdFeB permanent magnet materials is a powder metallurgy process. Like other powder materials, the structure is loose and the porosity is high. During the electroplating process, the solution easily penetrates into the pores and is not easy to clean. The magnetic material is composed of a variety of phases with different electrode potentials, and micro-battery reactions are extremely prone to occur, causing the NdFeB and the coating to corrode laterally during use and storage, resulting in a decrease in the bonding force of the coating, bubbling and peeling of the coating, and the material Pulverization, etc.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] A method for reducing the porosity of the surface coating of NdFeB permanent magnet materials, comprising the steps of:

[0034] 1) Deash the NdFeB permanent magnet material;

[0035] The brand of the permanent magnet is 42H, the specification is 13×5.1×2.2mm, and the grinding chamfer is R≤0.25. The NdFeB permanent magnet material is deashed by ultrasonic cleaning, and the ash is washed in ultrasonic water for 100s, and the vibration frequency of the ultrasonic wave is 1000Hz.

[0036] 2) Soak the NdFeB permanent magnet material in the sealing agent, so that the oxide in the gap of the NdFeB permanent magnet material can be hydrated to form a hydrated oxide to increase the volume of the oxide, thereby sealing the pores, and then Washing with water, wherein the sealing agent is an alcohol amine compound;

[0037] Soak in a solution of 12mL / L triethanolamine at a temperature of 100°C for 18min to complete sealing, and then wash with running water for 60s to remove triet...

Embodiment 2

[0051] A method for reducing the porosity of the surface coating of NdFeB permanent magnet materials, comprising the steps of:

[0052] 1) Deash the NdFeB permanent magnet material;

[0053] The brand of the permanent magnet is 42H, the specification is 13×5.1×2.2mm, and the grinding chamfer is R≤0.25. The NdFeB permanent magnet material is deashed by ultrasonic cleaning, and the ash is washed in ultrasonic water for 90s, and the vibration frequency of the ultrasonic wave is 1200Hz.

[0054] 2) Soak the NdFeB permanent magnet material in the sealing agent, so that the oxide in the gap of the NdFeB permanent magnet material can be hydrated to form a hydrated oxide to increase the volume of the oxide, thereby sealing the pores, and then Washing with water, wherein the sealing agent is an alcohol amine compound;

[0055] Soak in a solution of 10 mL / L triethanolamine at a temperature of 95°C for 20 minutes to complete sealing, and then wash with flowing water for 50 seconds to r...

Embodiment 3

[0069] A method for reducing the porosity of the surface coating of NdFeB permanent magnet materials, comprising the steps of:

[0070] 1) Deash the NdFeB permanent magnet material;

[0071] The brand of the permanent magnet is 42H, the specification is 13×5.1×2.2mm, and the grinding chamfer is R≤0.25. The NdFeB permanent magnet material is deashed by ultrasonic cleaning, and the ash is washed for 120s in the ultrasonic wave, and the vibration frequency of the ultrasonic wave is 800Hz.

[0072] 2) Soak the NdFeB permanent magnet material in the sealing agent, so that the oxide in the gap of the NdFeB permanent magnet material can be hydrated to form a hydrated oxide to increase the volume of the oxide, thereby sealing the pores, and then Washing with water, wherein the sealing agent is an alcohol amine compound;

[0073] Soak in a solution of 15mL / L triethanolamine at a temperature of 100°C for 15min to complete sealing, and then wash with flowing water for 70s to remove tri...

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PUM

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Abstract

The invention discloses a method for reducing porosity of a surface coating of a neodymium iron boron permanent magnet material, belonging to the field of surface treatment of sintered neodymium ironboron permanent magnet materials. The method is characterized by comprising the steps of 1) deashing a neodymium iron boron permanent magnet material; 2) soaking the neodymium iron boron permanent magnet material in a sealant, and then carrying out water washing, wherein the sealant is an alcohol amine compound; 3) sequentially cleaning the wahsed neodymium iron boron permanent magnet material through an oil removal agent and an acid; and 4) activating the neodymium iron boron permanent magnet material, and then carrying out electroplating. According to the method for reducing the porosity ofthe surface coating of the neodymium iron boron permanent magnet material, hole sealing treatment is carried out before electroplating, water is sucked into gaps through capillary action, and oxide inthe gaps generates hydrated oxide through hydration, so that the volume of the oxide is increased, and the gaps are sealed; and furthermore, the porosity of the coating can be reduced, the coating isrelatively smooth and bright, and the magnetic flux loss of the magnet can be reduced.

Description

technical field [0001] The invention discloses a method for reducing the porosity of a surface coating of an NdFeB permanent magnet material, which belongs to the field of surface treatment of sintered NdFeB permanent magnet materials. Background technique [0002] NdFeB permanent magnet materials, known as the "King of Permanent Magnets", have been widely used in various fields such as military, medical and environmental protection since their inception, and are favored by people. However, the manufacture of NdFeB permanent magnet materials is a powder metallurgy process. Like other powder materials, the structure is loose and the porosity is high. During the electroplating process, the solution easily penetrates into the pores and is not easy to clean. The magnetic material is composed of a variety of phases with different electrode potentials, and micro-battery reactions are extremely prone to occur, causing the NdFeB and the coating to corrode laterally during use and st...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C25D7/00C25D5/14C25D5/34H01F41/02
CPCC25D5/14C25D5/34C25D7/001H01F41/026
Inventor 张友亮仉喜峰孙菲菲李军
Owner ARCFL TECHNOLOGY LIMITED
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