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A kind of halogen-free resin composition, flexible printed circuit reinforcing plate containing it and application thereof

A resin composition and printed circuit technology, applied in the field of flexible printed circuit reinforcement boards and halogen-free resin compositions, can solve the problems of unsuitable touch stickiness, achieve excellent storage stability, and meet processing and application requirements. Effect

Active Publication Date: 2021-10-19
GUANGDONG SHENGYI SCI TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the adhesive requires heat-assisted curing, and its tackiness cannot be applied to the preparation of large-scale industrial reinforcement materials.

Method used

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  • A kind of halogen-free resin composition, flexible printed circuit reinforcing plate containing it and application thereof
  • A kind of halogen-free resin composition, flexible printed circuit reinforcing plate containing it and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0058] A halogen-free resin composition, comprising the following components in parts by weight: 50 parts by weight of polyacrylate SG-P3, 10 parts by weight of epoxidized polybutadiene L680, 15 parts by weight of copolyamide M1276F, 5 parts by weight of dicyandiamide Amine, 10 parts by weight of flame retardant SPB-100.

[0059] The halogen-free resin composition is used for the preparation of a reinforcing board for a flexible printed circuit, and the specific method is as follows:

[0060] (1) Mix the halogen-free resin composition with methyl ethyl ketone, and disperse it uniformly by using a ball mill to obtain a uniformly dispersed resin glue with a solid content of 40%;

[0061] (2) Use a coating machine to coat the resin glue solution obtained in step (1) on the surface of a polyimide composite film with a thickness of 50 μm, and the coating thickness is 25 μm; place it at 85° C. and dry for 3 minutes to make the polyimide A partially cured resin layer is formed on th...

Embodiment 2

[0063] A halogen-free resin composition, comprising the following components in parts by weight: 55 parts by weight of polyacrylate SG-708-6, 15 parts by weight of epoxidized polybutadiene L681, 18 parts by weight of copolyamide M995F, 8 parts by weight 4,4'-diaminodiphenyl sulfone and 15 parts by weight of flame retardant OP-935.

[0064] The halogen-free resin composition is used for the preparation of a reinforcing board for a flexible printed circuit, and the specific method is as follows:

[0065] (1) Mix the halogen-free resin composition with toluene, and disperse it uniformly by using a pot mill to obtain a uniformly dispersed resin glue solution with a solid content of 50%;

[0066] (2) Use a coating machine to coat the resin glue solution obtained in step (1) on the surface of a polyimide composite film with a thickness of 75 μm, and the coating thickness is 50 μm; place it at 130° C. and dry for 5 minutes to make the polyimide A partially cured resin layer is forme...

Embodiment 3

[0068]A halogen-free resin composition, comprising the following components in parts by weight: 60 parts by weight of polyacrylate PMS-12-81, 20 parts by weight of epoxidized polybutadiene L682, 25 parts by weight of copolyamide M995F, 10 parts by weight of Diphenylmethanediamine, 20 parts by weight of flame retardant OP-930.

[0069] The halogen-free resin composition is used for the preparation of a reinforcing board for a flexible printed circuit, and the specific method is as follows:

[0070] (1) Mix the halogen-free resin composition with cyclohexanone, and use a sand mill to disperse it evenly to obtain a uniformly dispersed resin glue with a solid content of 60%;

[0071] (2) Use a coating machine to coat the resin glue solution obtained in step (1) on the surface of a polyimide composite film with a thickness of 200 μm, and the coating thickness is 25 μm; place it at 160° C. for 8 minutes to make the polyimide A partially cured resin layer is formed on the surface of...

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Abstract

The invention provides a halogen-free resin composition, a reinforcing board for a flexible printed circuit containing the same and its application. The halogen-free resin composition includes the following components in parts by weight: 50-60 parts by weight of polyacrylate , 10-20 parts by weight of epoxidized polybutadiene, 15-25 parts by weight of copolyamide, 5-10 parts by weight of amine curing agent and 10-20 parts by weight of flame retardant; After compounding, the resin composition is cured to form a stable interpenetrating cross-linked network structure. The reinforcing board for flexible printed circuits prepared by using the halogen-free resin composition has moderate tackiness, excellent storage stability, bonding strength, cohesiveness, heat resistance and flame retardancy, and can fully Meet the processing and application requirements of reinforcing materials in flexible printed circuit boards.

Description

technical field [0001] The invention belongs to the technical field of printed circuits, and in particular relates to a halogen-free resin composition, a flexible printed circuit reinforcing board containing the same and an application thereof. Background technique [0002] In recent years, consumer electronics products have been gradually developing in the direction of thinner and wearable. Flexible printed circuit boards have been widely used in consumer electronics due to their advantages of light weight and small thickness. Flexible printed circuit boards use polymer films as insulating and supporting substrates. They have the characteristics of repeated flexing and bending. They have good flexibility but lack rigidity. Insufficient and difficult to support. Therefore, it is usually necessary to reinforce the flexible printed circuit board at a local position to improve the strength of the plug-in part and improve the operability. [0003] Reinforcement materials commo...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L33/08
CPCC08L2201/02C08L2201/08C08L2201/22C08L2203/206C08L2205/03C09J11/06C09J133/064C09J133/14C09J2203/326C09J2479/086C09J7/25C09J7/29C09J7/30C09J2301/122H05K1/0281C08L47/00C08L77/00C08K5/5399C08K5/5313
Inventor 左陈茹敬宏伍宏奎
Owner GUANGDONG SHENGYI SCI TECH