Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

A kind of preparation technology of hexamethylenediamine based on cyclohexene

A preparation process and technology of cyclohexene, which are applied in the direction of reductive alkylation preparation, ozone oxidation preparation of carboxylic acid, catalyst activation/preparation, etc., can solve the problems of high toxicity of adiponitrile, dependence on imports, high price, etc. Selectivity and catalyst stability, effect of route cleaning

Active Publication Date: 2021-05-25
DALIAN INST OF CHEM PHYSICS CHINESE ACAD OF SCI
View PDF10 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The raw material adiponitrile in the route of industrialized hydrogenation of adiponitrile to hexamethylenediamine is highly toxic and depends on imports and the price is high

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • A kind of preparation technology of hexamethylenediamine based on cyclohexene
  • A kind of preparation technology of hexamethylenediamine based on cyclohexene
  • A kind of preparation technology of hexamethylenediamine based on cyclohexene

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0060] Cyclohexene oxidation is adipaldehyde in embodiment 1' microchannel reactor

[0061] 50 g of cyclohexene and 116 g of acetone were mixed to prepare a cyclohexene solution with a mass concentration of 30%, and 7.89 g of vanadyl acetylacetonate was added to the cyclohexene solution, and the mixed solution was obtained after ultrasonic vibration and uniform mixing;

[0062] A pump is used to inject the mixed solution into the microchannel reactor, and the flow rate of the mixed solution is 10g / min. At the same time, the mixed gas is injected into the microchannel reactor through a mass flow meter, and the flow rate of the mixed gas is controlled to be 15.1L / min. Composed of ozone, the ozone concentration is 100mg / L;

[0063] The reaction temperature in the microchannel reactor was 10° C., the reaction pressure was 0.10 MPa, and the materials were collected after 10 minutes of reaction, and analyzed by gas chromatography.

Embodiment 2

[0064] Cyclohexene is oxidized to adipaldehyde in embodiment 2'-11' microchannel reactor

[0065] Adopt the described operation of embodiment 1 ', change the pressure of reaction, solvent, catalyzer and temperature of reaction to react, concrete reaction condition and result are shown in Table 1.

[0066] Table 1 Reaction conditions and result list of cyclohexene oxidation to adipaldehyde in microchannel reactor

[0067]

[0068]

[0069] As can be seen from Table 1, in the preparation process provided by the application, adipaldehyde generally has higher selectivity, and the selectivity of adipaldehyde can reach more than 53.8%, the highest can reach 91.2%, and the conversion rate of cyclohexene can reach 35.2% above, up to 100%.

Embodiment 1-10

[0070] The preparation of embodiment 1-10 basic molecular sieve

[0071] Step 1): dissolving an alkali metal salt in water to obtain a precursor solution with a concentration of 0.2-0.6 mol / L, the alkali metal salt being selected from one of potassium nitrate, rubidium nitrate, and cesium nitrate;

[0072] Step 2): Weighing 30g molecular sieves, the molecular sieves are selected from one of NaX, NaY, KL, and NaBeta molecular sieves;

[0073] Step 3) According to the solid-to-liquid ratio of 10:1, use the alkali metal ion precursor solution in step 1) to carry out ion exchange on the molecular sieve weighed in step 2), exchange at 80°C for 4 hours, suction filter and wash 1. After drying, the obtained solid is roasted at 550° C. in a muffle furnace for 6 hours;

[0074] Step 4) Change the object of ion exchange in step 3) from the molecular sieve weighed in step 2) to the molecular sieve obtained after roasting, repeat step 3) twice to obtain a basic molecular sieve sample, an...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

No PUM Login to View More

Abstract

The present application discloses a process for preparing hexamethylenediamine based on cyclohexene, which includes: passing the mixed solution containing cyclohexene and catalyst I and the mixed gas containing ozone into the reactor I to react to prepare adipaldehyde, Wherein, the catalyst I is a transition metal complex catalyst; the obtained adipaldehyde, ammonia, and hydrogen are passed into the reactor II containing the catalyst II to generate hexamethylenediamine under reaction conditions, wherein the catalyst II Metal catalyst supported by basic molecular sieve. Using cyclohexene as raw material, hexamethylenediamine is prepared by oxidation and amination, avoiding the use of highly toxic raw material adiponitrile, using ozone as oxidant, heterogeneous catalyst can prepare adipaldehyde with high selectivity, and further using basic molecular sieve The supported metal catalyst uses the confinement effect of molecular sieves to effectively improve the selectivity of the target product and the stability of the catalyst, and the route is clean and environmentally friendly.

Description

technical field [0001] The application relates to a preparation process of hexamethylenediamine based on cyclohexene, which belongs to the field of chemical industry. Background technique [0002] The production technologies of hexamethylenediamine mainly include adiponitrile method, hexanediol method and caprolactam method. At present, almost all hexamethylenediamine is prepared by hydrogenation of adiponitrile, and the production methods of adiponitrile include catalytic amination of adipic acid, electrolytic dimerization of acrylonitrile and butadiene method. [0003] Domestic adiponitrile is completely dependent on imports, and its price has remained high, seriously affecting the economic benefits and international market competitiveness of my country's nylon industry, and restricting the development of my country's nylon 66 and related industries. Therefore, the development of new technologies for the preparation of hexamethylenediamine has become an urgent problem in ...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Patents(China)
IPC IPC(8): C07C209/26C07C211/12C07C51/34C07C55/14B01J29/12B01J29/14B01J29/62B01J29/74B01J37/02B01J37/30
CPCB01J29/123B01J29/126B01J29/143B01J29/62B01J29/7415B01J37/0207B01J37/30B01J2229/18C07C51/34C07C209/26C07C211/12C07C55/14
Inventor 袁扬扬许磊李沛东赵晓炜陆标史鑫
Owner DALIAN INST OF CHEM PHYSICS CHINESE ACAD OF SCI
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic, Popular Technical Reports.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap|About US| Contact US: help@patsnap.com