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Coal-based activated carbon production process

A technology of coal-based activated carbon and production process, applied in inorganic chemistry, non-metallic elements, carbon compounds, etc., can solve the problems of poor product mechanical strength, long preparation process, complicated process, etc., to simplify production steps, reduce production costs, The effect of good market competitiveness

Inactive Publication Date: 2020-05-05
WUHAN COSRED SCI & TECH LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0007] In order to solve the technical problems of the existing coal-based activated carbon such as long preparation process, complex process, high cost, and poor mechanical strength of the product, the present invention provides a preparation method of activated carbon. The activation and reduction are completed in one step, and carbonization and molding units are omitted. Simplify the process flow to obtain high-quality activated carbon, and the by-product reduced pellets can be recycled to maximize the utilization of resources, aiming to simplify the preparation process, reduce the preparation cost, improve the adsorption performance and mechanical strength of the prepared activated carbon, and improve the competition of the process force

Method used

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  • Coal-based activated carbon production process

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Effect test

Embodiment 1

[0032] Embodiment 1: a kind of activated carbon production technology that uses granular bituminous coal and hematite lump ore, its main production steps are:

[0033] (1) Use 5-20mm bituminous coal particles, wherein the volatile fraction of bituminous coal is 25%, and the fixed carbon is 45%;

[0034] (2) Use 5-30mm hematite natural lump ore, of which the total iron is 58%;

[0035] (3) mix bituminous coal particles and natural lump ore in a weight ratio of 60:100;

[0036] (4) The distributing facility sends the above-mentioned mixed material into the multi-chamber vertical furnace, and runs from top to bottom. The temperature of the carbonization section is 300-800°C, and the temperature of the activation section is 1000-1100°C; the residence time of the charge in the activation section is 10-12 hours; the charge is finally discharged from the lower cooling area to 50-100°C;

[0037] (5) Carry out magnetic separation and separation of mixed material etc., receive gac and...

Embodiment 2

[0038] Embodiment 2: a kind of production technology that uses pulverized coal bituminous coal and magnetite cold-pressed pelletized activated carbon, its main production steps are:

[0039] (1) Use bituminous coal powder less than 50 mesh and content greater than 90%, wherein the volatile content of bituminous coal is 25%, and the fixed carbon is 45%. Bituminous coal is extruded into briquette;

[0040] (2) use Magnetite cold-pressed pellets, of which total iron is 68%;

[0041] (3) Mixing briquette and pellet weight ratio 50:100;

[0042] (4) The distributing facility sends the above-mentioned mixed material into the multi-chamber vertical furnace, and runs from top to bottom. The temperature of the carbonization section is 300-800°C, and the temperature of the activation section is 1000-1100°C; the residence time of the charge in the activation section is 10-12 hours; the charge is finally discharged from the lower cooling area to 50-100°C;

[0043] (5) magnetic separ...

Embodiment 3

[0044] Embodiment 3: a kind of production technology that uses anthracite particle and iron oxide skin pellet activated carbon, its main production steps are:

[0045] (1) Use 5-20mm anthracite particles, 10% volatile matter and 80% fixed carbon;

[0046] (2) use Iron oxide cold-pressed pellets, the total iron is 71%;

[0047] (3) mixing coal briquette and pellet weight ratio 70:100;

[0048](4) The distributing facility sends the above-mentioned mixed materials into the multi-chamber vertical furnace, and runs from top to bottom. The temperature of the carbonization section is 300-800°C, and the temperature of the activation section is 1100-1200°C; the residence time of the charge in the activation section is 12-14 hours; the charge is finally discharged from the lower cooling area to 50-100°C;

[0049] (5) Carry out magnetic separation and separation of mixed material etc., receive gac and sponge iron, the productive rate of gac is 70%, the iodine adsorption value is 550...

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Abstract

The invention discloses a coal-based activated carbon production process which comprises the following steps: a uniform mixing step: uniformly mixing iron oxide and coal to obtain a uniform mixture; acarbonization step: heating the uniformly mixed material to 300-850 DEG C, and carbonizing the coal to generate carbon; and an activation step: raising the temperature to 1,000-1,200 DEG C after thecarbonization step, enabling one part of the carbon generated in the carbonization step to react with the iron oxide to generate CO2 gas and elemental iron, and activating the other part of the carbonby taking the CO2 gas as an activating agent to generate the activated carbon. According to the process disclosed by the invention, a coal-based shaft furnace used in a reduced iron production process is used for producing activated carbon (referred to as a vertical furnace in the invention); carbonization and activation steps in the activated carbon production process are set in the same device,and the CO2 gas generated by reduction of iron oxide is used as an activating agent of coal and carbon is used as a reducing agent of the iron oxide, so that the working conditions of the two are highly coupled, two products are produced simultaneously, the production efficiency is effectively improved, and the production cost is reduced.

Description

technical field [0001] The invention relates to the technical field of activated carbon production, in particular to a coal-based activated carbon production process. Background technique [0002] Activated carbon is a carbonaceous porous material with a developed pore structure and a large specific surface area. It has excellent adsorption properties and good chemical stability. It is widely used in food, pharmaceutical, medical and health and environmental protection and other fields. [0003] Commercial activated carbon products are mainly coal-based activated carbon, wood-based activated carbon and fruit shell activated carbon, and other carbon-containing materials (such as activated carbon prepared from chemical and domestic waste) are mostly used in experimental research and special purposes. Compared with activated carbon prepared from wood chips, husks, and petroleum coke, coal is a cheap and stable source of activated carbon production raw material. Activated carbon...

Claims

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Application Information

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IPC IPC(8): C01B32/33C01B32/336C21B13/00
CPCC21B13/0066C01B32/33C01B32/336
Inventor 唐恩李建涛周强李森蓉陈泉锋汪朋付邦豪
Owner WUHAN COSRED SCI & TECH LTD