Method and device for preparing low-carbon olefin from petroleum hydrocarbon

A technology of low-carbon olefins and petroleum hydrocarbons, which is applied in the direction of hydrocarbon cracking, petroleum industry, and hydrocarbon oil treatment, etc., and can solve problems such as low yield of low-carbon olefins, insufficient crude oil gasification, and easy coking

Active Publication Date: 2020-05-08
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0010] The purpose of the present invention is to provide a method and device for preparing low-carbon olefins from petroleum hydrocarbons in order to overcome the problems of insufficient crude oil gasification, easy coking in the cracking process, and low yield of low-carbon olefins in the prior art. The method can improve the cracking efficiency of crude oil, reduce its coking phenomenon during cracking, prolong the operation period, and simultaneously increase the yield of low-carbon olefins in the product

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  • Method and device for preparing low-carbon olefin from petroleum hydrocarbon
  • Method and device for preparing low-carbon olefin from petroleum hydrocarbon
  • Method and device for preparing low-carbon olefin from petroleum hydrocarbon

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Embodiment 1

[0065] This embodiment is used to provide a device for producing light olefins by vacuum cracking of petroleum hydrocarbons.

[0066] Such as figure 1As shown, the device includes a hydrogenation unit, a cracking unit connected to the hydrogenation unit, a heat exchange unit connected to the cracking unit, a separation unit connected to the heat exchange unit, and a decompression unit connected to the separation unit.

[0067] In this embodiment, the hydrogenation unit is the first hydrogenation reactor 12 .

[0068] The cracking unit includes a cracking furnace 4, a first cyclone separator 5, a second hydrogenation reactor 10 and a second cyclone separator 11, and the cracking furnace 4 includes a convection section first tube group 1 and a convection section arranged in sequence along the fluid direction. The second tube group 2 and the radiation section 3 connected to the second tube group 2 of the convection section. The outlet of the first hydrogenation reactor 12 is co...

Embodiment 2

[0072] This embodiment is used to provide a kind of method that adopts petroleum hydrocarbon to prepare light olefin, and this method comprises:

[0073] (1) Send the dehydrated and desalted crude oil to the first hydrotreater for hydroprocessing to obtain refined crude oil. The catalyst used is Co-Ni-Mo / Al 2 o 3 , the hydrogenation temperature is 270°C, the hydrogenation pressure is 2.6MPa, the hydrogen-to-oil ratio is 3.0, and the volumetric space velocity of crude oil is 2.0h -1 , The hydrogenation rate of monoene is 95%. The hydrotreated refined crude oil is mixed with naphtha to form a first mixture, wherein the weight ratio of refined crude oil to naphtha is 90:10.

[0074] (2) The first mixture is preheated in the first pipe group 1 of the convection section of the cracking furnace 4, and mixed with superheated steam for gasification to obtain the gasified first mixture, and the weight ratio of superheated steam to the first mixture is 0.75: 1. The gasified first m...

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Abstract

The invention relates to the field of preparation of low-carbon olefins from petroleum hydrocarbons, and discloses a method and a device for preparing low-carbon olefins from petroleum hydrocarbons. The method comprises: carrying out first hydrotreatment on crude oil to obtain refined crude oil, and mixing the refined crude oil and liquid-state hydrocarbon to form a first mixture; gasifying the first mixture under a reduced pressure condition to obtain a gasified first mixture, and carrying out primary cyclone separation on the gasified first mixture to obtain a first steam phase and a first liquid phase; carrying out secondary hydrogenation treatment on the first liquid phase to obtain a refined first liquid phase, mixing the refined first liquid phase and liquid-state hydrocarbon to forma second mixture, gasifying the second mixture, and carrying out secondary cyclone separation to obtain a second steam phase; and combining the first steam phase and the second steam phase, crackingto obtain cracked gas, and separating the cracked gas to obtain low-carbon olefin. According to the method, the cracking efficiency of crude oil can be improved, the coking phenomenon during crackingis reduced, the operation period is prolonged, and the yield of low-carbon olefins in the product is increased.

Description

technical field [0001] The invention relates to the field of preparing low-carbon olefins from petroleum hydrocarbons, in particular to a method and device for preparing low-carbon olefins by vacuum cracking of petroleum hydrocarbons. Background technique [0002] Low-carbon olefins usually refer to the general term of unsaturated hydrocarbons with carbon four or less, mainly including ethylene, propylene, isobutylene, butadiene and other organic chemical raw materials with high economic value. With the development of my country's economy, the demand for these organic chemical raw materials is increasing year by year. Although the production scale of low-carbon olefins is also increasing year by year, it cannot meet the growing demand. [0003] For a long time, my country has been preparing low-carbon olefin products from naphtha. However, in recent years, with the massive exploitation of associated gas in oilfields in the Middle East and shale gas in the United States, the...

Claims

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Application Information

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IPC IPC(8): C10G69/02C07C4/04C07C11/04C07C11/06C07C11/167
CPCC07C4/04C10G69/02C07C11/04C07C11/06C07C11/167
Inventor 李蔚石莹周丛蒋冰张兆斌刘俊杰张利军王国清
Owner CHINA PETROLEUM & CHEM CORP
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