A gas content evaluation method for highly mature-over-mature shale based on alkane carbon isotope inversion
A shale gas content and carbon isotope technology, applied in the field of oil and gas exploration, can solve the problems of high cost, limited number of cores, and high cost of experiments, and achieve the effects of mature experimental methods, improved accuracy, and great economic advantages
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[0045] The technical solution provided by the present invention is based on the principle that carbon isotope inversion is closely related to the secondary cracking of residual liquid hydrocarbons in shale.
[0046]The carbon isotopes of alkane gas in natural gas have a certain arrangement according to the relationship between the carbon numbers in their molecules:
[0047] (1) If the number of carbon atoms in the alkane gas increases, δ 13 The value of C increases sequentially (δ 13 C 甲烷 13 C 乙烷 13 C 丙烷 13 C 丁烷 ) is called the positive carbon isotope series, which is a characteristic of alkane gas of organic origin;
[0048] (2) If the number of carbon atoms in the alkane gas increases, δ 13 The value of C decreases in turn (δ 13 C 甲烷 >δ 13 C 乙烷 >δ 13 C 丙烷 >δ 13 C 丁烷 ) is called the negative carbon isotope series.
[0049] The irregular increase or decrease that does not follow the above two rules is called carbon isotope inversion, which can be referred to as ...
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