Preparation method of anti-puncture glove for hot-line working
A live working and anti-piercing technology, which is applied in the field of polymer materials, can solve the problems of inability to guarantee safe operation, rubber is not resistant to aging, and short service life, so as to reduce the possibility of two-phase interface defects and damage, Good electrical performance, the effect of improving the strength of the body
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Embodiment 1
[0019] (1) Add 33 parts of isocyanate to 25 parts of liquid nitrile rubber and 27 parts of polymer polyol in parts by weight, fill it with dry nitrogen for protection, raise the temperature to 100°C, and keep it warm for 180 minutes to obtain isocyanate-terminated nitrile-butadiene-modified polyurethane Prepolymer; (2) Cool the isocyanate-terminated butyronitrile-modified polyurethane prepolymer to 42°C, then add 18 parts of small molecule chain extender, 2.6 parts of crosslinking agent, 0.30 part of catalyst, heat up to 82°C, and keep warm Stir for 200 minutes, cool down to 36°C, then add 8 parts of chain extender, maintain the temperature at 50°C, and keep it warm for 180 minutes to obtain isocyanate-based nitrile-modified polyurethane; cool the isocyanate-based nitrile-modified polyurethane to 36°C, and perform high-speed shearing , add 1 part of dispersant sodium allyl sulfonate during high-speed shearing process, then add 320 parts of water to emulsify to obtain water-base...
Embodiment 2
[0021](1) Add 20 parts of isocyanate to 25 parts of liquid nitrile rubber and 22 parts of polymer polyol in parts by weight, fill it with dry nitrogen for protection, raise the temperature to 90°C, and keep it warm for 160 minutes to obtain isocyanate-terminated nitrile-butadiene-modified polyurethane Prepolymer; (2) Cool the isocyanate-terminated butyronitrile-modified polyurethane prepolymer to 38°C, then add 6 parts of small molecule chain extender, 0.5 part of crosslinking agent, 0.15 part of catalyst, heat up to 78°C, and keep warm Stir for 120 minutes, cool down to 34°C, add 3.5 parts of chain extender, maintain the temperature at 30°C, and keep warm for 30 minutes to obtain isocyanate-based nitrile-modified polyurethane; cool the isocyanate-based nitrile-modified polyurethane to 34°C, and perform high-speed shearing , add 0.5 parts of dispersant sodium allyl sulfonate during high-speed shearing process, then add 210 parts of water to emulsify to obtain water-based nitril...
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