Composition for controlling Macdunnoughia crassisigna Warren and application thereof
A technology of Spodoptera frugiperda and a composition, applied in the field of biological control, can solve problems such as pollution, and achieve the effects of reducing reproduction rate, reducing mating frequency and strong specificity
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Embodiment 1
[0021] Embodiment 1 cis-7-dodecene-N, the preparation of N-dimethylcarbamate:
[0022] Synthetic route such as Figure 4 As shown, put 0.5g Z7-12:OH (2.71mmol) into a 100mL round-bottom single-necked flask, add 15mL of redistilled N,N-dimethylformamide (DMF), and bind 0.56g (4.07mmol) Acid K 2 CO 3 . A solution of dimethylcarbamoyl chloride (4.07 mmol) in DMF was slowly added dropwise. After dropping, react overnight at room temperature, and monitor with TLC during the reaction. The reaction was quenched with deionized water, extracted with ethyl acetate (10mL×3), the extract was washed with saturated brine (15mL×3), dried over anhydrous magnesium sulfate, concentrated under reduced pressure, and the crude product was purified by silica gel column chromatography to obtain cis-7-dodecene-N,N-dimethylcarbamate.
[0023] cis-7-dodecene-N,N-dimethylcarbamate (Z)-dodec-7-en-1-yldimethylcarbamate, light yellow oily liquid, yield 62%; 1 H NMR (300MHz, CDCl 3 )δ:5.34-5.30(m,2H...
Embodiment 2
[0024] Embodiment 2 field biological activity determination test
[0025] Lure preparation:
[0026] The n-hexane solution containing the sex pheromone is added in proportion to the anti-mouth rubber head to obtain the sex pheromone lure core (SP) containing silver spodoptera. Then add different sex pheromone analog components to the lure. After the solution has completely penetrated into the trans rubber head, add 100 μL of n-hexane. lure. Each of the above-mentioned lure treatments was set up with 5 repetitions. As a control, the lure blank treatment (CK) and the barrel trap containing three live female silver-cutting moths (PE) that had not mated for 3 to 5 days were 5 each. repeat.
[0027] The prepared lure cores were placed in barrel traps and placed in areas where silver armyworm occurred seriously. In order to further illustrate the feasibility of the present embodiment, 22 specific formulas are provided in table 1:
[0028] Table 1 Treatment numbers of different ...
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