The invention discloses a stereoselective synthetic method of tea geometrid sex pheromone and relates to a stereoselective synthetic method of propylene epoxide compounds. The tea geometrid sex pheromone is I [dextrorotation-(3Z, 9Z, 6R, 7S)-6, 7-epoxy octadecadiene] and an enantiomer II [sinistrogyration-(3Z, 9Z, 6S, 7R)-6, 7-epoxy octadecadiene]. According to the invention provides the stereoselective synthetic method of tea geometrid sex pheromone provided by the invention, cis-2-butene-1, 4-glycol (1) is taken as raw material, the efficiency, the yield and the enantioselectivity are high, the operation and the separation are simple, the yield is high, the using reagents are all commonly used, so that the tea geometrid sex pheromone is cheap and easy to obtain, a protecting group does not need to be used, and the preparation procedures are few, so that the tea geometrid sex pheromone is suitable for batch production.