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Multiphase reinforced nickel-cobalt-based high-chromium wear-resistant high-temperature alloy and preparation method

A high-temperature alloy, nickel-cobalt-based technology, used in metal rolling, metal rolling, metal processing equipment, etc., can solve the problems of difficult welding and processing of materials, difficult to meet performance requirements, unfavorable wear resistance, etc., and achieve excellent resistance. Effects of corrosion/oxidation properties, good microstructure stability and hot workability, excellent hardness and wear resistance

Active Publication Date: 2020-07-31
HUANENG POWER INT INC +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, higher carbon content often makes welding and processing of materials difficult, thus limiting its application
At the same time, the addition of too high carbon content will lead to significant embrittlement of the material, which is not conducive to the further improvement of wear resistance
In addition, the strength of the above-mentioned alloys is often low at high temperatures, and it is difficult to meet the performance requirements of ultra-supercritical steam turbine rotors, blades and other components for materials.

Method used

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  • Multiphase reinforced nickel-cobalt-based high-chromium wear-resistant high-temperature alloy and preparation method
  • Multiphase reinforced nickel-cobalt-based high-chromium wear-resistant high-temperature alloy and preparation method
  • Multiphase reinforced nickel-cobalt-based high-chromium wear-resistant high-temperature alloy and preparation method

Examples

Experimental program
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Effect test

Embodiment 1

[0034] By increasing the Cr content, excellent high-temperature corrosion / oxidation resistance can be obtained, and at the same time, the precipitation of a large amount of а-Cr phase in the grain can be promoted to improve the strength of the alloy. The alloy is smelted in a vacuum induction furnace, and the obtained alloy includes: C: 0.07%, Cr: 23%, Co: 20-25%, Mn: 0.3%, Si: 0.3%, Mo: 3.0%, W: 3.0%, Ti: 5.8%, Al: 3.0%, Zr: 0.03%, B: 0.02%, and the balance is Ni.

[0035] Heat the alloy with the furnace at a rate of 10°C / min to 1020°C for 0.5 hours, and then continue to heat up with the furnace to a range of 90°C below the γ' melting temperature for 4.0 hours, and air cool to room temperature after completion;

[0036] The alloy was heated with the furnace at a rate of 60 °C / min to 760 °C for 8 hours, then cooled to room temperature, then rapidly heated to 860 °C at the same rate for 2 hours, and finally cooled to room temperature.

[0037] figure 1 and figure 2It is the...

Embodiment 2

[0039] By increasing the Cr content, excellent high-temperature corrosion / oxidation resistance can be obtained, and at the same time, the precipitation of a large amount of а-Cr phase in the grain can be promoted to improve the strength of the alloy. The alloy is smelted in a vacuum induction furnace, and the obtained alloy includes: C: 0.07%, Cr: 23%, Co: 20-25%, Mn: 0.3%, Si: 0.3%, Mo: 3.0%, W: 3.0%, Ti: 5.8%, Al: 3.0%, Zr: 0.03%, B: 0.02%, and the balance is Ni.

[0040] The alloy was homogenized at 1200°C for 24 hours, followed by high-temperature rolling at 70°C below the γ' melting temperature, with a deformation of 10% per pass, and returned to the furnace for 20 minutes after rolling. The final total deformation of the alloy was 50%. In order to avoid problems such as cracking of alloy ingots caused by transverse shear stress during alloy rolling, high-temperature hot rolling is carried out by sheathing, and the sheathing material is 304 stainless steel sheet with a t...

Embodiment 3

[0044] A multiphase strengthened nickel-cobalt-based high-chromium wear-resistant superalloy, including C: 0.01%, Cr: 27%, Co: 20%, Mn: 0.5%, Si: 0.1%, Mo: 1.0% by mass percentage , W: 2.5%, Ti: 5.5%, Al: 2.0%, Zr: 0.03%, B: 0.02%, and the balance is Ni.

[0045] The preparation method of the above-mentioned multiphase strengthened nickel-cobalt-based high-chromium wear-resistant superalloy comprises the following steps:

[0046] 1) Melting: alloy ingots are obtained by vacuum melting;

[0047] 2) Homogenize the alloy ingot obtained in step 1) at 1180°C for 72 hours, and then carry out high-temperature rolling at 30°C below the γ' melting temperature, with a deformation of 5% in each pass. After the preparation is completed, return to the furnace and keep warm for 10 minutes. The total deformation of the final alloy is not less than 50%. And the high-temperature rolling is carried out by sheathing, and the sheathing material is a 304 stainless steel sheet with a thickness o...

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Abstract

The invention discloses a multiphase reinforced nickel-cobalt-based high-chromium wear-resistant high-temperature alloy and a preparation method. The alloy comprises the following compositions by masspercentage: less than or equal to 0.08% of C, 23-27% of Cr, 20-25% of Co, less than or equal to 0 .5% of Mn, less than or equal to 0.5% of Si, 1.0-3.0% of Mo, 2.5-3.5% of W, 5.5-6.5% of Ti, 2.0-3.0%of Al, less than or equal to 0.03% of Zr, less than or equal to 0.03% of B and balance of Ni. The material obtained by the invention consists of four phases: austenite, Ni3Al (gamma'), a-Cr and grainboundary M23C6 carbide, wherein the volume fraction of the gamma's reinforced phase in the crystal and a-Cr phase is not less than 25 and 20% respectively, and a-Cr is uniformly distributed in the crystal in needle-like and massive morphologies. The alloy prepared by the invention has excellent high-temperature strength and good corrosion resistance.

Description

technical field [0001] The invention belongs to the field of high-temperature alloys, and specifically relates to a multiphase-strengthened nickel-cobalt-based high-chromium wear-resistant superalloy and a preparation method thereof, and is especially suitable for rotors and blades of ultra-supercritical coal-fired units, high-temperature gas-cooled reactors of nuclear power units, and chemical plant production. Performance requirements for high temperature components such as hydrogen reformer tubes. Background technique [0002] With the increasingly harsh service environment, the performance requirements of high-temperature components for materials continue to increase. For example, with the continuous increase of steam parameters of coal-fired units, the requirements for the strength and performance of steam turbine rotors, blades and other components have not been increased. At the same time, the high-temperature service environment has continuously proposed new adjustm...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C30/00C22F1/00B21B3/00B21B37/56B21B45/00
CPCB21B3/00B21B37/56B21B45/004C21D2211/001C21D2211/004C22C19/055C22C30/00C22F1/10
Inventor 严靖博杨征谷月峰袁勇孙宇明张兴营刘茜
Owner HUANENG POWER INT INC