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Resin modifier, resin composition, molding, and molded article

A resin modifier and resin composition technology, applied in the field of resin modifiers, can solve the problems of poor wettability, poor adhesion, low solubility and high crystallinity, and achieve good adhesion, wettability and The effect of excellent adhesion, good coatability and printability

Active Publication Date: 2020-09-29
SANYO CHEM IND LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] On the other hand, thermoplastic resins, especially polyolefin resins, which are so-called non-polar and extremely inert polymer substances having no polar groups in their molecules, have high crystallinity and remarkably low solubility in solvents.
Therefore, there are problems such as adhesion and coating properties, such as poor wettability and adhesion to paints, printing inks, and adhesives, and problems such as inapplicability without post-processing surface treatment.

Method used

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  • Resin modifier, resin composition, molding, and molded article
  • Resin modifier, resin composition, molding, and molded article
  • Resin modifier, resin composition, molding, and molded article

Examples

Experimental program
Comparison scheme
Effect test

manufacture example 1

[0281] [Single-terminal acid-modified ethylene-propylene random copolymer (a-1)]

[0282] Put the low molecular weight ethylene-propylene random copolymer obtained by the thermal degradation method into a stainless steel pressure-resistant reaction vessel equipped with a stirrer, a thermometer, a heating and cooling device, a nitrogen gas introduction pipe and a decompression device [the ethylene-propylene random copolymer (Propylene content = 33 mol%) was obtained by performing thermal degradation at 410±0.1° C. under a nitrogen atmosphere (80 mL / min) for 16 minutes. Mn: 3,900, average number of double bonds per molecule: 1.0] 90 parts, 10 parts of maleic anhydride, and 30 parts of xylene were uniformly mixed, replaced with nitrogen, and heated to 200° C. while stirring under airtight conditions. It melted and reacted at this temperature for 10 hours. Next, under reduced pressure (below 0.013MPa), excess maleic anhydride and xylene were distilled off at 200°C for 3 hours to...

manufacture example 2

[0284] [Single-terminal acid-modified ethylene-propylene random copolymer (a-2)]

[0285] Put the low molecular weight ethylene-propylene random copolymer obtained by the thermal degradation method into a stainless steel pressure-resistant reaction vessel equipped with a stirrer, a thermometer, a heating and cooling device, a nitrogen gas introduction pipe and a decompression device [the ethylene-propylene random copolymer (Propylene content = 52 mol%) was obtained by performing thermal degradation at 410±0.1° C. under nitrogen (80 mL / min) for 16 minutes. Mn: 3,900, average number of double bonds per molecule: 1.0] 90 parts, 10 parts of maleic anhydride, and 30 parts of xylene were uniformly mixed, replaced with nitrogen, and heated to 200° C. while stirring under airtight conditions. It melted and reacted at this temperature for 10 hours. Next, under reduced pressure (below 0.013MPa), excess maleic anhydride and xylene were distilled off at 200°C for 3 hours to obtain a sin...

manufacture example 3

[0287] [Single-end acid-modified 1-butene-propylene random copolymer (a-3)]

[0288] Put the low molecular weight 1-butene-propylene random copolymer obtained by the thermal degradation method into a stainless steel pressure-resistant reaction vessel equipped with a stirrer, a thermometer, a heating and cooling device, a nitrogen gas introduction pipe and a decompression device [the 1-butene - Propylene random copolymer (propylene content = 82 mol %) obtained by thermal degradation at 410±0.1° C. under nitrogen (80 mL / min) for 16 minutes. Mn: 3,900, average number of double bonds per molecule: 1.0] 90 parts, 10 parts of maleic anhydride, and 30 parts of xylene were uniformly mixed, replaced with nitrogen, and heated to 200° C. while stirring under airtight conditions. It melted and reacted at this temperature for 10 hours. Next, under reduced pressure (below 0.013MPa), excess maleic anhydride and xylene were distilled off at 200°C for 3 hours to obtain a single-terminal acid...

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Abstract

The present invention relates to a resin modifier (Y) containing a block polymer (X) having blocks of a hydrophobic polymer (a) and blocks of a hydrophilic polymer (b) as constituent units thereof, the orientation index (omega) described below of the block polymer (X) being 1.5-15. Orientation index (omega) = (beta) / (alpha), where (alpha) is the weight ratio [([alpha]b) / ([alpha]a)] of the hydrophilic polymer (b) and the hydrophobic polymer (a) in the block polymer (X), and (beta) is the weight ratio [([beta]b) / ( [beta]a)] of the hydrophilic polymer (b) and the hydrophobic polymer (a) determined by reflective IR measurement when the block polymer (X) is heat-melted and pressed to a thickness of 500 [mu]m.

Description

technical field [0001] The present invention relates to resin modifiers. Specifically, the present invention relates to a resin that imparts excellent wettability and adhesiveness (coatability) to a thermoplastic resin with respect to paints, printing inks, adhesives, etc., without impairing the mechanical properties of the thermoplastic resin. Modifier. [0002] The wettability in the present invention refers to the affinity for paint, printing ink, adhesive, etc., and is evaluated by the wetting tension described later. Background technique [0003] Thermoplastic resins such as polyolefin resins are excellent in moldability, rigidity, heat resistance, chemical resistance, light weight, and electrical insulation, and are widely used as films, fibers, hollow fiber membranes, and other molded products in various shapes . [0004] On the other hand, thermoplastic resins, especially polyolefin resins, which are so-called non-polar and extremely inert polymer substances havin...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08G81/02C08L87/00C08L101/00
CPCC08G81/025C08L53/00C08L23/00C08L101/00C08L81/02C08L87/00C08G81/021C08L23/12C08L2205/06C08L2207/10
Inventor 长谷川真平田中友平
Owner SANYO CHEM IND LTD