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Preparation method and application of single crystal GeSe triangular nanosheet array material

A nanosheet array and triangular technology, which is applied in the field of preparation of single crystal GeSe triangular nanosheet array materials, can solve the problems of limiting the application of GeSe nanomaterials and further breakthroughs

Inactive Publication Date: 2020-11-17
SICHUAN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This greatly limits the application and further breakthrough of GeSe nanomaterials in optical and optoelectronic devices.

Method used

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  • Preparation method and application of single crystal GeSe triangular nanosheet array material
  • Preparation method and application of single crystal GeSe triangular nanosheet array material
  • Preparation method and application of single crystal GeSe triangular nanosheet array material

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] (1) Cleaning of growth substrate and loading tray

[0026] The Si substrate (50*25*0.8 mm) was used as the growth substrate of the GeSe triangular nanosheet array, and two pieces of Al 2 o 3 Ceramic sheets (10*10*0.5 mm) were used as the first loading plate and the second loading plate respectively, and the growth substrate and the loading plate were respectively washed with deionized water, acetone, deionized water, ethanol, deionized Water ultrasonic vibration cleaning to completely remove the dirt on it, then soak the Si substrate in 10% hydrofluoric acid aqueous solution for 5 min, after the immersion time expires, rinse the Si substrate with deionized water to remove the hydrofluoric acid on the surface of the substrate, and then Finally, blow dry the above-mentioned growth substrate and the loading plate with a nitrogen gun;

[0027] (2) Growth of single crystal GeSe triangular nanosheet array material

[0028] ① Spread the GeSe powder 3 on the first loading tr...

Embodiment 2

[0031] (1) Cleaning of growth substrate and loading tray

[0032] The Si substrate (50*25*0.8 mm) was used as the growth substrate of the GeSe triangular nanosheet array, and two pieces of Al 2 o 3 Ceramic sheets (10*10*0.5 mm) were used as the first loading plate and the second loading plate respectively, and the growth substrate and the loading plate were respectively washed with deionized water, acetone, deionized water, ethanol, deionized Water ultrasonic vibration cleaning to completely remove the dirt on it, then soak the Si substrate in 10% hydrofluoric acid aqueous solution for 5 min, after the immersion time expires, rinse the Si substrate with deionized water to remove the hydrofluoric acid on the surface of the substrate, and then Finally, blow dry the above-mentioned growth substrate and the loading plate with a nitrogen gun;

[0033] (2) Growth of single crystal GeSe triangular nanosheet array material

[0034]① Spread 0.085 mg of GeSe powder 3 on the first loa...

Embodiment 3

[0037] (1) Cleaning of growth substrate and loading tray

[0038] The mica substrate (50*25*0.5 mm) was used as the growth substrate of the GeSe triangular nanosheet array, and two pieces of Al 2 o 3 Ceramic sheets (10*10*0.5 mm) were used as the first loading plate and the second loading plate respectively, and the growth substrate and the loading plate were respectively cleaned with deionized water, ethanol, and deionized water by ultrasonic oscillation until completely Remove the dirt on it, then soak the Si substrate in 10% hydrofluoric acid aqueous solution for 5 min, rinse the Si substrate with deionized water after the expiration of the soaking time to remove the hydrofluoric acid on the substrate surface, and then place the Si substrate through the aforementioned treatment Dry the growth substrate and loading tray with a nitrogen gun;

[0039] (2) Growth of single crystal GeSe triangular nanosheet array material

[0040] ① Spread the GeSe powder 3 on the first loadi...

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Abstract

The invention belongs to the technical field of semiconductor nano materials, and particularly relates to a preparation method and application of a single-crystal GeSe triangular nanosheet array material. The method adopts physical vapor deposition (PVD), and comprises the following steps: (1) cleaning of a substrate; (2) single crystal GeSe triangular nanosheet array growth: (1) respectively placing the GeSe powder and a substrate in the centers of a high-temperature region and a low-temperature region of a double-temperature-region tubular furnace; and (2) vacuumizing until the pressure in the furnace is 10-50 Pa, introducing inert gas at 10-60 sccm to enable the pressure to be 400-800 Pa, heating the low-temperature region to 50-150 DEG C, heating the high-temperature region to 350-530DEG C, and keeping the temperature for 1-3 hours to obtain the GeSe material. The GeSe triangular nanosheet has a temperature-dependent photoluminescence property in a near-infrared region, and can beapplied to a photoelectric device. The preparation method provided by the invention has the advantages of simple process, high quality, low cost and the like.

Description

technical field [0001] The invention belongs to the technical field of semiconductor nanometer materials, and in particular relates to a preparation method and application of a single crystal GeSe triangular nanosheet array material. Background technique [0002] Two-dimensional layered nanomaterials have superior optical, electrical, thermal, magnetic and other physical properties, and are one of the most potential candidate materials for a new generation of optoelectronic components. In recent years, the Group IV-VI semiconductor compound GeSe has attracted extensive attention due to its natural layered crystal structure and excellent semiconductor performance, and it has extremely broad application prospects in many fields such as microelectronics and optoelectronic devices. [0003] With the rapid development of modern technology, GeSe materials have played an important role in the field of semiconductor industry and optoelectronic manufacturing technology and have relat...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C30B29/46C30B23/02C01B19/04B82Y30/00B82Y40/00
CPCB82Y30/00B82Y40/00C01B19/007C01P2004/64C01P2006/80C30B23/02C30B29/46
Inventor 张析向钢李学燕
Owner SICHUAN UNIV