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Composite material and macromolecule positive temperature coefficient thermistor made of composite material

A composite material and polymer technology, applied in the field of polymer positive temperature coefficient thermistors, can solve the problems of affecting resistance value, large amount of grafted polymer, and coupling agent precipitation, etc., to meet the stability and maintain low Resistance characteristics, the effect of excellent room temperature and low resistivity

Active Publication Date: 2020-12-04
THINKING ELECTRONIC IND CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] In order to make the polymer positive temperature coefficient thermistor have excellent resistance reproducibility after repeated high and low temperature cycles, the prior art uses a coupling agent or maleic anhydride grafted polyethylene to increase the polymer and The interface binding property of conductive particles, however, if a coupling agent is used, there will be a problem of precipitation of the coupling agent during use
If maleic anhydride-grafted polyethylene is used, because the grafting rate of maleic anhydride-grafted polyethylene is low, generally only 0.4% to 2%, so in order to achieve the purpose, grafted polymers such as maleic anhydride are required. A large amount will affect the resistance value

Method used

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  • Composite material and macromolecule positive temperature coefficient thermistor made of composite material
  • Composite material and macromolecule positive temperature coefficient thermistor made of composite material
  • Composite material and macromolecule positive temperature coefficient thermistor made of composite material

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0031] Comparing the material components and weight percentages of Example 1 and Comparative Example 6, the difference lies in the ratio of metal tungsten to tungsten carbide. In Example 1 with a ratio of metal tungsten to tungsten carbide of 2.05%, compared to Comparative Example 6 with a ratio of metal tungsten to tungsten carbide of 1.39%, the resistance value after multiple high and low temperature cycles decreased by about 35%. In a similar situation, compared to Comparative Example 7 in which the ratio of metal tungsten to tungsten carbide was 2.00% in Example 2, which was 1.07% in metal tungsten to tungsten carbide, the resistance value after multiple high and low temperature cycles decreased by about 43%.

Embodiment 3

[0032] Compared with the material components and weight percentages of Example 3 and Comparative Example 8, the difference lies in the selection of the compatibilizer. Compared with the compatibilizer in Example 3, which uses ethylene-vinyl alcohol copolymer, the compatibilizer uses a silane coupling agent. In Comparative Example 8, the resistance value after multiple high and low temperature cycles was reduced by about 27%. In a similar situation, the compatibilizer was selected from ethylene-vinyl alcohol copolymer compared with Example 6 in which the compatibilizer was selected from silane coupling agent. In Comparative Example 9, the resistance value after multiple cycles of high and low temperature decreased by about 53%.

Embodiment 7

[0033] Comparing the material composition and weight percentage of Example 7 and Comparative Example 11, the weight percentage of polyethylene is the same, and the ratio of metal tungsten to tungsten carbide is similar. The difference lies in whether ethylene-vinyl alcohol copolymer is used as a compatibilizer. Compared with Comparative Example 11 in which ethylene-vinyl alcohol copolymer was used as a compatibilizer, the resistance value after multiple high and low temperature cycles was reduced by about 30%. In a similar situation, compared with Comparative Example 5 in which ethylene-vinyl alcohol copolymer was used as a compatibilizer, the resistance value after multiple high and low temperature cycles was reduced About 59%.

[0034] The effect of the proportion of ethylene in the compatibilizer ethylene-vinyl alcohol copolymer of the composite material layer 102 of the present invention on the resistance value after multiple high and low temperature cycles is shown in Tab...

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PUM

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Abstract

The invention discloses a composite material and a macromolecule positive temperature coefficient thermistor prepared from the composite material. The composite material comprises a macromolecule crystalline polymer, a conductive filler and a compatilizer, wherein the macromolecule crystalline polymer accounts for 5-15 wt% of the composite material, the conductive filler accounts for 70-95 wt% ofthe composite material, the compatilizer accounts for 0.5-2 wt% of the composite material, the conductive filler is a mixture of a carbide and metal tungsten, the metal tungsten accounts for 2-6 wt% of the weight of the conductive filler, the compatilizer is an ethylene-vinyl alcohol copolymer, the thermistor comprises two conductive layers and a composite material layer, the composite material layer is arranged between the two conductive layers, the composite material layer is made of a composite material, and the thermistor has the characteristic of low initial resistance and can still keepthe characteristic of low resistance after multiple high-low temperature cycles so as to meet lithium battery stability.

Description

technical field [0001] The invention relates to a composite material used in electronic components and a polymer positive temperature coefficient thermistor made of the composite material. Background technique [0002] The polymer positive temperature coefficient thermistor can maintain an extremely low resistance value at normal temperature, and has the characteristic of being sensitive to temperature changes, that is, when an overcurrent or overtemperature occurs in the circuit, its resistance will instantly increase to one High resistance value keeps the circuit in an open circuit state to achieve the purpose of protecting circuit components. Therefore, conductive composite materials with a positive temperature coefficient of resistance can be connected to the circuit. As materials for current sensing components, such conductive composite materials have been widely used in electronic circuit protection components. [0003] However, with the popularization of electric loc...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01B1/22H01B1/24H01C7/02
CPCH01B1/22H01B1/24H01C7/027
Inventor 萧富昌陈志源
Owner THINKING ELECTRONIC IND CO LTD
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