A kind of preparation method of seaweed polysaccharide-based silver phosphate composite material
A technology of seaweed polysaccharide-based silver phosphate and composite materials, which is applied in the fields of botanical equipment and methods, chemicals for biological control, biocides, etc., can solve the problem of uneven distribution of silver ions, restrict the application of composite materials, and low distribution density and other problems, to achieve the effect of good elasticity, elimination of internal stress and good uniformity
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Embodiment 1
[0040] A preparation method of seaweed polysaccharide-based silver phosphate composite material, comprising the following steps:
[0041] (1) Weigh according to the mass ratio of sodium dihydrogen phosphate: sodium alginate: deionized water=1:3:80, dissolve sodium dihydrogen phosphate in deionized water, and adjust the pH to 1% with sodium hydroxide solution. 9-10, then heated to 45 ℃, slowly add sodium alginate under the action of ultrasonic, after the sodium alginate is completely dissolved, maintain for 30min, that is, solution A;
[0042] (2) Weigh the equimolar silver nitrate with phosphate, then weigh according to the mass ratio of silver nitrate: 25% ammonia water: deionized water=1:5:5, and dissolve the silver nitrate in deionized water at room temperature , and then drop 25% ammonia water into the silver nitrate solution under stirring, and then maintain stirring and react for 3min to obtain solution B;
[0043] (3) drop solution B into solution A under stirring, sto...
Embodiment 2
[0046] A preparation method of seaweed polysaccharide-based silver phosphate composite material, comprising the following steps:
[0047] (1) Weigh according to the mass ratio of sodium monohydrogen phosphate: sodium alginate: deionized water=1:3:85, dissolve sodium monohydrogen phosphate in deionized water, and adjust the pH to 1% with sodium hydroxide solution. 9-10, then heated to 45 ℃, slowly add sodium alginate under the action of ultrasonic, after the sodium alginate is completely dissolved, maintain for 45min, that is, solution A;
[0048] (2) Weigh the equimolar silver nitrate with phosphate, then weigh according to silver nitrate: 25% ammonia water: deionized water according to the mass ratio of 1:5.5:6, and dissolve silver nitrate in deionized water at room temperature , and then drop 25% ammonia water into the silver nitrate solution under stirring, and then maintain stirring and react for 4 min to obtain solution B;
[0049] (3) drop solution B into solution A und...
Embodiment 3
[0052] A preparation method of seaweed polysaccharide-based silver phosphate composite material, comprising the following steps:
[0053] (1) Weigh according to the mass ratio of sodium phosphate: sodium alginate: deionized water = 1:4:100, dissolve sodium phosphate in deionized water, adjust pH to 9-10 with 1% nitric acid solution, and then heat To 45 ℃, slowly add sodium alginate under the action of ultrasound, after the sodium alginate is completely dissolved, maintain for 60min, that is, solution A;
[0054] (2) Weigh the equimolar silver nitrate with phosphate, and then weigh according to the mass ratio of silver nitrate: 25% ammonia water: deionized water=1:6:7, and dissolve the silver nitrate in deionized water at room temperature , and then drop 25% ammonia water into the silver nitrate solution under stirring, and then maintain stirring and react for 5min to obtain solution B;
[0055] (3) drop solution B into solution A under stirring, stop stirring when the reactio...
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