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Natural gas conversion to chemicals and power with molten salts

A technology of molten salts and products, which is used in the production of chemical substances and solid carbon, the production of hydrogen and solid carbon, and the production of heat and steam from natural gas, which can solve the problems of low methane conversion rate and so on.

Pending Publication Date: 2021-02-09
RGT UNIV OF CALIFORNIA
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

CH 4 ←→2H 2 The reaction of +C is limited by equilibrium such that methane conversion is relatively low at pressures of about 5-40 bar and temperatures below 1100 °C required for industrial production

Method used

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  • Natural gas conversion to chemicals and power with molten salts
  • Natural gas conversion to chemicals and power with molten salts
  • Natural gas conversion to chemicals and power with molten salts

Examples

Experimental program
Comparison scheme
Effect test

example 1

[0151] Referring to Figure 3, pyrolysis of methane is performed to form hydrogen and solid carbon, which are separated by filtration in a bubble lift pump. 100% methane was used as feed 101 into a reactor containing a molten mixture of 50% KCl and 50% NaCl salts at a rate of 30 sccm at 1000° C. through a concentric inlet pipe 202 made of quartz. Feed gas is caused to bubble upward in liquid filled reactor 332 . The methane reacts within the bubbles, and the products carbon and hydrogen, as well as the liquid, rise up the reactor due to their density differences. At the top of the liquid, channels allow the carbon and gas containing liquid to move out of the main reactor section 335 and through the filter 336 where the solid carbon is retained and the molten salt is passed. The filter is removable and the photo shows the solid carbon remaining on the filter. The gas phase product is primarily hydrogen leaving reactor 337. The molten salt returns to the bottom of the reactor ...

example 2

[0153] (Pyrolysis of Methane in Binary Molten Salts)

[0154] In the second example, according to the simplified diagram Figure 15 , methane is thermally decomposed in the reactor configuration. Some embodiments may also contain more reaction zones, post-reaction separation units or gas preheating units.

[0155] In this particular example, at a pressure of 1 bar, a methane feed stream 1501 at a flow rate of 15 sccm was bubbled through a quartz inlet tube 1502 (3 mm outer diameter (OD) and 2 mm inner diameter (ID)) into a In the alkali metal halide molten salt 1503 in the reactor 1504 (OD is 25 mm, ID is 22 mm). will total 77cm 3 The molten salt is loaded in the reactor. The bubble ascent velocity was estimated to be 24 cm / sec, resulting in a gas residence time of approximately 0.75 sec. Collect gaseous products such as hydrogen, C from the top 1505 of the column 2 Hydrocarbons (such as ethane, ethylene, and acetylene), aromatic hydrocarbons (such as benzene), and unrea...

example 3

[0162] (MP in carbon-salt slurry)

[0163] In this example, according to the simplified illustration Figure 15 , methane is thermally decomposed in the reactor configuration. Some embodiments may also contain more reaction zones, post-reaction separation units or gas preheating units. Other embodiments may incorporate solids suspended in molten salt media to increase reaction rates and increase reactive surface area. For example, both metal and carbon-based materials have been thoroughly explored as heterogeneous methane conversion catalysts.

[0164] In this particular example, a feed stream 1501 of methane (15 sccm) was bubbled through a quartz inlet tube 1502 (OD 3 mm and ID 2 mm) at 1000° C. at a pressure of 1 bar into a quartz reactor housed in (OD is 25mm, and ID is 22mm) in alkali metal halide molten salt 1503 (ie NaCl, NaBr, KCl or KBr). will total 77cm 3 The molten salt is loaded in the reactor. The bubble ascent velocity was estimated to be 24 cm / sec, resultin...

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Abstract

A reaction process comprises the steps: feeding a feed stream comprising a hydrocarbon into a vessel, reacting the feed stream in the vessel, producing solid carbon and a gas phase product based on the contacting of the feed stream with the molten salt mixture, separating the gas phase product from the molten salt mixture, and separating the solid carbon from the molten salt mixture to produce a solid carbon product. The vessel comprises a molten salt mixture, and the molten salt mixture comprises a reactive component.

Description

[0001] Related Application Cross Reference [0002] This application claims priority to U.S. Provisional Application No. 62 / 674,268, filed May 21, 2018, entitled "Natural Gas Conversion to Chemicals and Power with Molten Salts" , said US provisional application is incorporated herein by reference in its entirety. [0003] Statement Regarding Federally Sponsored Research or Development [0004] This invention was made with Government support under Grant No. DE-FG02-89ER14048 awarded by US DOE BES. The government has certain rights in this invention. technical field [0005] This invention relates to the removal of carbon from reactors using molten salts to produce chemicals and solid carbon from natural gas. The invention also relates to the production of hydrogen and solid carbon from other hydrocarbon feedstocks including natural gas, petroleum and components thereof. The present invention also broadly relates to the reactive separation of reactants and catalysts from ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J19/00B01J19/28B01J23/89B01J35/27
CPCB01J19/24B01J19/18B01J23/745B01J27/10B01J23/755B01J27/08B01J27/128B01J23/75B01J23/89C01B3/24C01B32/05C01B2203/0277C01B2203/0833C01B2203/1241C01B2203/0272B01J19/2465B01J6/008C01B3/26C01B2203/1041B01J35/27
Inventor E·W·麦克法兰C·厄珀姆C·帕尔默S·苏D·曼尼尼N·拉希米D·康H·梅丘M·戈登
Owner RGT UNIV OF CALIFORNIA