373results about "Pyrolysis reactions" patented technology

A pyrolytic reactor comprising a fuel injection zone, a combustion zone adjacent to the fuel injections zone, an expansion zone adjacent to the combustion zone, a feedstock injection zone comprising a plurality of injection nozzles and disposed adjacent to the expansion zone, a mixing zone configured to mix a carrier stream and feed material and disposed adjacent to the feedstock injection zone, and a reaction zone adjacent to the mixing zone. The plurality of injection nozzles are radially distributed in a first assembly defining a first plane transverse to the feedstock injection zone and in a second assembly transverse to the feedstock injection zone.

This invention provides a continuous process for the growth of vapor grown carbon fiber (VGCNT) reinforced continuous fiber preforms for the manufacture of articles with useful mechanical, electrical, and thermal characteristics. Continuous fiber preforms are treated with a catalyst or catalyst precursor and processed to yield VGCNT produced in situ resulting in a highly entangled mass of VGCNT infused with the continuous fiber preform. The continuous process disclosed herein provides denser and more uniform carbon nanotubes and provides the opportunity to fine-tune the variables both within an individual preform and between different preforms depending on the characteristics of the carbon nanotubes desired. The resulting continuous fiber preforms are essentially endless and are high in volume fraction of VGCNT and exhibit high surface area useful for many applications. The invention also provides for composites made from the preforms.

A process for the pyrolysis of carbonaceous material is carried out in a cyclone reactor which is fitted with enhanced filtering equipment. In addition the invention relates to the use of a cyclone fitted with a rotating filter as a pyrolysis reactor. By using a cyclone of the rotating separator type as a pyrolysis reactor, carbonaceous material, such as biomass, can effectively be converted in a product having excellent chemical properties and which product is free from particulate matter.

Embodiments presented herein describe an apparatus and method to convert carbonaceous materials, particularly biomass and those biomass resources which are remotely located, into a high performance solid fuel. This method, and the apparatus described as the means to accomplish this method, provides a continuous process which can be completely powered by the energy contained in the biomass. The heat, mechanical power and electrical power are provided from the energy in the biomass, through the methods described. In this way, the apparatus is free to operate in remote locations, where no power or auxiliary fuel sources are available.

The present invention relates to single walled and multi-walled carbon nanotubes (CNTs), functionalized CNTs and carbon nanotube composites with controlled properties, to a method for aerosol synthesis of single walled and multi-walled carbon nanotubes, functionalized CNTs and carbon nanotube composites with controlled properties from pre-made catalyst particles and a carbon source in the presence of reagents and additives, to functional, matrix and composite materials composed thereof and structures and devices fabricated from the same in continuous or batch CNT reactors. The present invention allows all or part of the processes of synthesis of CNTs, their purification, doping, functionalization, coating, mixing and deposition to be combined in one continuous procedure and in which the catalyst synthesis, the CNT synthesis, and their functionalization, doping, coating, mixing and deposition can be separately controlled.

A method is disclosed for generating useful chemical intermediates from biomass using a novel pyrolysis reactor that utilizes the inherent thermal properties of carbon under compression as the biomass is subjected to sequential or concurrent temperature ramps. The ramps are sufficient to volatilize and selectively create different components, while the pressure application aids the selective decomposition of the biomass.

Systems and processes for efficiently cracking of hydrocarbon mixtures, such as mixtures including compounds having a normal boiling temperature of greater than 450° C., 500° C., or even greater than 550° C., such as whole crudes for example, are disclosed.

The invention relates to a method for the preparation of porous carbon-based material comprising the steps provision of a polymer film provided in the form of a sheet or a coating; as well as pyrolysis and / or carbonization of the polymer film in an atmosphere that is essentially free of oxygen at temperatures in the range of 80° C. to 3,500° C. The invention further relates to carbon-based material producible according to the method mentioned above.

Disclosed is a process for the synthesis of 1,3,3,3-tetrafluoropropene which comprises, in one embodiment, reacting a compound of CF3X1 with a compound of CX2H═CHX3, wherein X1, X2, and X3 are each independently selected from the group consisting of fluorine, chlorine, bromine and iodine, to produce a reaction product comprising a compound of CF3CH═CHX3, wherein X3 is as described above; and when X3 is not fluorine, fluorinating the compound to produce 1,3,3,3-tetrafluoropropene. The process in another embodiment comprises preparing tetrafluoropropene comprising thermally cracking one or more compounds capable of producing a reaction mixture which preferably comprises diflurocarbene radicals and vinylidene fluoride, and converting said reaction mixture into—tetrafluoropropene (1,3,3,3-tetrafluoropropene).

Disclosed is a process for the synthesis of 1,3,3,3-tetrafluoropropene which comprises, in one embodiment, reacting a compound of CF3X1 with a compound of CX2H═CHX3, wherein X1, X2, and X3 are each independently selected from the group consisting of fluorine, chlorine, bromine and iodine, to produce a reaction product comprising a compound of CF3CH═CHX3, wherein X3 is as described above; and when X3 is not fluorine, fluorinating the compound to produce 1,3,3,3-tetrafluoropropene. The process in another embodiment comprises preparing tetrafluoropropene comprising thermally cracking one or more compounds capable of producing a reaction mixture which preferably comprises diflurocarbene radicals and vinylidene fluoride, and converting said reaction mixture into—tetrafluoropropene (1,3,3,3-tetrafluoropropene).

A cylindrical screw feeder main body, catalyst feeding portions for introducing a catalyst into the screw feeder main body, low hydrocarbon feeding portions for introducing a low hydrocarbon into the screw feeder main body as a raw material, a screw for conveying the catalyst and nanocarbon produced by pyrolysis of the low hydrocarbon in the feeder main body, a solid matter discharging portion for discharging the catalyst and the nanocarbon conveyed by the screw out of the screw feeder main body and a gas discharging portion for discharging the unreacted low hydrocarbon and hydrogen produced by the pyrolysis of the low hydrocarbon out of the screw feeder main body are provided. Nanocarbon grown with the catalyst as top with time is continuously discharged out of the screw feeder main body while unused catalyst is being fed thereto at the same amount as that of nanocarbon, allowing efficient continuous reaction.

High enthalpy low power plasma reformer. An annular ground electrode includes a air intake manifold and helical structure for directing an air helically along the ground electrode in a heat transfer relation. A high voltage electrode is spaced from the ground electrode to create a gap through which preheated air flows, the high voltage electrode including a passage for delivery of hydrocarbon fuel to an atomizer. A plasma discharge occurs within an electric arc discharge region within the annular ground electrode in which the fuel is partially pyrolized to produce hydrogen rich gas.

A feedstock flexible process for converting feedstock into oil and gas includes (i) indirectly heated hydrous devolatilization of volatile feedstock components, (ii) indirectly heated thermochemical conversion of fixed carbon feedstock components, (iii) heat integration and recovery, (iv) vapor and gas pressurization, and (v) vapor and gas clean-up and product recovery. A system and method for feedstock conversion includes a thermochemical reactor integrated with one or more hydrous devolatilization and solids circulation subsystems configured to accept a feedstock mixture, comprised of volatile feedstock components and fixed carbon feedstock components, and continuously produce a volatile reaction product stream therefrom, while simultaneously and continuously capturing, transferring, and converting the fixed carbon feedstock components to syngas.

A drag chain carbonizer is provided with a system and methods for anaerobic thermal transformation processing to convert waste into various solid carbonized products and varied further co-products. The drag-chain carbonizer includes an adjustable bed depth mechanism, a heating mechanism, a pressure management mechanism, and a chain tensioning mechanism containing at least one position sensor for communication of an actuator position to at least one programmable logic controller (PLC). Carbonaceous waste is transformed into useful co-products that can be re-introduced into the stream of commerce at various economically advantageous points. Depending upon the input materials and the parameters selected to process the waste, including real time economic and other market parameters, the system adjusts co-products output to reflect changing market conditions.

An apparatus and method to convert carbonaceous materials, particularly biomass and those biomass resources which are remotely located, into a solid material, which may be a high performance solid fuel, are presented. This method, and the apparatus described as the means to accomplish this method, provides a continuous process which can be completely powered by the energy contained in the biomass. The heat, mechanical power and electrical power are provided from the energy in the biomass, through the methods described. In this way, the apparatus is free to operate in remote locations, where no power or auxiliary fuel sources are available.

The invention relates to waste processing and to producing hydrocarbons from domestic and industrial organic waste by pyrolysis. The inventive waste processing method involves carrying out the first and second pyrolysis stages, fractionating pyrolysis products and processing each fraction for producing useful products. The second pyrolysis stage is carried out simultaneously with the electromagnetic action produced on the pyrolysis products. The device for carrying out said method comprises a two-sectional pyrolysis reactor. An electromagnetic source is arranged on the second section of the reactor. The output of the second section is connected to a system for dividing the vaporous pyrolysis products. The technical result consists in increasing the waste processing effectiveness and producing solid, liquid and vaporous fuel components.

A method is described for generating useful chemical intermediates from biomass using a novel pyrolysis reactor that utilizes the inherent thermal properties of carbon under compression as the biomass is subjected to sequential or concurrent temperature ramps. The ramps are sufficient to volatilize and selectively create different components, while the pressure application aids the selective decomposition of the biomass.

An improved furnace which provides for multizone, separate and independent cracking is provided.

A method and apparatus for producing nanometer-sized particles, the method including the steps of forming of mixture by mixing a first precursor reactant, a second precursor reactant, a surface-stabilizing surfactant, and a high boiling point liquid to form a mixture, forming a mist of droplets of the mixture, heating the droplets to cause a reaction between species of the first and second precursor reactants within the heated droplets, and collecting the nanometer-sized products.

A batch of a substance, e.g., a biomass, is processed in a batch-wise operated retort under the application of heat. The substance releases a combustible process fluid during the processing. The process fluid is combusted for generating heat. The heat is supplied to the retort and / or stored in temporary heat storage in dependence on the progress of the processing for postponed heat supply to the retort.

A method and apparatus for producing nanometer-sized particles, the method including the steps of forming of mixture by mixing a first precursor reactant, a second precursor reactant, a surface-stabilizing surfactant, and a high boiling point liquid to form a mixture, forming a mist of droplets of the mixture, heating the droplets to cause a reaction between species of the first and second precursor reactants within the heated droplets, and collecting the nanometer-sized products.

A method of forming a three dimensional fiber structure is disclosed which comprises the steps of a) providing a starting material which comprises liquid carrier, fibers and binder; b) passing the starting material over a substrate so as to deposit fibers onto the substrate; c) forming a three dimensional fiber matrix; and d) curing the binder. The flow of material onto the substrate may be controlled such that the flow of a starting material over the substrate is chaotic and fibers are laid down in a three dimensional structure containing a high proportion of voids. The preform may be pressurized while moist and is cured under pressure. The fibers may comprise carbon fibers; recycled carbon fiber has been found to be particularly useful. The resulting preform may be stochastic and is suitable for use in ablative and braking applications.

The present invention relates to an apparatus for self-propagating high temperature synthesis of an inorganic compound from a combustible charge mixture of initial ingredients. The apparatus comprises mechanisms for continuously feeding the combustible charge into a reaction chamber and removing the synthesized compound therefrom. The apparatus also contains sensors to control and contain the combustion inside a combustion zone of the reaction chamber.

The invention provides a method for refining and resource utilization of byproduct salt. The method comprises the following steps: (1), byproduct salt of certain mass is placed into a microwave cracking furnace; (2), a waste gas emission opening is arranged on the microwave cracking furnace; (3), waste gas emitted out of the waste gas emission opening enters a heat exchanger; (4), the waste gas passing through the heat exchanger is connected with a waste gas treatment device; (5), the byproduct salt subjected to treatment of the step (1) is tested; (6), the byproduct salt which is tested to be qualified in the step (5) is dissolved in pure water and is purified; (7), the purified salt is subjected to electrolysis with an ion-exchange film; and (8), after the purified salt is subjected to the electrolysis with the ion-exchange film, H2, Cl2, and NaOH can be obtained. The method is high in resource utilization degree and simple in technological process; identification of dangerous waste is not needed; waste salt can be subjected to resource utilization directly; most test and analysis cost can be omitted; automatic production is realized; and operation is simple.

A system and method for torrefying a combination of biomass and biochar colloidal dispersion is provided.

The invention relates to a solid waste and hazardous waste cleaning and recycling treatment method. The method comprises the following steps: S1, pre-treating wastes and feeding the wastes and a gasifying agent into a high-temperature thermal reaction device for high-temperature gasification reaction to obtain high-temperature coal gas and molten slag, wherein the highest reaction temperature in the high-temperature thermal reaction device is higher than the ash melting point flowing temperature of the waste and the high-temperature gasification reaction is completed in a reducing atmosphere,and the reducing atmosphere refers to that the molar concentration of oxygen in gas in a reaction system is lower than 0.5% and the molar concentration of the sum of carbon monoxide and hydrogen in the gas is higher than 5%; and S2, carrying out heat exchange and purification on the high-temperature coal gas to obtain clean coal gas, and cooling and recycling the molten slag.