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Adding method of composite gypsum crystallization promoter for improving crystallization quality of desulfurization slurry

A technology of crystallization accelerator and desulfurization slurry, applied in chemical instruments and methods, flocculation/sedimentation water/sewage treatment, gaseous effluent wastewater treatment, etc., can solve the problems of poor overall water quality, small gypsum crystal grains, unit outage, etc. , achieve high efficiency and low cost quality, ensure implementation effect and improve quality

Active Publication Date: 2021-03-19
HEBEI GUOHUA DINGZHOU POWER GENERATION +1
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Problems solved by technology

[0002] Under the background of the implementation of zero discharge of waste water in the thermal power plant, the high-salt and high-chlorinated waste water of the whole plant is finally collected into the wet desulfurization tower. The crystallization process leads to difficulty in crystallization of gypsum in the absorption tower, small gypsum crystal grains, difficulty in separating gypsum particles on the cyclone, difficulty in dehydrating gypsum on the dehydrator, and a decline in the quality of the slurry in the desulfurization system tower, which seriously affects the normal operation of the desulfurization system and even causes the unit to shut down

Method used

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Embodiment

[0056] Firstly, the gypsum grains are divided into three directions, the a-axis, b-axis and c-axis are perpendicular to each other. The crystal plane corresponding to the a-axis direction is mainly formed by the combination of sulfate and calcium ions; the crystal plane corresponding to the b-axis direction is formed by the combination of sulfate and crystal water, the crystal plane has the weakest binding force, and the b-axis direction grows the slowest ; The crystal face corresponding to the c-axis direction is mainly composed of calcium ions, the binding ability of calcium ions is the strongest, and the growth rate of the c-axis is the fastest; under the background of waste discharge from the whole plant, the crystal face growth in the b-axis direction of gypsum is inhibited, and the c-axis growth rate is the fastest. The axis grows fast, resulting in needle-shaped grains, and the particle size is too small, so the gypsum is not easy to dehydrate.

[0057] The gypsum cryst...

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PUM

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Abstract

The invention belongs to the technical field of flue gas desulfurization of thermal power plants, and relates to a composite gypsum crystallization promoter for improving the crystallization quality of desulfurization slurry and an adding method. Through the added composite gypsum crystallization promoter, the absorption process of sulfur dioxide, the dissolution process of limestone, the oxidation process of sulfites and the crystallization process of gypsum are carried out; gypsum particle size in the tower is increased, desulfurization slurry quality is improved, and operating parameters and water quality characteristics in the absorption tower are improved; and gypsum crystallization in the absorption tower is effectively improved. The invention provides the adding opportunity and adding position of the gypsum crystallization promoter. The implementation effect of the composite gypsum crystallization accelerator is ensured, and the quality of slurry in the tower is ensured to be improved with high efficiency and low cost; and normal operation of a desulfurization system is guaranteed, zero emission of wastewater of the whole plant meets the requirement, and the environment is protected.

Description

technical field [0001] The invention belongs to the technical field of flue gas desulfurization in thermal power plants, and in particular relates to a composite gypsum crystallization accelerator and an adding method for improving the crystallization quality of desulfurization slurry. Background technique [0002] Under the background of the implementation of zero discharge of waste water in the thermal power plant, the high-salt and high-chlorinated waste water of the whole plant is finally collected into the wet desulfurization tower. The crystallization process leads to difficult crystallization of gypsum in the absorption tower, small gypsum crystal grains, difficulty in separating gypsum particles on the cyclone, difficulty in dehydrating gypsum on the dehydrator, and degraded slurry quality in the desulfurization system tower, which seriously affects the normal operation of the desulfurization system, and even causes the unit to shut down . [0003] Chinese patent 20...

Claims

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Application Information

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IPC IPC(8): C02F1/52C02F1/54C02F103/18
CPCC02F1/5236C02F1/54C02F2001/5218C02F2103/18
Inventor 王祖林李勇苑斌韩长亮肖海平
Owner HEBEI GUOHUA DINGZHOU POWER GENERATION
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