The present invention provides a
polyamic acid film, a rod-shaped silver
powder /
polyimide composite film and a preparation method thereof, and relates to the field of
antistatic materials. The preparation method first prepares a
polyamic acid solution and a first silver
powder, and then successively coats the first silver
powder with vinyl triacetoxysilane and 12-
hydroxystearic acid to obtain a second silver powder; finally, the second silver powder is added to the aforementioned
polyamic acid solution, a film is formed by a
casting method, and then heat-treated to obtain a polyamic acid film with processability. The film is treated in a vacuum environment of 280-300°C for 4-5h to obtain a rod-shaped silver powder /
polyimide composite film, the bottom of the
composite film is uniformly precipitated and enriched with rod-shaped silver powder, and the silver powders overlap each other to form a three-dimensional mesh conductive structure, so that the upper and lower surfaces of the film have different surface resistances, and the composite film can be applied to electrostatic dissipation or electrostatic conduction according to the surface resistance of the silver powder enriched surface.