Ion exchange resin composition, preparation method thereof and membrane material formed by ion exchange resin composition
A technology of ion exchange resin and ion polymer, applied in the direction of chemical instruments and methods, membrane, membrane technology, etc., can solve the problems of low membrane strength, poor dimensional stability, swelling deformation, etc.
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Embodiment 1
[0061] After getting 70 parts by weight of sulfonate polyester (model AQ48, available from Eastman) with hydroxyl or carboxyl groups at the end and mixing 2 parts by weight of ethylene glycol with dimethylacetamide (DMAC) of 102.5 parts by weight, add 7.72 1,2,4,5-pyromellitic dianhydride (benzene-1,2:4,5-tetracarboxylic dianhydride; PMDA) in parts by weight forms a solution. The solution was heated to 130° C. for 3 hours to prepare a solution (the first intermediate) with the ionic polymer, and then the temperature was lowered to 90° C.
[0062]20 parts by weight of epoxy-based compounds (epoxy equivalent EEW: 215 grams / equivalent) are dissolved in dimethylacetamide of 20 parts by weight, and then the above-mentioned solution (first intermediate) with ionic polymer is added , heated to 90°C and reacted for 2 hours, and after cooling down to room temperature, the first mixed solution can be obtained. This first mixed solution is an alkyd resin homogeneous solution, which is a...
Embodiment 2
[0074] After getting 80 parts by weight of sulfonate polyester (type AQ55S, purchased from Eastman) whose terminal is a hydroxyl or carboxyl group, mixed with 2 parts by weight of ethylene glycol and 107 parts by weight of dimethylacetamide (DMAC), add 1.93 Parts by weight of 1,2,4,5-pyromellitic dianhydride (PMDA) form a solution. The solution was heated to 130° C. for 3 hours to prepare a solution (the first intermediate) with the ionic polymer, and then the temperature was lowered to 90° C.
[0075] 18 parts by weight of epoxy-based compounds (epoxy equivalent EEW: 215 grams / equivalent) are dissolved in 25 parts by weight of dimethylacetamide, then add the above-mentioned solution (the first intermediate) with the ionic polymer, and heat After reacting at 90° C. for 2 hours, and then cooling down to room temperature, the first mixed solution can be obtained. This first mixed solution is an alkyd resin homogeneous solution, which is a fluid dark amber liquid.
[0076] Get ...
Embodiment 3
[0087] After getting 80 parts by weight of sulfonate polyester (type AQ55S, purchased from Eastman) whose terminal is a hydroxyl or carboxyl group, mixed with 2 parts by weight of ethylene glycol and 107 parts by weight of dimethylacetamide (DMAC), add 1.93 Parts by weight of 1,2,4,5-pyromellitic dianhydride (PMDA) form a solution. The solution was heated to 130° C. for 3 hours to prepare a solution (the first intermediate) with the ionic polymer, and then the temperature was lowered to 90° C.
[0088] 18 parts by weight of epoxy-based compounds (epoxy equivalent EEW: 215 grams / equivalent) are dissolved in 25 parts by weight of dimethylacetamide, then add the above-mentioned solution (the first intermediate) with the ionic polymer, and heat React at 90° C. for 2 hours, and after cooling down to room temperature, the first mixed solution can be obtained. This first mixed solution is an alkyd resin homogeneous solution, which is a fluid dark amber liquid.
[0089] Take 10 g of...
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