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Continuous carbon fiber reinforced polyphenylene sulfide composite material

A polyphenylene sulfide and composite material technology, which is applied in the field of continuous carbon fiber reinforced polyphenylene sulfide composite materials, can solve the problem that the surface of carbon fiber is inert, the activity of common modifiers is low, and the strength of carbon fiber polyphenylene sulfide reinforced material is continuously improved. Unsatisfactory and other issues to achieve the effect of improving performance

Pending Publication Date: 2021-06-29
SHANDONG DAWN POLYMER CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] However, the above-mentioned existing method improves the mechanical properties of the CF / polyphenylene sulfide composite material to a certain extent by treating the carbon fiber, but the surface inertia of the carbon fiber is too strong, and the activity of common modifiers reacting with it is very low; at the same time , polyphenylene sulfide is also a weaker polar material with low end group reactivity
Therefore, the reported strength improvement of carbon fiber polyphenylene sulfide reinforced materials is still unsatisfactory, and cannot meet the special requirements for high-strength materials in the military and aerospace fields, and further improvement is needed

Method used

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  • Continuous carbon fiber reinforced polyphenylene sulfide composite material
  • Continuous carbon fiber reinforced polyphenylene sulfide composite material
  • Continuous carbon fiber reinforced polyphenylene sulfide composite material

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Experimental program
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Effect test

Embodiment 1

[0050] Interface modifier direct addition method

[0051] The continuous carbon fiber is plasma-treated and pulled to the mixing plate;

[0052] The polyphenylene sulfide / interface modifier / processing aid are mixed evenly, enter the extruder through the feeding equipment to melt and mix, and introduce the mixed flow plate;

[0053] The melt is mixed with carbon fiber through a mixed flow plate, dragged and granulated, and a continuous carbon fiber reinforced polyphenylene sulfide composite material is obtained.

[0054] Among them, the extrusion temperature has 7 sections from the feeding section to the head temperature, which are 285, 290, 300, 320, 320, 320, and 320°C, and the temperature of the mixed flow plate is 330°C.

Embodiment 2

[0056] Interfacial Modifier Carbon Fiber Prepreg Method

[0057] The continuous carbon fiber is treated by plasma, pulled to the pre-impregnation tank of the interface modifier, and introduced into the mixed flow plate after reaction;

[0058] The polyphenylene sulfide / processing aid is mixed evenly, enters the extruder through the feeding equipment to melt and mix, and is introduced into the mixing plate;

[0059] The melt is mixed with carbon fiber through a mixed flow plate, dragged and granulated, and a continuous carbon fiber reinforced polyphenylene sulfide composite material is obtained.

[0060] Among them, the extrusion temperature has 7 sections from the feeding section to the head temperature, which are 285, 290, 300, 320, 320, 320, and 320°C, and the temperature of the mixed flow plate is 330°C.

[0061] Wherein, the pre-dipping temperature of the interface modifier is 90-110°C, and the pre-dipping time is 0.5-10s.

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Abstract

A continuous carbon fiber reinforced polyphenylene sulfide composite material comprises the following substances in parts by weight: 5-65 parts of continuous carbon fibers, 30-95 parts of polyphenylene sulfide resin, 0.3-10 parts of an interface modifier and 0.3-1 part of a processing modifier. According to the prepared composite material, the interface bonding performance between the continuous carbon fibers and the polyphenylene sulfide resin is effectively improved through the carbon fiber treatment process and the interface modifier, the high-strength and heat-resistant continuous carbon fiber / polyphenylene sulfide composite material is prepared, and the application prospects in the industries of spaceflight, military industry, traffic vehicles and sports goods are good.

Description

technical field [0001] The invention belongs to the field of carbon fiber polyphenylene sulfide composite materials, in particular to a continuous carbon fiber reinforced polyphenylene sulfide composite material. Background technique [0002] For carbon fiber reinforced polyphenylene sulfide materials, methods such as modifying polyphenylene sulfide resin or sizing the carbon fiber surface are usually used to enhance the interfacial bonding strength between carbon fiber and polyphenylene sulfide. [0003] Document "Improvement of Mechanical Properties of Polyphenylene Sulfide / Carbon Fiber Composites Modified by Aminated Reinforcement", HRui, K Zhang, ...Materials Science Forum (2015), using different mass fractions of ammoniated polyphenylene sulfide to modify carbon fiber reinforced polyphenylene sulfide composites, containing 7wt% PPS-NH2 The tensile strength of the PPS / CF composite was increased by 12.5%. [0004] Plastic Industry, 2013 (01), P100, reported that the intr...

Claims

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Application Information

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IPC IPC(8): C08L81/02C08K7/06C08K9/00C08K5/29C08J5/06
CPCC08J5/06C08J2381/02C08K7/06C08K9/00C08K5/29
Inventor 左振杰于晓宁田洪池陈军陈青葵李伟伟张伟卫
Owner SHANDONG DAWN POLYMER CO LTD
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