Method for detecting main medicinal components of cinnamon and storax in medicinal preparation
A technology for pharmaceutical preparations and active ingredients, applied in the detection field of cinnamic acid, can solve problems such as lack, and achieve the effects of ensuring stability, good stability, and improving quality control system
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[0056] 1. Preparation of the test solution
[0057] Grind the pharmaceutical preparation sample into powder, add organic solvent to dissolve, and accurately weigh. Wherein, the ratio of the mass of the pharmaceutical preparation sample added to the volume of the organic solvent added is 1:20-50, g / mL. Ultrasonic extraction was then performed for 10-40 min at a power of 250-350 W and a frequency of 35-45 kHz. Cool, weigh again, and make up for the weight loss with an organic solvent. Shake well, take the supernatant and pass it through a 0.45μm filter membrane, discard the initial filtrate, and obtain the subsequent filtrate, which is the solution of the test product. The above organic solvent is selected from one of methanol, ethanol, acetonitrile, 95% ethanol, and 80% methanol.
[0058] 2. Preparation of reference solution
[0059] The cinnamic acid reference substance was added into an organic solvent to dissolve and constant volume to prepare a reference substance solut...
Embodiment 1
[0071] 1. Preparation of the test solution
[0072] Grind 120 pills of the pharmaceutical preparation sample into powder, take 1.0 g and accurately weigh it, put it in a stoppered Erlenmeyer flask, accurately add 20 ml of 80% methanol to dissolve, seal it tightly, and accurately weigh it. Ultrasonic extraction was then performed for 20 min at a power of 300 W and a frequency of 40 kHz. Cool, weigh again, and make up for the weight loss with 80% methanol. Shake well, take the supernatant and pass through a 0.45 μm filter membrane, and discard the initial filtrate to obtain the subsequent filtrate, which is the test solution 1#.
[0073] 2. Preparation of reference solution
[0074] The cinnamic acid reference substance was dissolved in methanol and fixed to volume to prepare the reference substance solution 1#. The content range of cinnamic acid in reference substance solution 1# is 5.34-222.40 μ g / ml.
[0075] 3. Determination
[0076] Use high performance liquid chromato...
Embodiment 2
[0085] Get the pharmaceutical preparation sample of batch number H160350, adopt the preparation need testing solution in the step 1 in the embodiment 1. At the same time, the reference substance solution was prepared according to step 2 in Example 1, wherein the content of cinnamic acid in the reference substance solution was 60 μg / ml. Accurately draw reference substance solution and need testing solution 10 μ l respectively, inject liquid chromatograph, measure by step 2 in embodiment 1, compare retention time and carry out qualitative, specifically see Fig. 1, determine the output of cinnamic acid in need testing solution For peak conditions, see Table 2 for specific data.
[0086] Table 2
[0087]
PUM
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