Dextran microsphere, and preparation method and application thereof
A technology of dextran and microspheres, applied in application, prosthesis, surgery, etc., can solve problems such as suboptimal treatment, suboptimal tumor and cancer treatment, etc.
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Embodiment 1
[0034] A dextran microsphere, comprising the following raw materials by weight fraction: 1.6 parts of modified dextran, 50 parts of methyl silicone oil and 1 part of nitrogen nitrogen methylenebisacrylamide.
[0035] A preparation method of dextran microspheres, comprising the following steps:
[0036] S1. Prepare various raw materials according to the formula, and conduct raw material screening;
[0037] S2. Under nitrogen atmosphere, dextran and succinic anhydride are reacted and modified in dimethyl sulfoxide;
[0038] S3. Vacuum drying the modified dextran;
[0039] S4. Slowly add the modified dextran into the methyl silicone oil dropwise, then add nitrogen nitrogen methylenebisacrylamide into it, and carry out the reaction together. The reaction time is 20 hours, the temperature is 75°C, and then Stand still for 20h;
[0040] S5. After the reaction is over, discard the supernatant, take the precipitate, and wash it twice with absolute ethanol;
[0041] S6. Then vacuum...
Embodiment 2
[0043] A dextran microsphere comprises the following raw materials by weight fraction: 2.5 parts of modified dextran, 60 parts of liquid paraffin and 1.5 parts of polypropylene vinyl maleic anhydride grafted with β-cyclodextrin.
[0044] S1. Prepare various raw materials according to the formula, and conduct raw material screening;
[0045] S2. Dissolving the crosslinking agent and β-cyclodextrin in dry DMF for reaction, the reaction time is 7 hours, and the temperature is 80°C;
[0046] S3. DMF is then evaporated to obtain polypropylene vinyl maleic anhydride grafted with β-cyclodextrin;
[0047] S4. Under nitrogen atmosphere, dextran and succinic anhydride are reacted and modified in dimethyl sulfoxide;
[0048] S5. Vacuum drying the modified dextran;
[0049] S6. Slowly add the partially modified dextran into the oil phase solvent, and react with the oil phase solvent for a period of time, the reaction time is 24 hours, the temperature is 85 ° C, and then stand still for ...
Embodiment 3
[0053] A dextran microsphere comprises the following raw materials by weight fraction: 2.8 parts of modified dextran, 75 parts of methyl silicone oil and 1.2 parts of polypropylene vinyl maleic anhydride grafted with β-cyclodextrin.
[0054] A preparation method of dextran microspheres, comprising the following steps:
[0055] S1. Prepare various raw materials according to the formula, and conduct raw material screening;
[0056] S2. Dissolving the cross-linking agent and β-cyclodextrin in dry DMF for reaction, the reaction time is 8.5 hours, and the temperature is 85°C;
[0057]S3. DMF is then evaporated to obtain polypropylene vinyl maleic anhydride grafted with β-cyclodextrin;
[0058] S4. Under nitrogen atmosphere, dextran and succinic anhydride are reacted and modified in dimethyl sulfoxide;
[0059] S5. Vacuum drying the modified dextran;
[0060] S6. Dissolving the partially modified dextran in the oil phase solvent, and reacting with the oil phase solvent for a peri...
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