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White foaming agent with delayed foaming function and preparation method thereof

A foaming agent and functional technology, applied in the field of white foaming agent, can solve the problems of sodium bicarbonate foaming, product performance decline, waste and other problems

Pending Publication Date: 2021-09-10
连云港有道新材料科技有限公司 +3
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, since polystyrene and polyvinyl chloride among the three major foam plastics are thermoplastics, they need to be heated and formed during the production process, and the temperature is above 120 degrees Celsius, which is much higher than the thermal decomposition of sodium bicarbonate temperature, which will lead to premature foaming of sodium bicarbonate in the production of related foam plastics, resulting in product performance degradation, as well as serious waste

Method used

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Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0037] The preparation method of the white blowing agent having delayed foaming function includes the steps of:

[0038] 1) First, the oxidized polyethylene wax emulsion is first manufactured.

[0039] Weighing a certain amount of oxidized polyethylene wax, according to its acid value, calculates the total carboxyl rats therebet, and then prepares the corresponding mass of alkali, water, emulsifier, film forming agent, input according to the total carboxyl rats. In the reactor having a sealing pressurized function, stirring is stirred until the temperature is controlled between 110-200 degrees Celsius, stirred for 15 minutes, then cooling and cooled to prepare an oxidized polyethylene wax emulsion;

[0040] Among them: The number of molar numbers added is larger than the moles containing the carboxyl group contained in the oxidized polyethylene wax; the mass of water is about 110% to 10000% of the oxidized polyethylene wax mass; the emulsifier mass is the quality of oxidized polye...

Embodiment 1

[0068] Example 1 A white foaming agent having delayed foaming function applied to a PVC foam field

[0069] First, the oxidized polyethylene wax (Lianyungang has a new material technology Co., Ltd. 316 # product), 80 grams of potassium hydroxide (Pharmaceutical Group is purified), 3000 g of deionized water, 50 grams of dodecyl benzenesulfonic acid Sodium (Pharmaceutical Group Analysis Pure), 150 grams of flat plus -10 (Jiangsu Hai'an Petrochemical Plant), 100 grams Tween-60 (Wuxi Yatai Joint Chemical Co., Ltd.), 90 grams of oil, spare.

[0070] All materials were added to the reactor having a sealing pressurized heating function, and then stirring the stirring temperature in 2-5 degrees Celsius / min. The speed is controlled between 100-300 rp. When the stirring is continuously stirred to 130 degrees Celsius, the stirring speed is accelerated between 400-700 revolutions. Continue to 130-180 degrees Celsius, preferably between 135-145 degrees Celsius, maintaining the corresponding ...

Embodiment 2

[0072] Embodiment 2 A white foaming agent having delayed foaming function applied to a PS foam field

[0073] Take the oxidized polyethylene wax 1000 grams (Lianyungang has a new material technology Co., Ltd. 719 # product), 80 grams of potassium hydroxide (Pharmaceutical Group is purified), 3000 grams of deionized water, 50 grams of sodium dodecyl benzene sulfonate National Pharmaceutical Group Analysis Pure), 150 grams of flat plus -10 (Jiangsu Hai'an Petrochemical Plant), 100 grams Tween-60 (Wuxi Yatai Joint Chemical Co., Ltd.), 90 grams of oil, spare.

[0074]All materials were added to the reactor having a sealing pressurized heating function, and then stirring the stirring temperature in 2-5 degrees Celsius / min. The speed is controlled between 100-300 rp. When the stirring is continuously stirred to 130 degrees Celsius, the stirring speed is accelerated between 400-700 revolutions. Continue between 140-145 degrees Celsius, maintaining the corresponding temperature and the ...

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Abstract

The invention relates to a white foaming agent with a delayed foaming function and a preparation method thereof. The foaming agent is of a core-shell structure, a core of the foaming agent adopts sodium bicarbonate particles as a gas forming material, and the shell of the foaming agent is composed of non-volatile matters obtained by volatilizing an oxidized polyethlene wax emulsion. Through an emulsion volatilization method, the sodium bicarbonate particle gas-forming material is wrapped in a shell formed by the non-volatile matters obtained by volatilizing the oxidized polyethlene wax emulsion, so decomposition and gas forming of the sodium bicarbonate core at a temperature higher than the thermal decomposition temperature of the sodium bicarbonate core can be delayed, the function of delaying advanced decomposition and gas forming of sodium bicarbonate is achieved, the performance of foamed plastic can be greatly improved, cost is reduced, and production is convenient.

Description

Technical field [0001] The present invention relates to a foaming technique, particularly a white foaming agent having delayed foaming function. Background technique [0002] Foam plastics are widely used in all areas of the national economy, especially in the fields of heat insulation, loss of sound absorption, absorption load, etc., almost indispensable. At present, the foam is mainly polyurethane, polystyrene foam, polyvinyl chloride foam, polyethylene foam, phenolic foam, and the like. Among them, polyurethane, polystyrene, polyvinyl chloride, is the most widely used, called three major foam varieties. The foaming agent used is primarily azo-like yellow blowing agent, as well as a white foaming agent mainly based on sodium bicarbonate. Compared with the yellow foaming agent, the white foaming agent has the advantages of low price, non-toxic and harmless, and is difficult to replace. However, due to polystyrene, polyvinyl chloride, polystyrene, polyvinyl chloride, etc. in thre...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08J9/08C08L27/06C08L25/06
CPCC08J9/08C08J2203/02C08J2327/06C08J2325/06
Inventor 王语馨陆正
Owner 连云港有道新材料科技有限公司
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