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Flame-retardant and high-impact-resistance polystyrene composition and preparation method thereof

A technology for flame-retardant high-impact polystyrene and its composition, which is applied in the field of flame-retardant high-impact polystyrene composition and its preparation, and can solve the problems of no cost advantage, increased content of brominated flame retardants, rising costs, etc. question

Active Publication Date: 2021-09-10
ORINKO NEW MATERIAL CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Among them, increasing the content of brominated flame retardants will increase the cost significantly, and there is no cost advantage in the industry

Method used

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  • Flame-retardant and high-impact-resistance polystyrene composition and preparation method thereof
  • Flame-retardant and high-impact-resistance polystyrene composition and preparation method thereof
  • Flame-retardant and high-impact-resistance polystyrene composition and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0050] According to the ratio, 8 parts of decabromodiphenylethane, 4 parts of bromotriazine, 2.5 parts of antimony trioxide, 0.1 part of antioxidant 1076, 0.2 part of antioxidant 168, and 0.2 part of modified polytetrafluoroethylene , 1 part of ethylene bisstearamide, 0.5 part of aluminum hypophosphite and 0.2 part of dicumyl chloride were mixed uniformly in a high-speed mixer at a speed of 800-1000 r / min for 5 minutes to obtain a uniform first mixing material;

[0051] Mix 82 parts of HIPS resin and 3 parts of styrene-butadiene-styrene block copolymer in a low mixing pot to obtain the second mixture;

[0052] The first mixed material and the second mixed material are passed through a separate weight loss weighing scale, and several types of twin-screw extruders are added at the same time. 200°C, 200°C, 200°C, 200°C, 210°C, head temperature 210°C, screw length-to-diameter ratio 36:1, screw speed control 400-450r / min, after the material is melted in the screw, it is extruded, ...

Embodiment 2

[0054] According to the ratio, 5 parts of decabromodiphenylethane, 4 parts of bromotriazine, 2.5 parts of antimony trioxide, 0.1 part of antioxidant 1076, 0.2 part of antioxidant 168, and 0.2 part of modified polytetrafluoroethylene , 1 part of ethylene bisstearamide, 0.5 part of aluminum hypophosphite and 0.2 part of dicumyl chloride were mixed uniformly in a high-speed mixer at a speed of 800-1000 r / min for 5 minutes to obtain a uniform first mixing material;

[0055] Mix 85 parts of HIPS resin and 3 parts of styrene-butadiene-styrene block copolymer in a low mixing pot to obtain the second mixture;

[0056] The first mixed material and the second mixed material are passed through a separate weight loss weighing scale, and several types of twin-screw extruders are added at the same time. 200°C, 200°C, 200°C, 200°C, 210°C, head temperature 210°C, screw length-to-diameter ratio 36:1, screw speed control 400-450r / min, after the material is melted in the screw, it is extruded, ...

Embodiment 3

[0058] According to the ratio, 6 parts of decabromodiphenylethane, 4 parts of bromotriazine, 2.5 parts of antimony trioxide, 0.1 part of antioxidant 1076, 0.2 part of antioxidant 168, and 0.2 part of modified polytetrafluoroethylene , 1 part of ethylene bisstearamide, 0.5 part of aluminum hypophosphite and 0.2 part of dicumyl chloride were mixed uniformly in a high-speed mixer at a speed of 800-1000 r / min for 5 minutes to obtain a uniform first mixing material;

[0059] Mix 84 parts of HIPS resin and 3 parts of styrene-butadiene-styrene block copolymer in a low mixing pot to obtain the second mixture;

[0060] The first mixed material and the second mixed material are passed through a separate weight loss weighing scale, and several types of twin-screw extruders are added at the same time. 200°C, 200°C, 200°C, 200°C, 210°C, head temperature 210°C, screw length-to-diameter ratio 36:1, screw speed control 400-450r / min, after the material is melted in the screw, it is extruded, ...

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Abstract

The invention discloses a flame-retardant and high-impact-resistance polystyrene composition and a preparation method thereof. The flame-retardant and high-impact-resistance polystyrene composition is prepared from 70 to 85 parts by mass of HIPS resin, 3 to 5 parts by mass of a flexibilizer, 9 to 14 parts by mass of a brominated flame retardant, 2 to 4 parts by mass of antimony trioxide, 0.1 to 0.5 parts by mass of an antioxidant, 0.1 to 0.3 parts by mass of an anti-dripping agent, 0.5 to 1.0 part by mass of a lubricant and 0.2 to 0.7 parts by mass of auxiliary flame retardants, wherein the auxiliary flame retardants are aluminum hypophosphite and bicummyl. A trace amount of auxiliary flame retardants is added into a bromine-antimony flame-retardant HIPS system, so that the smoldering time required by UL-94 after flame is extinguished is greatly shortened, the requirement for 1.6 mm V-0 level is met, and the flame-retardant and high-impact-resistance polystyrene composition has good mechanical properties, is lower in cost compared with conventional flame-retardant HIPS in the industry, and is higher in application and popularization value.

Description

technical field [0001] The invention belongs to the technical field of polymer material modification, and in particular relates to a flame-retardant high-impact polystyrene composition and a preparation method thereof. Background technique [0002] High-impact polystyrene (HIPS) material, as a general-purpose plastic, is widely used in household appliances, office equipment, instruments, daily appliances and packaging materials, etc. However, the oxygen index of HIPS material is only 17.8, which is a kind of plastic that is extremely flammable. In order to endow it with flame retardant properties and maintain its normal mechanical properties, two methods are commonly used in the industry to modify its flame retardant: ① bromine antimony resistance Flame retardant is used to modify it. This method has high flame retardant efficiency, good mechanical performance retention, good fluidity, and relatively low cost. It is currently the most commonly used modification method in th...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L51/04C08L53/02C08K13/02C08K3/32C08K5/01C08K5/03C08K5/3492C08K3/22
CPCC08L51/04C08L2201/02C08L2205/03C08L2205/035C08L53/02C08K13/02C08K3/32C08K5/01C08K5/03C08K5/3492C08K3/2279
Inventor 黄骎何继辉魏子芳王超李荣群
Owner ORINKO NEW MATERIAL CO LTD