A kind of three-block polypeptide, a collagen biomimetic material formed by the self-assembly of three-block polypeptide
A triblock and polypeptide fragment technology, applied in the field of collagen biomimetic materials, can solve the problems of difficulty in introducing collagen functional sequences and cannot be used to prepare biological materials, etc., and achieves good application potential, wide applicability, and mild conditions. Effect
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Embodiment 1
[0079] Preparation of Example 1 Collagen Biomimetic Material CTC'-393
[0080] 1. Preparation method
[0081] Under the condition of aqueous solution, prepare 8 mg / mL triblock polypeptide K at pH 7.0 3 (GPO) 9 D. 3 solution, the triblock polypeptide K 3 (GPO) 9 D. 3 The structural representation of figure 1 Shown in middle d-f (CTC'-393), triblock polypeptide K 3 (GPO) 9 D. 3 A triple helix structure.
[0082] triblock polypeptide K 3 (GPO) 9 D. 3 solution, heated in a water bath at 40°C for 50 minutes; stop heating, wait for the triblock polypeptide K 3 (GPO) 9 D. 3 The solution was naturally cooled to room temperature, and transferred to 25°C for constant temperature incubation for 36hrs. Triblock Peptide K 3 (GPO) 9 D. 3 The solution becomes cloudy ( image 3 CTC'-393 in the upper middle). Simultaneous triblock polypeptide K 3 (GPO) 9 D. 3 The absorption value of the ultraviolet 313nm corresponding to the assembly is 1.811 ( figure 2 shown in a), t...
Embodiment 2
[0087] Preparation of Example 2 Collagen Biomimetic Material CTC'-494
[0088] 1. Preparation method
[0089] Under the condition of aqueous solution, prepare 5 mg / mL triblock polypeptide K at pH 7.0 4 (GPO)9 D. 4 solution. Triblock Peptide K 4 (GPO) 9 D. 4 The structural characterization results of figure 1 Shown in middle d-f (CTC'-494), the triblock polypeptide K 4 (GPO) 9 D. 4 Has a triple helix structure.
[0090] triblock polypeptide K 4 (GPO) 9 D. 4 solution, heated in a water bath at 37°C for 30 minutes; stop heating, wait for the triblock polypeptide K 4 (GPO) 9 D. 4 The solution was naturally cooled to room temperature, and transferred to 25°C for constant temperature incubation for 48hrs. Triblock Peptide K 4 (GPO) 9 D. 4 The solution becomes cloudy ( image 3 shown in CTC'-494). Triblock Peptide K 4 (GPO) 9 D. 4 The absorption value of the ultraviolet 313nm corresponding to the assembly is 2.153 ( figure 2 shown in a), the dynamic light sc...
Embodiment 3
[0095] Preparation of Example 3 Collagen Biomimetic Material CTC'-595
[0096] 1. Preparation method
[0097] Under the condition of aqueous solution, prepare 10 mg / mL triblock polypeptide K at pH 7.0 5 (GPO) 9 D. 5 solution. Triblock Peptide K 5 (GPO) 9 D. 5 The structural characterization results of figure 1 As shown in g-i (CTC'-595), the three-block polypeptide K 5 (GPO) 9 D. 5 A triple helix structure.
[0098] Triblock Peptide K 5 (GPO) 9 D. 5 solution, heated in a water bath at 30°C for 40 minutes; stop heating, wait for the triblock polypeptide K 5 (GPO) 9 D. 5 The solution was naturally cooled to room temperature, and transferred to 25°C for constant temperature cultivation for 24hrs. The triblock polypeptide K 5 (GPO) 9 D. 5 The solution becomes cloudy ( image 3 shown in CTC'-595). Triblock Peptide K 5 (GPO) 9 D. 5 The absorption value of the ultraviolet 313nm corresponding to the assembly is 2.162 ( figure 2 shown in a), the dynamic light ...
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