Method for rapidly synthesizing lithium cobalt oxide positive electrode material and application
A positive electrode material, lithium cobalt oxide technology, applied in the field of lithium ion materials, can solve the problems of power consumption and time, small specific surface area of lithium cobalt oxide materials, poor rate performance, etc., and achieve the effect of being beneficial to extraction and insertion
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Embodiment 1
[0022] Ultrafast synthesis of lithium cobaltate positive electrode material, according to the following steps:
[0023] Step 1, mix 3.3mol lithium carbonate and 2mol tricobalt tetroxide in a mortar evenly, and then grind to a fine powder, that is, the lithium cobaltate cathode material precursor, and then store the lithium cobaltate precursor in a vacuum desiccator.
[0024] Step 2, the lithium cobaltate cathode material precursor prepared in step 1 is evenly spread on the alumina ceramic sheet (the laying quality is 0.05g / cm 2 ), the aluminum oxide ceramic sheet is placed on the carbon cloth, the carbon cloth is connected to a DC power supply, and the electricity is energized under the air atmosphere. The electrified calcination is performed twice, the current of the first calcination is 12A, and the duration is 30s. After that, the product of the primary calcination is ground and then subjected to the second calcination. The energization current of the second calcination is ...
Embodiment 2
[0029] Ultrafast synthesis of lithium cobaltate positive electrode material, according to the following steps:
[0030] Step 1, mix 3.15mol lithium carbonate and 2mol tricobalt tetroxide uniformly in a mortar, then grind to a fine powder, that is, lithium cobaltate cathode material precursor, and then store the lithium cobaltate precursor in a vacuum desiccator.
[0031] Step 2, the lithium cobaltate cathode material precursor prepared in step 1 is evenly spread on the alumina ceramic sheet (the laying quality is 0.05g / cm 2 ), the aluminum oxide ceramic sheet is placed on the carbon cloth, the carbon cloth is connected to a DC power supply, and the electricity is energized under the air atmosphere. The electrified calcination is performed twice, the current of the first calcination is 11A, and the duration is 20s. After that, the product of the primary calcination is ground and then subjected to the second calcination. The energization current of the second calcination is 16A,...
Embodiment 3
[0035] Ultrafast synthesis of lithium cobaltate positive electrode material, according to the following steps:
[0036] Step 1: Mix 3 mol lithium carbonate and 2 mol tricobalt tetroxide uniformly in a mortar, then grind to a fine powder, that is, the lithium cobaltate cathode material precursor, and then store the lithium cobaltate precursor in a vacuum desiccator.
[0037] Step 2, the lithium cobaltate cathode material precursor prepared in step 1 is evenly spread on the alumina ceramic sheet (the laying quality is 0.05g / cm 2 ), the aluminum oxide ceramic sheet is placed on the carbon cloth, the carbon cloth is connected to a DC power supply, and the electricity is energized under the air atmosphere. The electrified calcining is performed twice, the current of the first calcining is 13A, and the duration is 24s. After that, the product of the first calcining is ground and then second calcined. The electrification current of the second calcining is 40A, and the duration is 60s...
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Abstract
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