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Composite material based on multilayer graphene as well as preparation method and application of composite material

A technology of multi-layer graphene and composite materials, which is applied in the field of air purification, can solve the problems of incompleteness, slow adsorption rate, and inconspicuous removal effect, and achieve the effects of low cost, improved adsorption capacity, and inconspicuous removal effect

Pending Publication Date: 2021-11-05
北京飞燕石化环保科技发展有限公司 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The present invention can realize to low concentration VOC (the described low concentration VOC refers to that concentration is 0.65~3mg / m 3 VOC) for fast and efficient adsorption, which effectively solves the technical problems of existing adsorbents such as ineffective, incomplete, and slow adsorption rates for indoor environments containing low-concentration air pollutants, and can greatly improve the air pollution treatment of the fresh air system The efficiency of the material, and the preparation process is simple, low cost, no secondary pollution, and can be regenerated and reused under certain conditions

Method used

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  • Composite material based on multilayer graphene as well as preparation method and application of composite material
  • Composite material based on multilayer graphene as well as preparation method and application of composite material
  • Composite material based on multilayer graphene as well as preparation method and application of composite material

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Experimental program
Comparison scheme
Effect test

Embodiment approach

[0035] (1) The multi-layer graphene accounts for 0.5wt% to 5wt% of the total mass of the composite material, which can make the composite material have better adsorption performance.

[0036] (2) described multilayer graphene preferably adopts the graphene powder that the physical exfoliation method in the prior art makes, and average sheet is 2~8 layers, and thickness is 1~5 nanometers, and sheet diameter is 0.5~15 microns, The specific surface area is 20~500m 2 / g, which can not only ensure that the multilayer graphene-based composite has good adsorption performance, but also has low cost and good economic benefits.

[0037] (3) The polymer material is at least one of polyvinyl alcohol, polyurethane, silane coupling agent, carboxymethyl cellulose, these polymer materials can carry multi-layer graphene, and can form high Molecular polymer films, so that multi-layer graphene can be supported on activated carbon, and these polymer materials themselves have adsorption propertie...

Embodiment 1

[0064] A kind of composite material based on multilayer graphene, its preparation method comprises the following steps:

[0065] Step b1, dissolving 1 g of polymer material in 199 g of deionized water to prepare a 0.5 wt % polymer material solution.

[0066] Step b2: Take 108.9 g of the polymer material solution prepared in step b1, and disperse 1.1 g of multilayer graphene in the polymer material solution, thereby preparing a 1 wt % multilayer graphene dispersion.

[0067] Step b3, immerse 9.79453 g of activated carbon in the multilayer graphene dispersion prepared in step b2 for 3 hours, take it out and dry it at 80° C., so as to prepare the initial composite material.

[0068]Step b4, activate the initial composite material prepared in step b3 for 3h in a vacuum environment at 120° C. to obtain a composite material based on multilayer graphene, and its scanning electron microscope photo (ie SEM image) is as follows figure 2 shown.

Embodiment 2

[0070] A kind of composite material based on multilayer graphene, its preparation method comprises the following steps:

[0071] Step c1, dissolving 1 g of polymer material in 199 g of deionized water to prepare a 0.5 wt % polymer material solution.

[0072] Step c2, take 105.1 g of the polymer material solution prepared in step c1, and disperse 1.6 g of multilayer graphene in the polymer material solution, thereby preparing a multilayer graphene dispersion with a concentration of about 1.5 wt % .

[0073] Step c3, immerse 10.82081 g of activated carbon in the multilayer graphene dispersion prepared in step c2 for 3 hours, take it out and dry it at 80° C., so as to prepare the initial composite material.

[0074] Step c4, activate the initial composite material prepared in step c3 in a vacuum environment at 120° C. for 3 h, so as to obtain a composite material based on multilayer graphene, and its scanning electron microscope photo (ie SEM image) is as follows image 3 shown...

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Abstract

The invention discloses a composite material based on multi-layer graphene and a preparation method and application of the composite material. The composite material based on the multi-layer graphene is a mixture formed by loading the multi-layer graphene on activated carbon through a high polymer material. The preparation method comprises the following steps: dispersing multi-layer graphene into a high polymer material solution to prepare a multi-layer graphene dispersion liquid, then putting activated carbon into the multi-layer graphene dispersion liquid to be soaked for 2-4 hours to prepare an initial composite material, and then activating the initial composite material in a vacuum environment of 100-150 DEG C for 2-4 hours to prepare the composite material based on the multi-layer graphene. According to the present invention, the low-concentration VOC can be rapidly and efficiently adsorbed, the technical problems of unobvious and incomplete removal effect, slow adsorption rate and the like of the existing adsorbent on the indoor environment containing the low-concentration air pollutants are effectively solved, the preparation process is simple, the cost is low, the secondary pollution is not generated, and the adsorbent can be regenerated and repeatedly used under a certain condition.

Description

technical field [0001] The invention relates to the technical field of air purification, in particular to a multi-layer graphene-based composite material and its preparation method and application. Background technique [0002] At present, many products such as paints, floors, and furniture used for interior decoration will release air pollutants such as benzene series, formaldehyde, and VOC (Volatile Organic Compounds) at low concentrations, and these air pollutants will continue to be released For a long period of time (about two to four months, some even longer), these low-concentration air pollutants will not cause much harm to the human body in a short period of time, but if you live in such an environment for a long time, then It will cause some irreversible damage to the human body. [0003] Since these air pollutants are released in low concentrations, are colorless and largely odorless, they are difficult to detect. At present, traditional activated carbon is usua...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J20/20B01J20/30B01J20/32B01D53/02
CPCB01J20/20B01J20/3078B01J20/3204B01J20/3289B01J20/3291B01D53/02B01D2253/25B01D2257/708B01D2258/06Y02A50/20
Inventor 孙桂芳徐传海刘太奇吴锦程赵晓敏韩子夜侯兴汉申静
Owner 北京飞燕石化环保科技发展有限公司