The invention discloses a preparation method of
rosin-based
polyamine, a product and application thereof, and belongs to the technical field of bio-based adhesives, the preparation method comprises the following steps: using
toluene as a
solvent, using
thionyl chloride to carry out acylating chlorination on disproportionated
rosin, after the reaction is finished, carrying out rotary
evaporation to remove
toluene, then reacting with
methanol, and carrying out methyl esterification on the disproportionated
rosin to obtain methyl esterified rosin; reacting the obtained methyl esterified rosin with acid to obtain nitrated rosin methyl ester; carrying out reduction reaction on the obtained nitrated rosin methyl ester and
iron powder to obtain rosin-based
polyamine; wherein the acid comprises one or more of
nitric acid and
sulfuric acid. The prepared rosin-based
polyamine is synthesized into rosin-based
isocyanate through a phosgenation method, and the rosin-based
isocyanate is glued to prepare a shaving board, a
fiberboard and a plywood with the thickness of 18 mm; the test method refers to GB / T17657-2013, and each performance of the artificial board meets the requirements of the
national standard (P2 type in GB / T 4897-2015) (MDF-FN type in GB / T 18259-2018) (class II board in GB / T 18259-2009).