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Continuous electric thermochromic fiber based on polyester filament yarn and preparation method of continuous electric thermochromic fiber

A polyester filament and color-changing technology, applied in fiber processing, fiber types, textiles and papermaking, etc., can solve the problems of difficult mass production, high cost, difficult large-scale continuous production, etc., and achieve short response time, Low cost, smooth and even surface effect

Active Publication Date: 2021-11-16
SUZHOU UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

But the shortcomings are also obvious. They developed electrothermochromic fabrics, which have certain limitations in application and are difficult to produce in large-scale continuous production, and because the conductive material is graphene, the cost is high and it is difficult to achieve continuous production. Mass production

Method used

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  • Continuous electric thermochromic fiber based on polyester filament yarn and preparation method of continuous electric thermochromic fiber
  • Continuous electric thermochromic fiber based on polyester filament yarn and preparation method of continuous electric thermochromic fiber
  • Continuous electric thermochromic fiber based on polyester filament yarn and preparation method of continuous electric thermochromic fiber

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Embodiment 1

[0045] This embodiment provides a method for preparing continuous electrothermochromic fibers based on polyester filaments, comprising the following steps:

[0046] 1. Preparation of polyester conductive filaments by electroless deposition

[0047] 1) Wind the polyester filament on a reel with a diameter of 5 cm for 20 minutes, and then remove it from the reel. The fiber can maintain the shape of a ring. Treat the polyester filament with a standard NaOH solution for 60 minutes to remove surface grease and impurities.

[0048] 2) Treat the surface of polyester filament with a plasma cleaning machine for 5 minutes to improve its hydrophilic property; then place it in an ethanol solution of 2% (v / v) vinyltrimethoxysilane (VTMS) and soak it for 15 minutes to make it The silane reacts with the hydroxyl groups on the fiber surface.

[0049] 3) Using potassium persulfate as an initiator, put the fiber modified by VTMS into an aqueous solution of methacryloyloxyethyltrimethylammonium...

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Abstract

The invention discloses a preparation method of continuous electric thermochromic fiber based on polyester filament yarn. The method comprises the following steps of S1, winding the polyester filament yarn in a ring shape, and removing grease and impurities on the surface of the polyester filament yarn; S2, depositing a metal copper plating layer on the surface of the polyester filament yarn through an electroless deposition process; S3, carrying out annealing treatment on the polyester filament yarn to obtain polyester conductive filament yarn; and S4, enabling the polyester conductive filament yarn to pass through a groove filled with thermochromic ink, drying the polyester conductive filament yarn through a heating device, and winding the polyester conductive filament yarn on a rolling shaft to obtain the continuous electric thermochromic fiber, wherein in the step S2, a compound stabilizer is added into a copper plating solution of electroless deposition, the compound stabilizer is composed of potassium ferrocyanide and 2,2'-dipyridyl, the concentration of the potassium ferrocyanide is 5-10 mg / L, and the concentration of the 2,2'-dipyridyl is 5-10 mg / L. The preparation method provided by the invention can realize continuous production of the electric thermochromic fiber, the production cost is low, the fiber diameter is controllable, and the obtained fiber has high conductivity.

Description

technical field [0001] The invention relates to the technical field of electrochromic fibers, in particular to an electrothermochromic fiber based on polyester filament and a preparation method thereof. Background technique [0002] With the increasing application of smart textiles, color-changing fiber technology has also developed rapidly. However, color-changing fibers are not wearable, costly, and cannot be mass-produced, so they are not complete in practical applications. , which greatly limits the industrial development of color-changing fibers. Therefore, it is of great scientific research value to produce continuous intelligent color-changing fibers with excellent properties through a low-cost process. [0003] Electrothermochromic fibers refer to fibers that can reversibly change color under the condition of applying a certain voltage, presenting an adjustable visual change. Its structure and process are relatively simple, and the preparation process of microcapsu...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D06M11/83D06M11/38D06M13/513D06M15/267D06M11/00D06M13/00D06M15/00D06M101/32
CPCD06M11/83D06M11/38D06M13/5135D06M15/267D06M11/00D06M13/00D06M15/00D06M2101/32
Inventor 李雅娟胡建臣张林星黄璇
Owner SUZHOU UNIV
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