The invention discloses a preparation method of a spherical CsPbX3@SiO2 (X=Cl, Br, I)
quantum dot with high stability and water
solubility. The preparation method adopts an improved thermal injectiontechnology and takes a CsPbX3
quantum dot as a precursor, and mainly comprises the following steps: adding
tetramethyl orthosilicate (TMOS) or
tetraethyl orthosilicate (TEOS) or a mixture of TMOS andTEOS into a
toluene solution containing a trace amount of water, conducting full reacting for a certain time in a stirring state, and carrying out low-speed
centrifugation, washing and
drying on an obtained precipitate to obtain the high-stability water-soluble spherical CsPbX3@SiO2 (X=Cl, Br, I)
quantum dot. Synthesis process is simplified, raw materials are simple, the cost is low, the
process equipment requirement is low, other
impurity elements are not introduced or generated in the preparation process, the method has the advantages that the purity of the product is improved, the environmental
pollution is reduced, the stability and the water
solubility of the prepared spherical CsPbX3@SiO2 (X=Cl, Br and I)
quantum dot are greatly improved, and conditions are provided for application of full-inorganic
perovskite quantum dots in biological and water-based environments.