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Cement kiln flue gas carbon dioxide capture and storage system based on hydrate method

A carbon dioxide and storage system technology, applied in carbon capture, cement production, carbon compounds, etc., can solve the problems that the generated heat cannot be dissipated in time, the nucleation of hydrate is slow, and the continuous operation cannot be achieved, so as to achieve low cost, good effect, and time short effect

Active Publication Date: 2021-11-26
SINOMA INT ENG
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Problems solved by technology

At present, the hydrate method has achieved certain results in the field of carbon capture, but there are still some problems, such as the inability to operate continuously in a large flow of flue gas, the slow nucleation of hydrates, and the formation of heat that cannot be dissipated in time and accumulates in droplets. wait

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  • Cement kiln flue gas carbon dioxide capture and storage system based on hydrate method

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Embodiment Construction

[0027] The present invention will be further described in detail below in conjunction with the accompanying drawings.

[0028] The invention discloses a method for capturing CO by using a hydrate method suitable for the cement industry. 2 system that utilizes CO 2 Under certain conditions, it can form CO with water 2 Characteristics of Hydrate Crystallization for CO in Cement Kiln Flue Gas 2 capture and storage. In this method, an aqueous solution containing a certain proportion of dodecyltrimethylammonium chloride and tetrabutylammonium bromide is used as a capture agent, and the nucleation process of hydrate is realized by means of atomization and spraying, and the obtained CO-enriched 2 Hydrate crystals are separated under reduced pressure and heating. CO removal is achieved through a two-stage hydration reaction process and a two-stage hydration decomposition process. 2 Continuous release, get the CO concentration as high as 99% 2 gas and is stored through cooling, d...

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Abstract

The invention discloses a cement kiln flue gas carbon dioxide capture and storage system based on a hydrate method, which comprises a waste gas pre-treatment unit and a gas inlet pressurization refrigeration unit which are connected in sequence, and the outlet of the gas inlet pressurization refrigeration unit is connected with the inlet of a hydration reaction tank first-stage chamber for a first-stage hydration reaction; an outlet of the hydration reaction tank first-stage chamber is connected with an inlet of the hydration decomposition tank first-stage chamber for first-stage separation, the outlet of the hydration decomposition tank first-stage chamber is connected with an inlet of a hydration reaction tank second-stage chamber for a second-stage hydration reaction, and an outlet of the hydration reaction tank second-stage chamber is connected with an inlet of the hydration decomposition tank second-stage chamber for second-stage separation; an outlet of the hydration decomposition tank second-stage chamber is connected with a CO2 cooling recovery unit; and a liquid supply unit is used for respectively supplying liquid to the hydration reaction tank first-stage chamber and the hydration reaction tank second-stage chamber for hydration reaction. The continuous release of CO2 is achieved through two-stage hydration reaction and two-stage hydration decomposition, CO2 gas with the concentration as high as 99% is obtained, and the CO2 gas is stored through cooling, drying and compression.

Description

technical field [0001] The invention relates to a cement industry carbon capture system, in particular to a cement kiln flue gas carbon dioxide capture and storage system based on a hydrate method. Background technique [0002] The production of cement is a high-energy-consuming process, and energy consumption accounts for about 2% of the global primary energy consumption. Since the production process mainly uses carbon-intensive fuels, such as coal, the cement industry has become a huge source of carbon dioxide emissions. In addition to the energy consumption process, the calcination process of cement clinker also produces a large amount of carbon dioxide. [0003] Carbon capture and storage technology (CCS) is one of the core strategies of the comprehensive carbon dioxide management program. The advantage of this technology is that it can not only effectively reduce carbon emissions, but also generate economic benefits, and does not require large-scale production systems. ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C01B32/50C04B7/43
CPCC01B32/50C04B7/475Y02P20/10Y02P20/129Y02P40/18
Inventor 刘仁越赵美江张健吴梦欣朱刚汤升亮宿向超宋华庭姜凯冯冬梅朱永长陈翼潘轶
Owner SINOMA INT ENG