The invention provides novel wood-like composite materials and methods for preparation thereof. The wood-like composite materials can be readily produced from widely available, low cost precursor materials by a production process that involves casting in a mold that is suitable for large-scale production. The precursor materials include calcium silicate, for example, wollastonite, and particulate filler materials which comprise silicon dioxide-rich materials such as quartz, mica, feldspar, sand and glass. Additives can include calcium carbonate-rich and magnesium carbonate-rich materials. Various additives can be used to fine-tune the physical appearance and mechanical properties of the composite material, such as colorants such as particles of colored materials, such as, and pigments (e.g., black iron oxide, cobalt oxide and chromium oxide). These wood-like composite materials exhibit visual patterns unique to wood as well as display compressive strength, flexural strength and water absorption superior to that of wood.