Micro-expansive cement prepared from fluidized bed combustion ash, and preparation method of cement

A sulfur-fixing ash and micro-expansion technology, applied in the field of materials, can solve the problems of limited solid waste absorption, failure to alleviate the pressure of solid waste environment, and less research and application of sulfur-fixing ash expansion agents.

Pending Publication Date: 2021-12-14
长江三峡技术经济发展有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] At present, cement concrete expansion agents mainly include sulphoaluminate expansion agents (such as UEA, alunite expansion agent EA-L type, etc.), calcium oxide expansion agents, magnesium oxide expansion agents, and composite expansion agents. The agent can achieve the effect, but the absorption effect on solid waste is limited, and the pressure of solid waste discharge on the environment cannot be alleviated.
[0003] Sulfur-fixing ash is produced by burning sulfur-containing coal and limestone and other sulfur-fixing agents in circulating fluidized bed boilers at about 900°C. The production of slag is increasing year by year, but it has not been fully utilized, and the research and application of sulfur-fixed ash as an expansion agent is less

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028]The proportioning is 20% of clinker, 35% of slag, 20% of sulfur-fixing ash, 25% of fly ash, and 0.5% grinding aid of the aforementioned materials. Grinding with coal ash, then adding clinker, slag and grinding aids to continue grinding), the expansion rate and drying shrinkage test were respectively in accordance with the standard "JC / T313-2009 Expansion Cement Expansion Rate Test Method", according to JC / T603- 2004 "Cement Mortar Drying Shrinkage Test Method", the standard consistency water consumption is 153.5ml, the 28-day linear expansion rate can reach 0.15%, the 28-day linear shrinkage rate can reach 0.13%, and the 28-day compressive strength is 43.7MPa, stable Sex (Ray's method) 1.8mm, good stability.

Embodiment 2

[0030] The ratio is 25% clinker, 30% slag, 25% sulfur-fixed ash, 20% fly ash, and 0.5% grinding aid of the aforementioned materials. After grinding according to the patent method, the expansion rate and dry shrinkage test are respectively According to the standard "JC / T313-2009 Test Method for Expansion Rate of Expansive Cement" and JC / T 603-2004 "Test Method for Drying Shrinkage of Cement Mortar", the standard consistency water consumption is 155.0ml, and the 28-day linear expansion rate can reach 0.18%. The 28-antenna dry shrinkage rate can reach 0.09%, the 28-day compressive strength is 42.2MPa, and the stability (Raye method) is 2.1mm, which is good stability.

Embodiment 3

[0032] The ratio is 25% clinker, 25% slag, 30% sulfur-fixed ash, 20% fly ash, and 0.5% grinding aid for the aforementioned materials. After grinding according to the patent method, the expansion rate and drying shrinkage test are respectively According to the standard "JC / T313-2009 Test Method for Expansion Rate of Expansive Cement" and JC / T 603-2004 "Test Method for Drying Shrinkage of Cement Mortar", the standard consistency water consumption is 157.5ml, and the 28-day linear expansion rate can reach 0.23%. The 28-antenna dry shrinkage rate can reach 0.06%, the 28-day compressive strength is 41.8MPa, and the stability (Raye method) is 2.4mm, which is good stability.

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Abstract

The invention provides a micro-expansive cement prepared from fluidized bed combustion ash, and a preparation method of the cement. The micro-expansive cement comprises, by weight, 20-30% of fluidized bed combustion ash, 20-28% of clinker, 17-40% of slag, 20-25% of fly ash and a grinding aid, and the addition amount of the grinding aid is less than or equal to 0.5% of the total mass of the materials. The micro-expansive cement with stable performance is prepared by adjusting the matching proportion of the fluidized bed combustion ash, the clinker, the slag and the fly ash, and has the characteristics of high strength and small dry shrinkage coefficient. The preparation method of the micro-expansive cement effectively consumes the sulfur-fixing ash residues, is economical and energy-saving, not only improves the comprehensive utilization of the solid wastes, but also relieves the pressure of the environment, and accords with the green and environment-friendly concept.

Description

technical field [0001] The invention belongs to the field of materials, and relates to the reuse of sulfur-fixed ash, which is a solid waste produced by a circulating fluidized bed boiler. Specifically, the sulfur-fixed ash, clinker, slag, and fly ash are used as raw materials to add grinding aids together. Grinding to prepare micro-expansion cement and the preparation method of the cement. Background technique [0002] At present, cement concrete expansion agents mainly include sulphoaluminate expansion agents (such as UEA, alunite expansion agent EA-L type, etc.), calcium oxide expansion agents, magnesium oxide expansion agents, and composite expansion agents. The agent can achieve the effect, but its absorption effect on solid waste is limited, and it fails to alleviate the pressure of solid waste discharge on the environment. [0003] Sulfur-fixing ash is produced by burning sulfur-containing coal and limestone and other sulfur-fixing agents in circulating fluidized bed...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B7/26C04B7/24C04B7/153C04B7/36C04B22/06C04B103/52
CPCC04B7/243C04B7/1535C04B7/36C04B40/0039C04B2103/52C04B22/062C04B12/04C04B24/026C04B24/122Y02P40/10
Inventor 刘利民刘奉霞李来芳戴刚窦立刚李建平张继屯吴世斌刘雪锋陈雪万刘益唐红平任月娟陈鸿熹韩淋
Owner 长江三峡技术经济发展有限公司
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