Adhesive, adhesive for packaging material for battery, laminate, packaging material for battery, container for battery, and battery
A packaging material and adhesive technology, which can be used in large-sized batteries/battery packs, small-sized batteries/battery packs, packaging, etc. It can solve the problems of poor heat sealability and insufficient oxygen barrier properties, and achieve excellent molding. sexual effect
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[0179] Hereinafter, the present invention will be described in more detail with reference to specific synthesis examples and examples, but the present invention is not limited to these examples. In addition, in the following examples, unless otherwise specified, "part" and "%" mean "part by mass" and "% by mass", respectively.
[0180]
Synthetic example 1
[0181] (Synthesis Example 1) Synthesis of Polyester Polyol (A1-1)
[0182] Using 410 parts of terephthalic acid, 66 parts of isophthalic acid, 173 parts of adipic acid, 238 parts of cyclohexanedimethanol, 116 parts of 1,4-butanediol, and 142 parts of 1,6-hexanediol, according to Conventional methods to synthesize polyester polyols. The obtained polyester polyol (A1-1) has crystallinity, a number average molecular weight (Mn) of 10000, a glass transition temperature (Tg) of 2°C, a melting point of 115°C, and a heat of fusion (ΔH) of 9.9J / g, the hydroxyl value is 11 mgKOH / g, and the acid value is 1.7 mgKOH / g.
Synthetic example 2
[0183] (Synthesis Example 2) Synthesis of Polyester Polyol (A1-2)
[0184] Using 411 parts of terephthalic acid, 66 parts of isophthalic acid, 177 parts of adipic acid, 248 parts of cyclohexanedimethanol, 116 parts of 1,4-butanediol, and 129 parts of 1,6-hexanediol, according to Polyester polyols were synthesized by conventional methods. The obtained polyester polyol (A1-2) has crystallinity, a number average molecular weight (Mn) of 22000, a glass transition temperature (Tg) of 4°C, a melting point of 141°C, and a heat of fusion (ΔH) of 0.49J / g, the hydroxyl value is 4mgKOH / g, and the acid value is 2.3mgKOH / g.
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