Anti-static coating, preparation method thereof, and blister product

An anti-static coating and material technology, applied in conductive coatings, polyester coatings, coatings, etc., can solve problems such as the inability to meet the application requirements of high-end products, the inability of anti-static coatings to meet the requirements, and the lack of coating light transmittance requirements. , to achieve good anti-static effect, improve appearance quality, good anti-static effect

Active Publication Date: 2022-01-11
安徽辅朗光学材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Different industries have different requirements for the resistance value and light transmittance of anti-static coatings; The oil tank requires a resistance value of 108Ω~1011Ω. The above two fields do not require the light transmittance of the coating; Static indicators, durability, transparency and alcohol resistance all have high requirements, and ordinary antistatic coatings cannot meet the requirement

Method used

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  • Anti-static coating, preparation method thereof, and blister product
  • Anti-static coating, preparation method thereof, and blister product
  • Anti-static coating, preparation method thereof, and blister product

Examples

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preparation example Construction

[0050] In still other embodiments, the present invention also provides a method of preparing an anti-static coating, which comprises the steps of:

[0051] Step S1: Supply materials in accordance with the components of the anti-static coating according to the present invention;

[0052] Step S2: Mix the single wall carbon nanotubes with a portion of water to coarse milling to obtain a single-walled carbon nanotube dispersion;

[0053] Step S3: Mix the single-walled carbon nanotube dispersion and dispersing agent, then perform crushing, resulting in a crushing material;

[0054] Step S4: Mix the crushing material with alcohol and another part of water, then carry out the grinding, the grinding process is added to the material to the material, filtered, filtered, and filtered, extract the filtrate to obtain the present invention. Anti-static coating.

[0055] The above preparation method is simple, low cost, suitable for scale production.

[0056] Specifically, in some embodiments, ...

Embodiment 1

[0067] 1) After mixing 2G fibrous single-walled carbon nanotube powder TNSSH and 800 g of water, it is divided into four ball grinding tanks (volume 300ml) of the uniform distribution of the planetary ball mill, and there are a variety of different diameters in the ball mill. The stainless steel beads were 1 mm, 2 mm, 3 mm, 4mm, 5 mm, etc., respectively, and was coarse milling the single-walled carbon nanotube dispersion by 500 rpm tension ball.

[0068] 2) In the coarse mills, 4G BASF TAMOL NN8906 and 2GPVP K30 were added to the coarse mill, and the mixture was mixed and uniformly mixed in a supersonic vessel of a double-layer glass volume (built-in circulation condensation). Water), use ultrasonic cell crusher (beam φ6cm), ultrasonic power 80W ~ 120W, ultrasonic time 4s ~ 8S, intermittent 4S ~ 8S, total ultrasound 30min;

[0069] 3) Add 100 g of water and 100 g isopropanol to the product of step 2), using a sand mill (2L, 1 0.5 μm zirconia bead, filling rate of 70% to 80%), unde...

Embodiment 2

[0072] 1) After mixing 0.2 g of fibrous single wall carbon nanotube powder TNSSH and 800 g of water, it is divided into four ball grinding tanks (volume 300ml) of the uniform distribution of the planetary ball mill, and there are a variety of different diameters in the ball mill. The stainless steel beads are 1 mm, 2 mm, 3 mm, 4mm, 5 mm, etc., respectively, and the single-walled carbon nanotube powder is coarsely grinded by 500 rpm rotary speed ball.

[0073] 2) In the coarse grinding single-walled carbon nanotube dispersion (about 800 g), 0.4 g of BASF TAMOL NN 8906 and 0.2 g of PVP K30 is added, and the mixing is mixed and homogeneous and is placed in an ultrasonic container having a volume of 1L. (Built-in circulating condensed water), with ultrasonic cell crusher (change galvanic φ6cm), ultrasonic power 80W ~ 120W, ultrasonic time 4s ~ 8S, intermittent 4S ~ 8S, total ultrasound 30min;

[0074] 3) Add 100 g of water and 100 g isopropanol to the product of step 2), using a sand ...

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Abstract

The invention provides an antistatic coating, a preparation method thereof, and a blister product. The antistatic coating is prepared from, by weight, 0.02 to 0.4 part of single-walled carbon nanotubes; 0.06 to 1.5 parts of a dispersing agent; 1 to 10 parts of water-based hyperbranched polyester resin; 0.2 to 0.6 part of a fluorine wetting leveling agent; 75 to 95 parts of water; and 5-25 parts of alcohol. Compared with the traditional anti-static coating for the blister product, the anti-static coating disclosed by the invention has good anti-static effect, alcohol wiping resistance, adhesive force, transparency and ultraviolet aging resistance on the surface of the blister product. And a coating layer formed by the anti-static coating shows excellent resistance stability in the plastic uptake stretching process, and meets the requirement of large-size plastic uptake.

Description

Technical field [0001] The present invention relates to the field of coating materials, and more particularly to an anti-static coating, a preparation method thereof, and a blister article. Background technique [0002] Anti-static coating is a functional coating, accompanied by the continuous improvement of the development of the microelectronics industry, and has achieved increasing application and development. Different industries have different resistance values ​​and light transmittance requirements of anti-static coatings; such as floor coating requirements resistance value of 10 4 Ω ~ 10 9 Ω, steel oil tank requires resistance value of 10 8 Ω ~ 10 11 Ω, the above two fields have no requirements for the light transmittance of the coating; the field of anti-static indicators, durability, transparency and mexicity, and the ordinary anti-static coating cannot be satisfied. Require. [0003] At present, the anti-static coating for the plastic products in the market is mainly a ...

Claims

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Application Information

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IPC IPC(8): C09D167/00C09D5/24C09D7/47C09D7/20
CPCC09D167/00C09D5/24C09D7/47C09D7/20C08K2201/011C08K3/041
Inventor 张景春司家林
Owner 安徽辅朗光学材料有限公司
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