Patents
Literature
Patsnap Copilot is an intelligent assistant for R&D personnel, combined with Patent DNA, to facilitate innovative research.
Patsnap Copilot

459results about How to "Improve alcohol resistance" patented technology

Polyurethane aqueous dispersion and preparation method thereof

The invention discloses a polyurethane aqueous dispersion and a preparation method thereof. The preparation method comprises the following steps: firstly, mixing trimethylolpropane or glycerol and acid anhydride and preparing a carboxylic acid type hydrophilic monomer; on the basis of molar parts, adding 20-60 parts of polymer dibasic alcohol, 4-10 parts of carboxylic acid type hydrophilic monomer and 30-60 parts of a diisocyanate monomer into a reactor, heating to 60 DEG C-100 DEG C and carrying out heat preservation; adding1-10 parts of small-molecular dibasic alcohol, 2-10 parts of a non-ionic hydrophilic chain extender and 1-6 parts of a cross-linking agent and reacting until the content of NCO is less than 5%; and adjusting the viscosity of the reactant, cooling, adding a neutralizing agent for neutralizing, adding water for emulsifying, adding an amine chain extender and removing the solvent by distillation to obtain the polyurethane aqueous dispersion. The carboxylic acid type hydrophilic monomer has stable performance and low cost, the polyurethane aqueous dispersion prepared from the carboxylic acid type hydrophilic monomer has high content of solids and the coating has relatively high hardness and excellent chemical product resistance.
Owner:SOUTH CHINA UNIV OF TECH

Polypyrrolone/sulfonated polymer composite proton exchange membrane material, and preparation method and application thereof

The invention discloses a polypyrrolone / sulfonated polymer composite proton exchange membrane material, and a preparation method and an application thereof. The composite proton exchange membrane material is prepared with the method comprising the steps that: (1) under the protection of an inert atmosphere, aromatic tetraamine monomer, aromatic dianhydride monomer, and a catalyst are subjected to an in-situ polymerization reaction in a sulfonate polymer solution, such that a membrane-forming liquid comprising a polypyrrolone prepolymer is obtained; and (2) the membrane-forming liquid is coated on a carrier, and heating treatment membrane preparation is carried out; cooling and demolding are carried out after membrane preparation is finished; the obtained membrane is transformed by washing by using an acid solution, such that the polypyrrolone / sulfonated polymer composite proton exchange membrane material is obtained. With the method provided by the invention, the components are dispersed more uniformly, and operation is simpler. The prepared composite membrane has good mechanical strength and conductivity. Compared with a non-modified sulfonated polymer, size stability and alcohol resistance are greatly improved. The membrane material can be used in fields such as proton exchange membrane of proton exchange membrane fuel cell, ion exchange resin, membrane separation, sensor, and the like.
Owner:TSINGHUA UNIV

Electroplating effect imitated plastic paint and preparation method, diluent and process of using same

InactiveCN101157813AStrongly oriented alignmentEasy alignmentCoatingsIsobutanolAcrylic resin
The invention discloses a plastic paint with simulated electroplating effect. The composition and the weight ratio of the invention are as follows: 30 to 45 of acrylic resin with 50 percent of solid content and 70 to 90 DEG C of Tg, 20 to 30 of cellulose acetate butyrate with 20 percent of solid content, 8 to 12 of triad copolymer vinyl chloride-acetate resin with 30 percent of solid content, 6 to 10 of non-floating aluminum and silver pulp with an average diameter less than or equal to 20 Mum, 0.3 to 0.5 of dispersant, 0.2 to 0.4 of flatting agent, 0.4 to 0.6 anti-settling agent, 6.0 to 10.0 of toluene, 3.5 to 6.0 of ethyl acetate, 3.5 to 6.0 methy isobutyl ketone, 3.0 to 5.0 of isobutanol and 4.0 to 7.0 of glycol butyl ether. The special diluent of the invention, according to the weight ratio, is made from the following components evenly mixed: 20 of white gas, 10 of toluene, 22 of ethyl acetate, 15 of acetone, 25 of isobutanol and 8 of glycol butyl ether. The main paint which comprises the composition and the diluent are evenly mixed according to the ratio of 1: 2-3, then the mixture is used for spray coating; the metallic appearance of the paint film obtained is very close to the effect of the electroplating, and the paint film has good alcohol resistance with high hardness and strong wear resistance, and also has simple process. The aluminum and silver pulp used is a common type, the cost of which is only 5 percent to 10 percent of the simulated electroplating aluminum and silver pulp and about 2 percent of electrosilvering.
Owner:SHENZHEN GRANDLAND ENVIRONMENTAL COATING CO LTD

Humidity and ultraviolet dual-cured polyurethane woodware coating and preparation method thereof

The invention discloses humidity and ultraviolet dual-cured polyurethane woodware coating and a preparation method thereof. A synthesis method includes synthesizing initial polyurethane polymer I, polyurethane pre-polymer II, polyurethane pre-polymer III, polyurethane acrylate oligomer and ultraviolet cured woodware coating. The humidity and ultraviolet dual-cured polyurethane woodware coating is mainly prepared by aliphatic diisocyanate, dihydric alcohol pre-polymer, polyhydroxy acid, epoxy resin and hydroxy acrylic ester and the like, and by adding auxiliaries such as photoinitiators, flatting agents, defoamers, substrate wetting agents and catalysts, the ultraviolet cured woodware coating is prepared. The ultraviolet cured woodware coating can form films and be cured under irradiation of ultraviolet, also can be cured by humidity in the air within 5 hours at the room temperature, and has the advantages of high solid, NCO (isocyanate) group content and adhesion force, fine resistance to chemical corrosion, high film coating hardness and fine storage stability and the like, can be used for irregular coating surfaces, hone finished UV (ultraviolet) paint and UV colored paint and the like where cannot be irradiated by the ultraviolet.
Owner:广州常圣新材料科技有限公司

Water-based paint for quick-drying alcohol-resistance plastics and preparation method thereof

The invention discloses a water-based paint for quick-drying alcohol-resistance plastics, comprising the following components by weight parts: 20-80 parts of modified polyacrylic ester water dispersoid, 1-25 parts of coloring pigment paste, 0-10 parts of filler pump, 5-25 parts of film formation assistant, 0.5-10 parts of assistant for water-based paint, and 10-50 parts of water. The invention further discloses a preparation method of the water-based paint, comprising the following steps: the water, the film formation assistant, polymer water dispersoid resin and the assistant for partial water-based paint are added in a make-up tank and are stirred uniformly, and then the coloring pigment paste and the assistant for the remaining partial water-based paint are sequentially added in and are stirred uniformly, the viscosity and pH value are regulated, filtering and discharging are carried out to obtain the water-based plastic paint finished products. The water-based paint is used for coating surface of the plastics, so as to achieve good decoration effect; in addition, the performance of the water-based paint is equivalent to that of solvent plastic paint, the water-based paint has good alcohol resistance and can be dried at 50 DEG C for 10 minutes, so as to meet the process requirements of manufacturers who use the solvent plastic paint at present.
Owner:GUANGZHOU KINTE IND

Multi-layer carbinol resistance compound film for decomposition-resisting fuel battery and its making method

The invention relates to the proton exchange membrane which is used for the fuel cell; put concretely it is an multi layered anti-alcohol compound membrane for anti- degenerating the fuel cell; is compound a layer Nafion proton exchange membrane which includes H2O2 decomposition catalyst on the altogether amixing hydrocarbon compound proton exchange membrane side or two sides. Its preparation method is, Nafion alcohol solution with the same volume high boiling point solvent, sets in the flask to reduce pressure distillation, removes alcohol, prepares the Nafion-high boiling point solvent solution, joins the H2O2 decomposition catalyst, the super-sonic surges 30 minutes, match the solution with H2O2 decomposition catalyst / (H2O2 decomposition catalyst +Nafion) load ratio is 1-10%, the solution compound altogether mixing hydrocarbon compound proton exchange membrane side or two sides, after treats solvent volatility, puts in the vacuum drying oven, under 120-160 degree centigrade, handing 2-8 hours, namely obtains the multilayered anti- mellow compound membrane which is used for anti- degeneration fuel cell. The multi layered anti-alcohol compound membrane for anti- degenerating the fuel cell in the invention has good anti-alcohol performance, high conductivity, the high anti-degeneration ability, good mechanics machine capability,the low cost and so on characteristic.
Owner:BEIJING JIAOTONG UNIV

Self-breathing direct methanol fuel cell monomer based on porous metal fiberboard

The invention discloses a self-breathing direct methanol fuel cell monomer based on a porous metal fiberboard. The cell monomer comprises an anode fuel chamber, a cell working unit and a cathode open type end plate, wherein the cell working unit comprises an anode collector plate, a membrane electrode and a cathode collector plate; two sides of the membrane electrode are respectively provided with the anode collector plate and the cathode collector plate; the anode fuel chamber and the cathode open type end plate used as a cell shell are respectively arranged at the outer sides of the anode collector plate and the cathode collector plate; the middle part of the anode collector plate is provided with a porous metal fiberboard, the porous metal fiberboard is formed by sintering copper metal fibers with diameter of 20-200 mu m, the porosity is 70%-90%, the permeability is 10<-12>-10<-9>m<2>, and the average pore size is 50 mu m to 500 mu m. According to the invention, because of the adoption of the porous metal fiberboard, the methanol penetration problem can be effectively solved and effective water management is realized, thus the fuel availability of the passive self-breathing direct methanol fuel cell can be improved and the output performance of the cell can be improved.
Owner:SOUTH CHINA UNIV OF TECH

Method for modifying sulfonated polyaryetherketone and method for preparing polymer electrolyte material

The invention relates to a method for modifying sulfonated polyaryetherketone and a method for preparing a polymer electrolyte material, and belongs to the technical field of the preparation of functional polymer materials. The method comprises the following steps: dissolving the sulfonated polyaryetherketone in a solvent; introducing inert gas and adding a reducing agent with stirring; performing vacuum drying to obtain reduced and modified sulfonated polyaryetherketone; adding a catalyst and a crosslinker into the solution of reduced and modified sulfonated polyaryetherketone under the inert gas, and stirring the mixture to prepare membrane liquor; performing membrane preparation; completing a crosslinking reaction in the process of membrane forming; and performing demoulding and washing for airing to obtain a cross-linked polymer electrolyte membrane material, wherein the crosslinker is polyaldehyde or polybasic carboxylic acid. The modification method has the characteristics of easily obtained raw materials and simple operation; the prepared cross-linked polymer electrolyte material has the advantages of excellent mechanical strength, conductivity, methanol-blocking performance and dimensional stability, can be directly used in the fields of methanol fuel cells, proton exchange membranes of proton exchange membrane fuel cells, ion exchange resin, membrane separation, sensors and the like, and has important application value.
Owner:TSINGHUA UNIV

Water-based polyurethane solution and preparation process thereof

The invention discloses water-based polyurethane solution and a preparation process thereof. The preparation process comprises the following steps of: dewatering polyester polyol for 1 to 2h under vacuum at the temperature of 120 DEG C; cooling to 80 DEG C and adding isophorone diisocyanate into the dewatered polyester polyol; heating to 90 DEG C and reacting for 2h; cooling to 80 DEG C and adding dimethylol propionic acid (DMPA) and N-methylpyrrolidone into the mixed solution and continuously reacting for 1h; cooling to 60 DEG C, adding AS-15, 1,4-butanediol and dibutyltin dilaurate into the mixed material, adding acetone for adjusting viscosity and reacting; cooling to below 50 DEG C, adding triethylamine, stirring for 0.5h and obtaining a pre-polymer; cooling to below 15 DEG C, dispersing distilled water at the temperature of below 15 DEG C into the prepolymer for 5 minutes at a high speed, instantly adding ethylenediamine for chain extension, dispersing for 0.5h at a high speed and then dispersing for 1h at an intermediate speed; removing acetone under vacuum, adjusting pH to 7.5 with ammonia water and then adding SC-100 into the mixed solution; stirring uniformly, filtering and then packaging. The water-based polyurethane solution has high water resistance, alcohol resistance and hardness; and water is used as a solvent, so that the use of energy resources such as petroleum is reduced and environment is protected at the same time.
Owner:ZHEJIANG FEIDA ZHONGKE FINE CHEM
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products