The invention discloses an organic amine compound absorbent for removal of carbon dioxide in fire coal flue gas; the organic amine compound absorbent comprises the following components: by mass, 10%-45% of a main absorbent component, 0-10% of an assistant absorbent component, 0.01%-6% of a corrosion inhibitor, 0.01-3% of an antioxidant, 0-5% of a defoaming agent and the balance of water; wherein the main absorbent component comprises the following components: account for the total mass percentage of the organic amine composite absorbent, 3%-20% of monoethanolamine MEA, 0-12% of 2-amino-2-methyl-1-propanol AMP, 1%-15% of sun of piperazine PZ and N-aminoethyl piperazine AEP and 1%-12% of sum of aminoethyl ethanolamine AEEA and N-methyl monoethanolamine MMEA; and the assistant absorbent comprises one or a plurality of component selected from the group comprising diethanol amine DEA, diethylenetriamine DETA, triethylene tetramine TETA, N-methyldiethanolamine MDEA, sulfolane and tertbutylaminoethoxyethanol TBEE. The organic amine compound absorbent has the advantages of good stability, large absorption capacity, high purification degree, low regeneration energy consumption, good desorption effect, great reduction of degradation loss of the compound absorbent in the process of using, and the like.