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Nickel-chromium-tungsten-molybdenum-cobalt-iron intermediate alloy and preparation method and application thereof

A master alloy, tungsten-molybdenum technology, applied in the field of nickel-chromium-tungsten-molybdenum-cobalt-iron master alloy and its preparation, can solve problems such as inability to recycle and achieve the effect of improving resource utilization

Active Publication Date: 2022-04-12
宝武特种冶金有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Aiming at the defects existing in the prior art, the object of the present invention is to provide a nickel-chromium-tungsten-molybdenum-cobalt-iron master alloy and its preparation method and application, using superalloy waste as raw material, by controlling the content of W, Mo, Co, etc., supplemented by The balance control of Fe, Cr and Ni matrix elements is smelted by medium frequency induction furnace and AOD furnace, which not only strictly controls the content of O and N, but also controls the content of C, Nb, Al, Ti, B, Ce, Zr and La at a relatively low level. Low level, so that the nickel-chromium-tungsten-molybdenum-cobalt-iron master alloy that can be applied to the preparation of N06230, N08120 and other alloys can be produced, and the waste materials containing W, Mo, Co, B, Ce, Zr, etc. produced in the production process of superalloys cannot be recycled. Utilize the problem, improve resource utilization

Method used

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  • Nickel-chromium-tungsten-molybdenum-cobalt-iron intermediate alloy and preparation method and application thereof
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preparation example Construction

[0035] The above-mentioned nickel-chromium-tungsten-molybdenum-cobalt-iron master alloy adopts the following preparation method, comprising the following steps:

[0036] S1, take superalloy waste (such as the waste produced in the preparation process of superalloys such as GH4720Li, GH4079, GH4586, GH3230, GH3536, GH4710, GH4098, GH4742, GH520, GH751, GH4099 as shown in Table 1, especially turning waste ) as a raw material, according to the target composition of the nickel-chromium-tungsten-molybdenum-cobalt-iron master alloy, then the raw materials are loaded into the induction furnace in batches for chemical transformation, and when the first batch of raw materials are melted by 80%, the second batch is loaded until After all the raw materials are melted, add 1.2-1.5% C element by weight of the raw materials and then measure the temperature. When the temperature reaches 1550°C, transfer the molten steel into the ladle;

[0037] Among them, the target composition of nickel-ch...

Embodiment 1

[0043] S1, according to the target composition of nickel-chromium-tungsten-molybdenum-cobalt-iron master alloy, different high-temperature alloy turning scraps (standard composition shown in Table 1) are used for batching, and the ratio of different high-temperature alloy turning scraps is shown in Table 2, and then Load the raw materials in batches into a 10-30t medium-frequency induction furnace and energize with high power to melt the materials. When the first batch of raw materials melts by 80%, load the second batch of raw materials and then melt the materials. The charging process is repeated 3 to 4 times. , until all the raw materials are melted, add 1.2-1.5% C element by weight of the raw materials, measure the temperature, and when the temperature reaches 1550°C, transfer the molten steel into the ladle;

[0044] Among them, the target composition of nickel-chromium-tungsten-molybdenum-cobalt-iron master alloy includes the following elements by weight percentage: Cr: 1...

Embodiment 2~4

[0048] Examples 2-4 When preparing nickel-chromium-tungsten-molybdenum-cobalt-iron master alloys, the proportions of different high-temperature alloy turning scraps as shown in Table 2 are used for batching. Other preparation processes are the same as in Example 1, and the obtained nickel-chromium The composition of the tungsten-molybdenum-cobalt-iron master alloy is shown in Table 3.

[0049] Composition and content (wt%) of superalloy of table 1

[0050]

[0051] Table 2 Different superalloy scraps and their proportions (wt%) in raw materials

[0052] Grade Example 1 Example 2 Example 3 Example 4 GH4738 5% 5% 5% 5% GH4720Li 5% 5% 5% 5% GH4141 5% 5% 5% 10% GH4037 20% 20% 25% 15% GH4698 25% 35% 40% 40% GH4586 5% 5% 5% 5% GH3230 10% 5% 5% 5% GH3536 15% 10% 5% 10% low carbon ferrochrome 10% 10% 5% 5%

[0053] Table 3 Composition and content (wt%) of nickel-chromium-tungsten-...

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Abstract

The invention discloses a nickel-chromium-tungsten-molybdenum-cobalt-iron intermediate alloy and a preparation method and application thereof.According to the nickel-chromium-tungsten-molybdenum-cobalt-iron intermediate alloy, high-temperature alloy waste serves as a raw material, the contents of W, Mo, Co and the like are controlled, Fe, Cr and Ni matrix elements are controlled in a balanced mode, an induction furnace and an AOD furnace are adopted for smelting, the contents of O and N are strictly controlled, and meanwhile C, Nb, Al, Ti, B, Ce, Zr and La are controlled to be at the low level; therefore, the nickel-chromium-tungsten-molybdenum-cobalt-iron intermediate alloy capable of preparing high-temperature alloys such as N06230 and N08120 is obtained, and the problem that waste materials containing W, Mo, Co, B, Ce, Zr and the like generated in the production process of the high-temperature alloys cannot be recycled is solved.

Description

technical field [0001] The invention relates to the field of nickel-based alloys, in particular to a nickel-chromium-tungsten-molybdenum-cobalt-iron master alloy and a preparation method and application thereof. Background technique [0002] As a class of superalloys, based on iron, nickel, chromium, and cobalt, a large number of strengthening elements such as W, Mo, Al, Ti, and Nb and trace elements such as B, Ce, and Zr are added to form high-temperature resistant alloys at 600°C and above. Oxidation or corrosion resistance, and metal materials that can work for a long time under a certain stress, compared with traditional metals, they have higher high-temperature strength, good oxidation resistance and thermal corrosion resistance, and good Comprehensive properties such as fatigue resistance, creep resistance, fracture toughness, plasticity, and structural stability, as well as high purity and reliability; due to the high-temperature alloy self-consumable steel ingots, ba...

Claims

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Application Information

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IPC IPC(8): C22C19/05C22C1/03C22C1/02C22C1/06C22B9/05C22B7/00
CPCY02P10/20
Inventor 马天军田沛玉余式昌
Owner 宝武特种冶金有限公司