High-strength electrolytic copper foil, method for producing same, electrode, and secondary battery
A technology of electrolytic copper foil and a manufacturing method, applied in the field of electrolytic copper foil, can solve problems such as copper foil breakage, and achieve the effects of preventing tearing or wrinkling, excellent strength and elongation, and high charge and discharge capacity
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Embodiment 1 to 4 and comparative example 1 to 5
[0208] Electrolytic copper foil is manufactured using a foil making machine including an electrolytic cell, a rotating cathode drum disposed in the electrolytic cell, and an anode plate disposed spaced apart from the rotating cathode drum. The electrolyte is copper sulfate solution. The concentration of copper ions in the electrolytic solution was set at 85 g / L, the concentration of sulfuric acid was set at 105 g / L, the average temperature of the electrolytic solution was set at 55° C., and the current density was set at 60 ASD.
[0209] In addition, the presence or absence of carbon filtration, the type and concentration of organic additives contained in the electrolyte, chloride ions (Cl - ) concentrations are shown in Table 1 below.
[0210] In Examples 1 to 4 and Comparative Examples 1, 3, 4, the organic additive was pretreated by carbon filtration before being added to the electrolytic solution. Granular carbon is used in carbon filtration. The added water-soluble organi...
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