Compressible non-fibrous adjunct
An appendage, compressive strength technology, used in nails, medical science, surgery, etc., can solve problems such as lack of tissue characteristics, no thickness, tissue tearing, etc.
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Embodiment 1-3
[0428] Examples 1-3: Preparation of Bifunctional Methacrylate (MA) Terminated Polyester Oligomer
[0429] Examples 1-3 describe the preparation of bifunctional methacrylate terminated polyester oligomers. The middle block is PLGA-PCL-PLGA with a molecular weight of 6 kilodaltons, and PCL accounts for 40 wt.% of the total molecular weight (MW). PLGA is a random copolymer of lactide (L) and glycolide (G), in which the weight ratio of L:G is 1:1.
[0430] The molar ratio and mass of each reagent used to synthesize a 1kg batch of HO-PLGA-b-PCL-b-PLGA-OH as discussed in Example 1 and Example 2 are provided in Table 3 below.
Embodiment 1
[0433] Example 1: synthesis of ho-PCL-oh
[0434] The round-bottom flask was dried overnight in a drying oven and dried in N. 2 Downstream cooling to room temperature. Caprolactone and stannous octoate were added into the round-bottom flask via a glass syringe and syringe needle. The content of that reaction flask were heated to 130. degree. C.. Meanwhile, diethylene glycol was heated to 130℃. After preheating, diethylene glycol was added to the reaction flask as an initiator and allowed to react until the monomer conversion was complete. Use h 1 Monitor monomer conversion by NMR. Once the complete monomer conversion rate is reached, the reaction is stopped and the reaction content is cooled to room temperature. HO-PCL-OH was precipitated from chloroform into cold MeOH to obtain a white solid. H 1 NMR, DSC, FTIR and THF GPC were used to characterize HO-PCL-OH.
Embodiment 2
[0435] Example 2: synthesis of ho-PLGA-b-PCL-b-PLGA-oh
[0436] HO-PCL-OH prepared in Example 1 was mixed with different amounts of D,L- lactide and glycolide in N 2 Added into a round bottom flask and heated to 140℃ to melt the reaction contents. After melting, the temperature was reduced to 120℃ and stannous octoate was added. The reaction was continued under stirring, while H. 1 And the monomer conversion was monitored by NMR and THF GPC. Once the reaction reaches the required molecular weight, the reaction contents are cooled to room temperature, dissolved in chloroform, and precipitated in cold ether for three times. The precipitate was dried under vacuum.
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