Organic compound, light-emitting device, display substrate and display device
A technology for organic compounds and light-emitting devices, applied in organic chemistry, chemical instruments and methods, light-emitting materials, etc., can solve problems such as low luminous efficiency, and achieve the goal of improving molecular orientation, extending molecular axial length, and stabilizing electrochemical stability. Effect
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[0092] Some embodiments of the present disclosure provide a method for preparing the above-mentioned organic compound, comprising the following steps:
[0093] A. Under the protective condition of inert gas, compound I, compound II, base and catalyst A are added to the organic solvent, and the reaction obtains compound III, and its reaction equation is:
[0094]
[0095] It should be noted that Compound I and Compound II are synthetic raw materials, and Compound III is an intermediate for synthesizing the organic compounds of the present disclosure. Wherein, compound I is a fused ring structure of bromobenzene-A-B, the specific structure of compound I can be adjusted according to the specific synthetic target, and the A ring in compound I contains a five-membered ring or six-membered ring with a reaction site of an electron-rich nitrogen atom structure. Ring; Ring B is a five-membered ring or a six-membered ring adjacent to Ring A and fused to Ring A, and Ring B may be pres...
Embodiment 1
[0104] Preparation of M1 Organic Compounds
[0105] Under nitrogen protection, 1-bromo-carbazole (2.2 g, 9 mmol), phenylene bipinacol ester (1.6 g, 0.5 mmol), Pd(dppf)Cl 2 (0.03g, 0.05mmol), sodium tert-butoxide (1.44g, 15mmol) and 200mL of tetrahydrofuran solvent were placed in a 500mL three-necked flask, the reaction temperature was controlled at 95±3°C, refluxed for 24h, and purified and separated to obtain indolo[1, 2,3-lm]indolo[3',2',1':7,1]indolo[2,3-h]carbazole intermediate. The resulting intermediate indolo[1,2,3-lm]indolo[3',2',1':7,1]indolo[2,3-h]carbazole (0.4 g, 1mmol), liquid bromine (0.19g, 1.2mmol), Pd(dppf)Cl 2 (0.03g, 0.05mmol) and 200mL tetrahydrofuran solvent in a 500mL there-necked flask, the reaction temperature was controlled at 95±3°C, and the reaction was refluxed for 24h; then sodium tert-butoxide (1.44g, 15mmol), phenylboronic acid (0.12g, 1mmol) were added. ), carbazole (0.17g, 1mmol), continue the reaction, the reaction temperature is controlled...
Embodiment 2
[0108] Preparation of M2 Organic Compounds
[0109] Under nitrogen protection, 1-bromo-6-tert-butyl-carbazole (2.7 g, 9 mmol), phenylene bipinacol ester (1.6 g, 0.5 mmol), Pd(dppf)Cl2 (0.03g, 0.05mmol), sodium tert-butoxide (1.44g, 15mmol) and 200mL of tetrahydrofuran solvent were placed in a 500mL three-necked flask, the reaction temperature was controlled at 95±3°C, the reaction was refluxed for 24h, and 5,14-di-tert. Butylindolo[1,2,3-lm]indolo[3',2',1':7,1]indolo[2,3-h]carbazole intermediate. The resulting intermediate 5,14-bis(2-methylpropan-2-yl)indolo[1,2,3-lm]indolo[3',2',1':7,1] Indolo[2,3-h]carbazole (0.5 g, 1 mmol), liquid bromine (0.19 g, 1.2 mmol), Pd(dppf)Cl 2 (0.03g, 0.05mmol) and 200mL of tetrahydrofuran solvent in a 500mL three-necked flask, the reaction temperature was controlled at 95±3°C, and the reaction was refluxed for 24h; then sodium tert-butoxide (1.44g, 15mmol), methylboronic acid (0.06g, 1mmol), carbazole (0.17g, 1mmol), continue the reaction, the...
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